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Novel Method for Preparation of Polypropylene Blends with High Melt Strength by Reactive Compounding 被引量:2
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作者 LIU Yu-guang HUANG Yu-dong +2 位作者 ZHANG Cheng-wu HOU Jing ZHANG Xue-quan 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2009年第4期569-572,共4页
Ultrafine full-vulcanized polybutadiene rubber(UFBR) with particle sizes of ca.50―100 nm were used for modifying mechanical and processing performances of polypropylene(PP) with PP-g-maleic anhydride(PP-g-MA) a... Ultrafine full-vulcanized polybutadiene rubber(UFBR) with particle sizes of ca.50―100 nm were used for modifying mechanical and processing performances of polypropylene(PP) with PP-g-maleic anhydride(PP-g-MA) as a compatibilizer for enhancing the interfacial adhesion between the two components.The morphology,dynamical rheology response and mechanical properties of the blends were characterized by means of SEM,rheometer and tensile test,respectively.The results show that the ternary PP/UFBR blends compatibilized with PP-g-MA possess rheological behaviors like highly branched PP,while no obvious strain hardening is observed in its control binary PP/UFBR blends,a low level of PP-g-MA in PP/UFBR blends can even endow the material with rheological characteristics of high melt strength materials like highly branched PP.The enhancement interfacial interaction between the UFBR particles and PP matrix accounting for the rheological behavior of compatibilized blends and effectiveness of PP-g-MA were proposed and proved. 展开更多
关键词 POLYPROPYLENE High melt strength Reactive compounding NANOPARTICLE RHEOLOGY
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Compounding Pattern of REE, Clay and Humic Acid in the Weathering Crust of Granites
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作者 陈炳辉 陈志澄 +3 位作者 梁群优 符群策 俞受鋆 张丽洁 《Journal of Rare Earths》 SCIE EI CAS CSCD 1996年第1期47-53,共7页
An anomalous phase containing clays and humic acid was found while extraction humic acid from samples of weathering crust of REE-bearing granites by using 0.1 mol/L NaOH solution.Studied by chemical separation experim... An anomalous phase containing clays and humic acid was found while extraction humic acid from samples of weathering crust of REE-bearing granites by using 0.1 mol/L NaOH solution.Studied by chemical separation experiments,column chromatography,ion-exchange chromatography,infrared spectrum.fluorescence spectrum,polarimicroscopic testing and elemental determination by ultraviolet-visible spectrometer and atomic absorption spectrometer.it was proved to be a compound of humic acid and clays which are connected in the form of bridge by heteronuclearpolynuclear complexing ions formed by cations of RE ̄(5+),Al ̄(3+).Fe ̄(3+) etc.The compounding pattern was further proved by the experiment for compounding humic acid,REE and kaolinite. 展开更多
关键词 REE Clays Humic acid compounding pattern Weathering crust of granites
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Optimization of ultrasonic elastography by coded excitation and transmit-side multi-frequency compounding
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作者 张志宏 刘昊霖 +1 位作者 何颖妮 刘东权 《Journal of Central South University》 SCIE EI CAS 2014年第3期1003-1010,共8页
To improve the quality of ultrasonic elastography, by taking the advantage of code excitation and frequency compounding, a transmitting-side multi-frequency with coded excitation for elastography (TFCCE) was propose... To improve the quality of ultrasonic elastography, by taking the advantage of code excitation and frequency compounding, a transmitting-side multi-frequency with coded excitation for elastography (TFCCE) was proposed. TFCCE adopts the chirp signal excitation scheme and strikes a balance in the selection of sub-signal bandwidth, the bandwidth overlap and the number of sub-strain image based on theoretical derivation, so as to further improve the quality of elastic image. Experiments have proved that, compared with the other optimizing methods, the elastographyic signal-to-noise ratio(Re-SN) and contrast-to-noise ratio(Re-CN) are improved significantly with different echo signal-to-noise ratios (ReSN) and attenuation coefficients. When ReSN is 50 dB, compared with short pulse, Rc-SN and Re-CN obtained by TFCCE increase by 53% and 143%, respectively. Moreover, in a deeper investigation (85-95 mm), the image has lower strain noise and clear details. When the attenuation coefficient is in the range of 0-1 dB/(cm.MHz), Re-SN and Re-CN obtained by TFCCE can be kept in moderate ranges of 5〈Re-SN〈6.8 and 11.4〈Re-CN〈15.2, respectively. In particular, for higher tissue attenuation, the basic image quality cannot be ensured with short pulse excitation, while mediocre quality strain figure can be obtained by TFCCE. Therefore, the TFCCE technology can effectively improve the elastography quality and can be applied to ultrasonic clinical trials. 展开更多
