Under the backdrop of“Carbon Peak and Carbon Neutrality”(dual carbon)goal in China,the methane-carbon dioxide reforming reaction has attracted considerable attention due to its environmental benefits of converting t...Under the backdrop of“Carbon Peak and Carbon Neutrality”(dual carbon)goal in China,the methane-carbon dioxide reforming reaction has attracted considerable attention due to its environmental benefits of converting two greenhouse gases(methane and carbon dioxide)into syngas and its promising industrial applications.Nickel(Ni)-based catalysts,with high catalytic activity,low cost,and abundant resources,are considered ideal candidates for industrial applications.In this article,three reaction kinetic models were briefly introduced,namely the Power-Law(PL)model,the Eley-Rideal(ER)model,and the Langmuir-Hinshelwood-Hougen-Watson(LHHW)model.Based on the LHHW model,the reaction kinetics and mechanisms of different catalytic systems were systematically discussed,including the properties of supports,the doping of noble metals and transition metals,the role of promoters,and the influence of the geometric and electronic structures of Ni on the reaction mechanism.Furthermore,the kinetics of carbon deposition and elimination on various catalysts were analyzed.Based on the reaction rate expressions for carbon elimination,the reasons for the high activity of transition metal iron(Fe)-doped catalysts and core-shell structured catalysts in carbon elimination were explained.Based on the detailed collation and comparative analysis of the reaction mechanisms and kinetic characteristics across diverse Ni-based catalytic systems,a theoretical guidance for the designing of high-performance catalysts was provided in this work.展开更多
Against the backdrop of integrated development between technical education and higher vocational education,the teaching of Chinese Medicine Processing Technology courses faces new opportunities and challenges.This pap...Against the backdrop of integrated development between technical education and higher vocational education,the teaching of Chinese Medicine Processing Technology courses faces new opportunities and challenges.This paper analyzes the existing problems in the current teaching of Chinese Medicine Processing Technology courses,discusses the necessity of reforming the teaching model under the context of integration,and proposes the construction of a"Dual-Capability Progression,Six-Dimensional Empowerment"teaching model.The aim is to enhance the teaching quality of Chinese Medicine Processing Technology courses and cultivate high-quality skilled talents in Chinese medicine processing who can meet industry demands.展开更多
The cell performance and temperature gradient of a tubular solid oxide fuel cell with indirect internal reformer （IIR-SOFC） fuelled by natural gas, containing a typical catalytic packed-bed reformer, a catalytic coa...The cell performance and temperature gradient of a tubular solid oxide fuel cell with indirect internal reformer （IIR-SOFC） fuelled by natural gas, containing a typical catalytic packed-bed reformer, a catalytic coated wall reformer, a catalytic annular reformer, and a novel catalytic annular-coated wall reformer were investigated with an aim to determine the most efficient internal reformer system. Among the four reformer designs, IIR-SOFC containing an annular-coated wall reformer exhibited the highest performance in terms of cell power density （0.67 W.cm 2） and electrical efficiency （68%） with an acceptable temperature gradient and a moderate pressure drop across the reformer （3.53 × 10 5 kPa）. IIR-SOFC with an annular-coated wall reformer was then studied over a range of operating conditions： inlet fuel temperature, operating pressure, steam to carbon （S ： C） ratio, gas flow pattern （co-flow and counter-flow pattern）, and natural gas compositions. The simulation results showed that the temperature gradient across the reformer could not be decreased using a lower fuel inlet temperature （1223 K-1173 K） and both the power density and electrical efficiency of the cell also decreased by lowering fuel inlet temperature. Operating in higher pressure mode （1-10 bar） improved the temperature gradient and cell performance. Increasing the S ： C ratio from 2 ： 1 to 4：1 could decrease the temperature drop across the reformer but also decrease the cell performance. The average temperature gradient was higher and smoother in IIR-SOFC under a co-flow pattern than that under a counter-flow pattern, leading to lower overpotential and higher cell performance. Natural gas compositions significantly affected the cell performance and temperature gradient. Natural gas containing lower methane content provided smoother temperature gradient in the system but showed lower power density and electrical efficiency.展开更多