关键词 ultrasonic elastography coded excitation transmit-side multi-frequency compounding elastographyic signal-to-noise ratio echo signal-to-noise ratio contrast-to-noise ratio
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Effects of Different Compounding of Formulae on Content of Gardenoside in Yin Chen Hao Decoction
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作者 梁光义 曹佩雪 +3 位作者 柴立 冼福荣 李霞 王友京 《Journal of Traditional Chinese Medicine》 SCIE CAS CSCD 2002年第1期55-60,共6页
In order to observe the effects of the ground and intact Zhi Zi (Fructus Gardeniae) and different combinations of the ingredients and refined single Chinese drug granules in Yin Chen Hao Decoction compound prescriptio... In order to observe the effects of the ground and intact Zhi Zi (Fructus Gardeniae) and different combinations of the ingredients and refined single Chinese drug granules in Yin Chen Hao Decoction compound prescription on the contents of gardenoside (an effective component of the prescription), the contents of gardenoside were determined with reversed phase high performance liquid chromatography (HPLC), with acetonitrile-water (15:85) as mobile phase, at wave length 238nm. The results indicated that the gardenoside-decocted-out rates in the decoctions prepared by different combinations of the ingredients with the ground Zhi Zi (Fructus Gardeniae) all were higher significantly than those in the decoction with intact Zhi Zi (Fructus Gardeniae), and generally, different combinations of the ingredients in the decoction had only little effect on the gardenoside-decocted-out rate. 展开更多
关键词 IRIDOIDS Chromatography High Pressure Liquid Comparative Study Drug compounding Drugs Chinese Herbal PYRANS Technology Pharmaceutical
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Optimization Analysis of Correction Tape Box Compounding Cavity Runner Balance Based on Moldflow
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作者 Hongbing Wang Chunhua Sun 《World Journal of Engineering and Technology》 2020年第1期42-49,共8页
Aiming at the problem of runner unbalance in the compounding cavity of the upper and lower cover of the correction tape box, the plastic injection analysis software Moldflow was used to optimize runner balance. First,... Aiming at the problem of runner unbalance in the compounding cavity of the upper and lower cover of the correction tape box, the plastic injection analysis software Moldflow was used to optimize runner balance. First, the 3D modeling software Proe was used to establish the geometric model of the upper and lower cover of the correction tape box, and introduced into the plastic injection analysis software Moldflow. Secondly, the upper and the lower cover of the correction tape box were meshed and the initial gating system was designed in Moldflow. Filling analysis of the initial scheme of the correction tape box combined cavity showed that the runner of the melt was not balanced in the mold cavity. Finally, the runner balance optimization analysis of the cavities was carried out. Through optimization, the time unbalance rate of the melt in the mold cavity decreased from 28.6% to 0.7%, the pressure unbalance rate decreased from 42.0% to 4.2%, and the pressure distribution in the cavity was more uniform in the whole injection process. 展开更多
关键词 compounding CAVITY RUNNER BALANCE Optimization
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A Morphological Compounding Analysis of Hausa Registers Use in Nigerian Cell-phone Market
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作者 Almustapha Wali Sambo 《宏观语言学》 2020年第1期139-150,共12页
This study aims to find the compound registers that are used among the Farm-Centre cell-phone marketers,analyse their compounding morphological structures,and explain the meaning they convey.The Farm-Centre Cell-phone... This study aims to find the compound registers that are used among the Farm-Centre cell-phone marketers,analyse their compounding morphological structures,and explain the meaning they convey.The Farm-Centre Cell-phone Market is located in Kano metropolis,the largest city of Northern Nigeria.The study employs an ethnographic method of data collection and adopts Abubakar(2000)as a model of approach when analysing the structures of the compound registers.It is found that the registers have the following six morphological compound structures:(i)Genitive-based compounds[LG+N]N,(ii)Noun-based compounds[N+GL+N]N,(iii)Adjective-based compounds[Adj+N]N,(iv)Diminutive-based compounds[Dim+N]N,(v)Particle dà‘with’compounds[dà+N]N,(vi)Verb-based compounds[V+VN/Prep]V.Moreover,the registers are so special among the marketers because they convey meanings that are irrelevant to the conventional meanings known by the general speakers of the Hausa language. 展开更多
关键词 Hausa morphology compounding REGISTERS MEANING Kano NIGERIA
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赢创和Compounding Solutions LLC签订了一项医用级聚合物的分销协议
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《环球聚氨酯》 2018年第12期20-20,共1页
赢创公司已与全球领先的定制医疗塑料配制和分销公司Compounding Solutions LLC签署了一项协议,用于销售其VESTAMID?Care ML聚酰胺12, VESTAMID?Care ME聚醚嵌段酰胺(PEBA), TROGAMID?Care clear聚酰胺,和VESTAKEEP?Care PEEK医用级聚合... 赢创公司已与全球领先的定制医疗塑料配制和分销公司Compounding Solutions LLC签署了一项协议,用于销售其VESTAMID?Care ML聚酰胺12, VESTAMID?Care ME聚醚嵌段酰胺(PEBA), TROGAMID?Care clear聚酰胺,和VESTAKEEP?Care PEEK医用级聚合物,在北美临时接触(体内<30天)医疗器械市场上销售。 展开更多
关键词 高性能聚合物 compounding SOLUTIONS LLC 医用级
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Derivation Versus Compounding
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作者 陈雅荃 《海外英语》 2019年第24期117-118,共2页
In English language,affixation is a significant way of forming new words,This essay intends to explore the concepts of two fundamental ways of forming new words,namely,derivation and compounding.They are different in ... In English language,affixation is a significant way of forming new words,This essay intends to explore the concepts of two fundamental ways of forming new words,namely,derivation and compounding.They are different in a lot of cases,yet,it is also argued that there is a clear dividing line between compounding and derivation. 展开更多
关键词 AFFIXATION DERIVATION compounding
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Characteristics of super drought in Southwest China and the associated compounding effect of multiscalar anomalies 被引量:2
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作者 Lin WANG Wen CHEN +7 位作者 Gang HAUNG Ting WANG Qiulin WANG Xiaoyun SU Zixuan REN Chakrit CHOTAMONSAK Atsamon LIMSAKUL Kritanai TORSRI 《Science China Earth Sciences》 SCIE EI CAS CSCD 2024年第7期2084-2102,共19页
In recent decades,Southwest China(SWC)has suffered from frequent super droughts,leading to severe economic losses and ecological degradation.This study investigates the characteristics of super droughts in SWC during ... In recent decades,Southwest China(SWC)has suffered from frequent super droughts,leading to severe economic losses and ecological degradation.This study investigates the characteristics of super droughts in SWC during 1961-2022,reveals the compounding effect of multiscalar anomalies,and explores the plausible atmospheric circulation mechanisms responsible.The nature of super drought is a compound drought caused by the superposition of extreme drought events across multiple time scales.By contrasting the typical drought cases in 2006 and 2022,the decisive role of multiscalar drought compounding is confirmed.Based on the Comprehensive Multiscalar Index(CMI),multiple super drought events in SWC were identified to be temporally clustered during 2006-2014.Among them,the decadal background of enhanced evaporation and precipitation deficit at long time scales is a necessary condition for shaping the overall pattern of super droughts,while the precipitation and evaporation anomalies at short time scales trigger the outbreak of super droughts,determining the exact timing of occurrence.These events include August-September 2006,November 2009 to May 2010,July-October 2011,April-May 2012,January-April 2013,etc.Statistical results suggest that the contribution of superposed precipitation anomalies