General Secretary Xi Jinping has emphasized that reform and opening up is a crucial move in determining the destiny of contemporary China and is also crucial for the success of Chinese modernization.General Secretary ...General Secretary Xi Jinping has emphasized that reform and opening up is a crucial move in determining the destiny of contemporary China and is also crucial for the success of Chinese modernization.General Secretary Xi Jinping and the Central Committee of the Communist Party of China(CPC)deeply care about and have high expectations for Jiangsu as a pioneer in reform and opening up.展开更多
The United Nations(UN)’s 80-year development history has been marked by continuous reform.From the Cold War era to the Post-Cold War period,the UN consistently restructured its mandates,institutional functions,and wo...The United Nations(UN)’s 80-year development history has been marked by continuous reform.From the Cold War era to the Post-Cold War period,the UN consistently restructured its mandates,institutional functions,and working methods to adapt to shifting global landscape.Since 2020,the organization has implemented systematic transformations through multiple reform documents to address global challenges.While progress has been made in reforming its peace and security frameworks.展开更多
The self-reforming of coke oven gas(COG)in a gas-based shaft furnace was investigated,employing metallized iron as a catalyst.Thermodynamic analyses,supported by FactSage 8.3 calculations and regression modeling,were ...The self-reforming of coke oven gas(COG)in a gas-based shaft furnace was investigated,employing metallized iron as a catalyst.Thermodynamic analyses,supported by FactSage 8.3 calculations and regression modeling,were used to investigate the effects of temperature(700–1100℃),CO_(2)(3%–10%),and H_(2)O(1%–9%)concentrations on CH_(4) conversion efficiency.Results indicate that CH_(4) conversion exceeds 90%at temperatures above 1000℃,with CO_(2) and H_(2)O concentrations at 9%and 5%,respectively.During the reforming process,introducing CO_(2) provides additional oxygen,facilitating the oxidation of CH_(4),while H_(2)O enhances H_(2) production through the steam reforming pathway.Experimental findings reveal a CH_(4) conversion of 85.83%with a H_(2)/CO ratio of 5.44 at 1050℃.In addition,an optimal H_(2)O concentration of 6%yields the highest CH_(4) conversion of 84.24%,while CO_(2) exhibits minimal effects on promoting the reforming process.Increasing the metallization rate of pellets from 43%to 92%significantly enhances CH_(4) reforming.This is mainly due to the fact that metallized iron is vital in promoting CH_(4) dissociation and improving syngas yield by providing active sites for the redox cycle of CO_(2) and H_(2)O.展开更多
提出了一种基于PiReformer的风功率预测模型。首先,针对海量高维传感器捕获的数据,提出融合F检验、互信息与方差分析的特征筛选方法,将3类方法提取的特征融合后输入后续预测模型。进一步,在现有Reformer模型的基础上,对嵌入层进行转置...提出了一种基于PiReformer的风功率预测模型。首先,针对海量高维传感器捕获的数据,提出融合F检验、互信息与方差分析的特征筛选方法,将3类方法提取的特征融合后输入后续预测模型。进一步,在现有Reformer模型的基础上,对嵌入层进行转置改进并引入随机噪声,显著提升了模型性能;同时,提出改进的前馈层网络,基于门控线性单元(gated linear unit,GLU)改进单一全连接层,增强对非线性特征的提取能力。此外,模型具备反向残差结构及局部敏感哈希(locality sensitive Hashing,LSH)注意力模块。将所提方法应用于实际风电场的风功率预测,相较于现有模型,取得了更高精度的预测结果。展开更多
With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Ni...With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.展开更多
The reform stems from honesty and determination. Since 2005, organ donation and transplantation in China has undergone thorough reform, which complies with legislation requirements and ethical principles established b...The reform stems from honesty and determination. Since 2005, organ donation and transplantation in China has undergone thorough reform, which complies with legislation requirements and ethical principles established by the World Health Organization(WHO). Reform in China has demonstrated the unwavering confidence and utmost determination of the Chinese government and the Chinese transplantation community. The year 2015 marked a historic turning point when voluntary donations from Chinese citizens became the sole legitimate source for organ transplantation. Since 2015, China has gradually established and refined the “Chinese Mode” and “China System” for organ donation and transplantation, fulfilling its political pledge of reform, and has garnered international recognition, and fostered a social culture which promotes organ donation. This article reviewed the history of reform on organ donation and transplantation in China, presented a new pattern of establishment of organ donation system in the new era of the country, and the direction of advances in the future.展开更多