to super drought is 2.4 times that of evaporation.As regards the circulation mechanisms affecting multiscalar precipitation,the anomalous spatial patterns at short-term and long-term scales are similar,featuring the cyclonic circulation over the South China Sea and the northeasterly wind anomalies together with the subsidence center over SWC.During 2006-2014,the possible causes for the cross-seasonal persistent precipitation reduction in SWC are the extreme negative phase of the Pacific Decadal Oscillation(PDO)in the North Pacific as well as the pronounced warming of the warm pool in the western Pacific.The key dynamic processes are outlined as follows.On the one hand,the negative PDO phase generates anomalous anticyclonic circulation in the North Pacific,with the northeasterly winds on its southwest flank extending to Southeast Asia,hindering moisture transport into SWC.On the other hand,the warming of the warm pool excites anomalous cyclonic circulation to its northwest,also giving rise to northeasterly wind anomalies over SWC.Meanwhile,the ascending motion over the warm pool region diverges at upper levels with outflows converging aloft over SWC,which further induces compensating downward motion there.The combined effect of the above two remote forcings establishes a climatic background state unfavorable for precipitation over SWC at long time scales,thus constituting a crucial prerequisite for the superimposition of short-term precipitation anomalies to develop into super droughts. 展开更多
关键词 Super drought Multiscalar compounding effect Mechanism analysis Southwest China
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Effects of Morphological Awareness on Reading Comprehension in Beginner Chinese EFL Learners
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作者 Weiqi Huang Rendong Cai Xiaomei Yu 《Chinese Journal of Applied Linguistics》 2025年第4期566-584,639,共20页
This study investigates how English morphological awareness contributes to reading comprehension in beginner Chinese EFL learners.The research examines both derivational and compounding morphological awareness at mult... This study investigates how English morphological awareness contributes to reading comprehension in beginner Chinese EFL learners.The research examines both derivational and compounding morphological awareness at multiple levels(identification,discrimination,and manipulation)on English reading comprehension and explores whether their contributions are mediated by vocabulary knowledge.Data were collected from 71 Grade 9 students using various morphological awareness tasks,a vocabulary test,and a reading comprehension assessment.Mixed-effects regression and mediation analyses revealed that all components of morphological awareness,except derivational identification,significantly contributed to reading comprehension.Derivational manipulation was found to have both direct and indirect effects on reading comprehension,partially mediated by vocabulary knowledge.In contrast,compounding awareness influenced reading comprehension primarily through its effect on vocabulary.These findings provide a more nuanced understanding of how different facets of morphological awareness impact reading comprehension in EFL contexts,offering valuable insights for vocabulary and reading instruction. 展开更多
关键词 morphological awareness derivational morphology compounding morphology L2 reading comprehension
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Preparation and Efficacy Evaluation of a Tibetan Gentiana Face Mask Suitable for Sensitive Skin
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作者 Luo Dan 《Asia Pacific Journal of Clinical Medical Research》 2025年第2期43-49,共7页
This study aims to investigate the antioxidant activity of Tibetan gentian(Gentiana spp.)extract and its essence when compounded with a facial mask matrix.It also evaluates the efficacy of facial masks containing gent... This study aims to investigate the antioxidant activity of Tibetan gentian(Gentiana spp.)extract and its essence when compounded with a facial mask matrix.It also evaluates the efficacy of facial masks containing gentian extract on sensitive facial skin and analyzes the comprehensive performance of the mask.A total of 90 patients with facial sensitive skin,enrolled between October 2022 and December 2024,were randomly assigned to either a control group or an observation group,with 45 patients in each.The control group used standard facial masks,while the observation group used masks containing gentian extract.Both groups underwent a 4-week intervention.The effi cacy,lactic acid stinging test indicators,and skin physiological function parameters were compared between the two groups.Results showed that the overall eff ectiveness rate in the observation group reached 93.26%,signifi cantly higher than 71.20%in the control group(P<0.05).After the intervention,both groups showed notable improvements compared to baseline in lactic acid stinging test scores and physiological skin indicators.Specifi cally,the observation group had signifi cantly lower stinging scores and a longer latency before the onset of stinging compared to the control group.Moreover,the skin pH values were lower,while sebum levels and stratum corneum hydration were higher than those in the control group(P<0.05).No serious adverse events occurred in either group.These fi ndings suggest that facial masks containing gentian extract eff ectively alleviate symptoms of sensitive facial skin,enhance skin barrier function and tolerance,and are safe for use. 展开更多
关键词 Tibetan Gentian Traditional Chinese Medicine Extract Facial Mask Matrix compounding Antioxidant Activity Sensitive Facial Skin
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Compound 3k治疗骨关节炎:调控氧化应激通路改善软骨细胞糖酵解的作用机制 被引量:2
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作者 郭素蓉 曹士盛 +2 位作者 穆星彤 杨青 张娟 《中国组织工程研究》 CAS 北大核心 2025年第2期363-370,共8页
背景:骨关节炎现已被认为是一种代谢性疾病,既往研究表明糖酵解在骨关节炎的发生发展中起重要作用。Compound 3k作为一种新型糖酵解小分子抑制剂,具有抗炎及抗肿瘤等功效,因此可靶向糖酵解,有望为骨关节炎治疗提供新的思路。目的:基于... 背景:骨关节炎现已被认为是一种代谢性疾病,既往研究表明糖酵解在骨关节炎的发生发展中起重要作用。Compound 3k作为一种新型糖酵解小分子抑制剂,具有抗炎及抗肿瘤等功效,因此可靶向糖酵解,有望为骨关节炎治疗提供新的思路。目的:基于缺氧诱导因子1α/活性氧的氧化应激通路探究Compound 3k在糖酵解过度活跃所导致的骨关节炎中的作用机制。方法:取对数生长期的ATDC5成软骨细胞,用10 ng/mL白细胞介素1β作用24 h诱导骨关节炎体外细胞模型,以CCK-8法检测不同浓度(0.25,0.5,1,2.5,5,10,15μmol/L)Compound 3k的细胞毒性,选出合适浓度进行后续实验。将软骨细胞随机分为对照组、模型组、治疗组,模型组以10 ng/mL的白细胞介素1β诱导,治疗组以Compound 3k预刺激2 h后与白细胞介素1β共培养,用CCK-8法检测各组细胞增殖情况;用ELISA试剂盒检测各组细胞炎症水平;用试剂盒检测各组细胞活性氧、细胞外乳酸脱氢酶及葡萄糖含量;qRT-PCR及Western blot检测相关炎症因子白细胞介素6、肿瘤坏死因子α及糖酵解相关基因葡萄糖转运蛋白1、甘油醛3-磷酸脱氢酶、单羧酸转运蛋白1和缺氧诱导因子1α的表达水平。结果与结论:①与对照组相比,模型组细胞增殖活性下降、糖酵解水平活跃,表现为细胞外乳酸脱氢酶含量增加(P<0.001),葡萄糖含量减少(P<0.001),相关炎症因子白细胞介素6(P<0.0001)及肿瘤坏死因子α(P<0.001),糖酵解相关基因葡萄糖转运蛋白1(P<0.001)、甘油醛3-磷酸脱氢酶(P<0.001)、单羧酸转运蛋白1(P<0.001)及缺氧诱导因子1α(P<0.001)的表达水平均上调,并伴随氧化应激,活性氧过量产生。②与模型组相比,Compound 3k的治疗有效提高细胞增殖活性,抑制过度活跃的糖酵解水平的同时,抑制了骨关节炎软骨细胞炎症(P<0.001)及糖酵解相关基因的表达(P<0.001),且抑制氧化应激,缺氧诱导因子1α的表达水平下调(P<0.0001),活性氧水平下降。③上述结果证实,Compound 3k抑制了白细胞介素1β诱导的软骨细胞炎症,其机制可能与糖酵解及缺氧诱导因子1α/活性氧介导的氧化应激有关。 展开更多
关键词 骨关节炎 糖酵解 Compound 3k 氧化应激 HIF-1α/ROS ATDC5细胞 葡萄糖代谢 白细胞介素1Β 小分子药物
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适宜中药筛选的不同肺炎小鼠模型的建立
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作者 岳星男 韩佳寅 +7 位作者 潘辰 张宇实 刘素彦 赵雍 张晓萌 吴静雯 唐璇 梁爱华 《中国中药杂志》 北大核心 2025年第15期4089-4099,共11页
该研究通过脂多糖(LPS)、卵清蛋白(OVA)、compound 48/80(C48/80)建立3种模拟临床条件下的非感染性肺炎模型,系统比较其病理特征与中医证候的关联性,为中药药效评价提供适配的动物模型选择依据。采用鼻腔滴注LPS联合腹腔注射强化刺激建... 该研究通过脂多糖(LPS)、卵清蛋白(OVA)、compound 48/80(C48/80)建立3种模拟临床条件下的非感染性肺炎模型,系统比较其病理特征与中医证候的关联性,为中药药效评价提供适配的动物模型选择依据。采用鼻腔滴注LPS联合腹腔注射强化刺激建立急性肺炎模型;第1、3、5天腹腔注射3种剂量卵清蛋白(OVA)+氢氧化铝佐剂,第14~18天经气管内滴注OVA进行激发,建立OVA诱导的过敏性肺炎模型;单次静脉注射3种剂量的C48/80建立C48/80诱导的肺炎模型。通过检测外周血白细胞分类、肺组织及血浆细胞因子、免疫球蛋白、组胺水平和花生四烯酸代谢物变化,结合病理学评估进行多维度分析。结果显示,3种模型均可造成肺水肿,肺部湿重增加,肺组织病理显示明显的渗出性炎症,以LPS最为显著。LPS肺炎模型的白细胞介素(IL)-6、干扰素(IFN)-γ、IL-1β、IL-4等多种致热原性细胞因子显著升高;致血管通透性增高的前列腺素(PG)E2、PGD2等PG类物质含量显著增高;外周血中性粒细胞显著上升。该模型可部分体现临床痰热蕴肺或湿毒壅肺特点。OVA模型主要表现为致敏介质免疫球蛋白(Ig)E和白三烯(LT)E4升高,6-酮(keto)-前列腺素(PG)F2α降低;免疫细胞(淋巴细胞、单核细胞)降低,炎性细胞(中性粒细胞和嗜碱性细胞)升高;体现“虚”“痰”或“湿”的特点。C48/80模型的淋巴细胞、单核细胞、嗜碱性粒细胞显著增加。该模型表现为组胺、大量前列环素类(6-keto-PGE1、PGF2α、15-keto-PGF2α、6-keto-PGF1α、13,14-D-15-keto-PGE2、PGD2、PGE2、PGH2)、LTE4以及5-羟基-二十碳四烯酸(5S-HETE)含量显著增高,这些指标均与血管扩展和血管通透性增高相关;而致热原性炎性细胞因子均未见增高。可见C48/80模型主要体现寒湿蕴肺特点。该研究成功构建了3种非感染性肺炎模型,LPS模型为中性粒细胞浸润及炎症因子升高,适合于清热解毒、化湿祛痰中药的药效研究;OVA模型以过敏性炎性为指标,适用于益气固表类方剂的药效研究;C48/80模型则以血管活性物质(组胺、PGs、LTE4)增多为主,适用于温肺散寒、燥湿化痰中药的药效评价研究。该研究为中药治疗肺炎的药效评价提供了模型选择的理论依据。 展开更多
关键词 肺炎 非感染性肺炎 LPS OVA compound 48/80
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Characterization and source apportionment of volatile organic compounds in Hong Kong:A 5-year study for three different archetypical sites 被引量:2
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作者 Yuchen Mai Vincent Cheung +5 位作者 Peter K.K.Louie Kenneth Leung Jimmy C.H.Fung Alexis K.H.Lau Donald R.B.lake Dasa Gu 《Journal of Environmental Sciences》 2025年第5期424-440,共17页
Initial success has been achieved in Hong Kong in controlling primary air pollutants,but ambient ozone levels kept increasing during the past three decades.Volatile organic compounds(VOCs)are important for mitigating ... Initial success has been achieved in Hong Kong in controlling primary air pollutants,but ambient ozone levels kept increasing during the past three decades.Volatile organic compounds(VOCs)are important for mitigating ozone pollution as its major precursors.This study analyzed VOC characteristics of roadside,suburban,and rural sites in Hong Kong to investigate their compositions,concentrations,and source contributions.Herewe showthat the TVOC concentrations were 23.05±13.24,12.68±15.36,and 5.16±5.48 ppbv for roadside,suburban,and rural sites between May 2015 to June 2019,respectively.By using Positive Matrix Factorization(PMF)model,six sources were identified at the roadside site over five years:Liquefied petroleum gas(LPG)usage(33%–46%),gasoline evaporation(8%–31%),aged air mass(11%–28%),gasoline exhaust(5%–16%),diesel exhaust(2%–16%)and fuel filling(75–9%).Similarly,six sources were distinguished at the suburban site,including LPG usage(30%–33%),solvent usage(20%–26%),diesel exhaust(14%–26%),gasoline evaporation(8%–16%),aged air mass(4%–11%),and biogenic emissions(2%–5%).At the rural site,four sources were identified,including aged airmass(33%–51%),solvent usage(25%–30%),vehicular emissions(11%–28%),and biogenic emissions(6%–12%).The analysis further revealed that fuel filling and LPG usage were the primary contributors to OFP and OH reactivity at the roadside site,while solvent usage and biogenic emissions accounted for almost half of OFP and OH reactivity at the suburban and rural sites,respectively.These findings highlight the importance of identifying and characterizing VOC sources at different sites to help policymakers develop targeted measures for pollution mitigation in specific areas. 展开更多
关键词 Volatile organic compounds Positive matrix factorization Source apportionment Ozone formation
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Chemical characteristics and sources apportionment of volatile organic compounds in the primary urban area of Shijiazhuang,North China Plain 被引量:2
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作者 Xiao Zhang Junfeng Wang +8 位作者 Jiangwei Zhao Junliang He Yali Lei Kai Meng RuiWei Xue Zhang Miaomiao Zhang Shuangying Ni Eleonora Aruffo 《Journal of Environmental Sciences》 2025年第3期465-475,共11页
VOCs(Volatile organic compounds)exert a vital role in ozone and secondary organic aerosol production,necessitating investigations into their concentration,chemical characteristics,and source apportionment for the effe... VOCs(Volatile organic compounds)exert a vital role in ozone and secondary organic aerosol production,necessitating investigations into their concentration,chemical characteristics,and source apportionment for the effective implementation of measures aimed at preventing and controlling atmospheric pollution.FromJuly to October 2020,onlinemonitoringwas conducted in the main urban area of Shijiazhuang to collect data on VOCs and analyze their concentrations and reactivity.Additionally,the PMF(positive matrix factorization)method was utilized to identify the VOCs sources.Results indicated that the TVOCs(total VOCs)concentration was(96.7±63.4μg/m^3),with alkanes exhibiting the highest concentration of(36.1±26.4μg/m^3),followed by OVOCs(16.4±14.4μg/m^3).The key active components were alkenes and aromatics,among which xylene,propylene,toluene,propionaldehyde,acetaldehyde,ethylene,and styrene played crucial roles as reactive species.The sources derived from PMF analysis encompassed vehicle emissions,solvent and coating sources,combustion sources,industrial emissions sources,as well as plant sources,the contribution of which were 37.80%,27.93%,16.57%,15.24%,and 2.46%,respectively.Hence,reducing vehicular exhaust emissions and encouraging neighboring industries to adopt low-volatile organic solvents and coatings should be prioritized to mitigate VOCs levels. 展开更多
关键词 Volatile organic compounds Pollution characteristics Ozone formation potential OH radical loss rate Source apportionment
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Emission characteristics and probabilistic health risk of volatile organic compounds from leather sofa 被引量:2
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作者 Chuanhui Mu Yuling Tang +2 位作者 Zhaohui Yang Jianfei Zhou Bi Shi 《Journal of Environmental Sciences》 2025年第2期79-87,共9页
Furniture is identified as a vital volatile organic compound(VOC)emission source in the indoor environment.Leather has become the most common raw and auxiliary fabric material for upholstered furniture,particularly wi... Furniture is identified as a vital volatile organic compound(VOC)emission source in the indoor environment.Leather has become the most common raw and auxiliary fabric material for upholstered furniture,particularly with extensive consumption in sofas,due to its abundant resources and efficient functions.Despite being widely traded across the world,little research has been conducted on the VOCs released by leathermaterials and their health risk assessment in the indoor environment.Accordingly,this study investigated the VOC emissions of leather with different grades and the health risk of the inhalation exposure.Based on the ultra-fast gas phase electronic nose(EN)and GC-FID/Qtof,the substantial emissions of aliphatic aldehyde ketones(Aks),particularly hexanal,appear to be the cause of off-flavor in medium and low grade(MG and LG)sofa leathers.The health risk assessment indicated that leather materials barely pose non-carcinogenic and carcinogenic effects to residents.Given the abundance of VOC sources and the accumulation of health risks in the indoor environment,more stringent specifications concerning qualitative and quantitative content should be extended to provide VOC treatment basic for the manufacturing industry and obtain better indoor air quality. 展开更多
关键词 Indoor environment LEATHER Volatile organic compounds(VOCs) Health risk assessment
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Enhanced VOC emission with increased temperature contributes to the shift of O_(3)-precursors relationship and optimal control strategy 被引量:2
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作者 Fangqi Qu Yuanjie Huang +11 位作者 Yemin Shen Genqiang Zhong Yan Xu Lingling Jin Hongtao Qian Chun Xiong Fei Zhang Jiasi Shen Bingye Xu Xudong Tian Zhengning Xu Zhibin Wang 《Journal of Environmental Sciences》 2025年第4期218-229,共12页
Assessing the impact of anthropogenic volatile organic compounds(VOCs)on ozone(O_(3))formation is vital for themanagement of emission reduction and pollution control.Continuousmeasurement of O_(3)and the major precurs... Assessing the impact of anthropogenic volatile organic compounds(VOCs)on ozone(O_(3))formation is vital for themanagement of emission reduction and pollution control.Continuousmeasurement of O_(3)and the major precursorswas conducted in a typical light industrial city in the YRD region from 1 May to 25 July in 2021.Alkanes were the most abundant VOC group,contributing to 55.0%of TVOCs concentration(56.43±21.10 ppb).OVOCs,aromatics,halides,alkenes,and alkynes contributed 18.7%,9.6%,9.3%,5.2%and 1.9%,respectively.The observational site shifted from a typical VOC control regime to a mixed regime from May to July,which can be explained by the significant increase of RO_(x)production,resulting in the transition of environment from NOx saturation to radical saturation with respect to O_(3)production.The optimal O_(3)control strategy should be dynamically changed depending on the transition of control regime.Under NOx saturation condition,minimizing the proportion of NOx in reduction could lead to better achievement of O_(3)alleviation.Under mixed control regime,the cut percentage gets the top priority for the effectiveness of O_(3)control.Five VOCs sources were identified:temperature dependent source(28.1%),vehicular exhausts(19.9%),petrochemical industries(7.2%),solvent&gasoline usage(32.3%)and manufacturing industries(12.6%).The increase of temperature and radiation would enhance the evaporation related VOC emissions,resulting in the increase of VOC concentration and the change of RO_(x)circulation.Our results highlight determination of the optimal control strategies for O_(3)pollution in a typical YRD industrial city. 展开更多
关键词 O_(3)pollution Volatile organic compounds Photochemical box model Source apportionment Optimal O_(3)control strategies
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Volatile flavor analysis of flesh oil and liver oil from Doederleinia berycoides based on HS-GC-IMS,HS-SPME-GC-MS and lipidomics 被引量:1
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作者 Feifan Wu Kewei Lin +7 位作者 Jixiang Zhang Xinyang Li Xiaoguo Ying Shanggui Deng Alessandra Guidi Gengsheng Xiao Feng Wang Lukai Ma 《Grain & Oil Science and Technology》 2025年第1期1-12,共12页
Edible oils derived from aquatic products are rich in lipids beneficial to human health.However,the volatile flavor characteristics of flesh oil and liver oil from Doederleinia berycoides remain unclear.In this study,... Edible oils derived from aquatic products are rich in lipids beneficial to human health.However,the volatile flavor characteristics of flesh oil and liver oil from Doederleinia berycoides remain unclear.In this study,flesh oil and liver oil were extracted from Doederleinia berycoides,revealing different fatty acid compositions and contents.Lipidomics analysis identified a total of 124 differential lipids between the flesh oil and liver oil,including 42 glycerophospholipids(GPs),33 glycerolipids(GLs),23 free fatty acids(FAs),13 sphingolipids(SPs),10 sterols(STs),and 3 prenol lipids(PRs).Analysis using HS-GC-IMS identified 12 key volatile compounds that significantly contributed to the distinct volatile flavors of the flesh and liver oils.The volatile flavors originated from these volatile compounds,which had different Relative Odor Activity Values(ROAVs).Further results from HSSPME-GC-MS showed that the volatile flavors of the flesh oil and liver oil were respectively attributed to 64 and 35 volatile compounds,each with unique key volatile compounds exhibiting different ROAVs.There were significant positive or negative correlations between 18 key differential lipids and 24 volatile compounds in both flesh oil and liver oil.Therefore,the complex lipid profiles are responsible for the unique volatile flavors of flesh oil and liver oil,and the differential lipids play a central role in their volatile flavor formation.These findings provide a foundation for understanding the volatile flavor differences in fish oils and hold promise for further exploration of the molecular mechanisms underlying oil volatile flavors. 展开更多
关键词 Flesh oil Liver oil LIPIDS Volatile compounds Volatile flavors
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Pathways of inhibition of filamentous sludge bulking by slowly biodegradable organic compounds 被引量:1
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作者 Chundi Gao Fan Yang +3 位作者 Zinan Tian Diyao Sun Weilin Liu Yongzhen Peng 《Journal of Environmental Sciences》 2025年第4期104-115,共12页
The organic compound composition ofwastewater,serves as a crucial indicator for the operational performance of activated sludge processes and has a major influence on the development of filamentous bulking in activate... The organic compound composition ofwastewater,serves as a crucial indicator for the operational performance of activated sludge processes and has a major influence on the development of filamentous bulking in activated sludge.This study focused on the impact of typical soluble and slowly-biodegradable organic compounds,investigating the pathways through which these substrates affect the occurrence of filamentous bulking in systems operated under both high-and low-oxygen conditions.Results showed that slowly-biodegradable organic compounds lead to a concentrated distribution of microorganisms within flocs,with inward growth of filamentous bacteria.Both Tween-80 and granular starch treated systems exhibited a significant increase in protein content.The glucose system,utilizing soluble substrates,exhibited a markedly higher total polysaccharide content.Microbial communities in the Tween-80 and granular starch treated systems were characterized by a higher abundance of bacteria known to enhance sludge flocculation and settling,such as Competibacter,Xanthomonadaceae and Zoogloea.These findings are of high significance for controlling the operational performance and stability of activated sludge systems,deepening our understanding and providing a novel perspective for the improvement of wastewater treatment processes. 展开更多
关键词 Sludge bulking Slowly biodegradable organic COMPOUNDS Sludge morphology EPS Microbial community
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