With the rapid development of artificial intelligence(AI)technology,the teaching mode in the field of education is undergoing profound changes.Especially the design and implementation of personalized learning paths ha...With the rapid development of artificial intelligence(AI)technology,the teaching mode in the field of education is undergoing profound changes.Especially the design and implementation of personalized learning paths have become an important direction of intelligent teaching reform.The traditional“one-size-fits-all”teaching model has gradually failed to meet the individualized learning needs of students.However,through the advantages of data analysis and real-time feedback,AI technology can provide tailor-made teaching content and learning paths based on students’learning progress,interests,and abilities.This study explores the innovation of the personalized learning path model based on AI technology,and analyzes the potential and challenges of this model in improving teaching effectiveness,promoting the all-round development of students,and optimizing the interaction between teachers and students.Through case analysis and empirical research,this paper summarizes the implementation methods of the AI-driven personalized learning path,the innovation of teaching models,and their application prospects in educational reform.Meanwhile,the research also discussed the ethical issues of AI technology in education,data privacy protection,and its impact on the teacher-student relationship,and proposed corresponding solutions.展开更多
This study examines the Big Data Collection and Preprocessing course at Anhui Institute of Information Engineering,implementing a hybrid teaching reform using the Bosi Smart Learning Platform.The proposed hybrid model...This study examines the Big Data Collection and Preprocessing course at Anhui Institute of Information Engineering,implementing a hybrid teaching reform using the Bosi Smart Learning Platform.The proposed hybrid model follows a“three-stage”and“two-subject”framework,incorporating a structured design for teaching content and assessment methods before,during,and after class.Practical results indicate that this approach significantly enhances teaching effectiveness and improves students’learning autonomy.展开更多
Low-concentration coal mine methane(LC-CMM),which is predominantly composed of methane,serves as a clean and low-carbon energy resource with significant potential for utilization.Utilizing LC-CMM as fuel for solid oxi...Low-concentration coal mine methane(LC-CMM),which is predominantly composed of methane,serves as a clean and low-carbon energy resource with significant potential for utilization.Utilizing LC-CMM as fuel for solid oxide fuel cells(SOFCs)represents an efficient and promising strategy for its effective utilization.However,direct application in Ni-based anodes induces carbon deposition,which severely degrades cell performance.Herein,a medium-entropy oxide Sr_(2)FeNi_(0.1)Cr_(0.3)Mn_(0.3)Mo_(0.3)O_(6−δ)(SFNCMM)was developed as an anode internal reforming catalyst.Following reduction treatment,FeNi_(3) nano-alloy particles precipitate on the surface of the material,thereby significantly enhancing its catalytic activity for LC-CMM reforming process.The catalyst achieved a methane conversion rate of 53.3%,demonstrating excellent catalytic performance.Electrochemical evaluations revealed that SFNCMM-Gd_(0.1)Ce_(0.9)O_(2−δ)(GDC)with a weight ratio of 7:3 exhibited superior electrochemical performance when employed as the anodic catalytic layer.With H_(2) and LC-CMM as fuels,the single cell achieved maximum power densities of 1467.32 and 1116.97 mW·cm^(−2) at 800℃,respectively,with corresponding polarization impedances of 0.17 and 1.35Ω·cm^(2).Furthermore,the single cell maintained stable operation for over 100 h under LC-CMM fueling without significant carbon deposition,confirming its robust resistance to carbon formation.These results underscore the potential of medium-entropy oxides as highly effective catalytic layers for mitigating carbon deposition in SOFCs.展开更多
China’s healthcare system faces increasing challenges,including surging medical costs,resource allocation imbalances favoring large hospitals,and ineffective referral mechanisms.The lack of a unified strategy integra...China’s healthcare system faces increasing challenges,including surging medical costs,resource allocation imbalances favoring large hospitals,and ineffective referral mechanisms.The lack of a unified strategy integrating standardized coverage with personalized payment compounds these issues.To this end,this study proposes a risk-sharing reform strategy that combines equal coverage for the same disease(ECSD)with an individualized out-of-pocket(I-OOP)model.Specifically,the study employs a Markov model to capture patient transitions across health states and care levels.The findings show that ECSD and I-OOP enhance equity by standardizing disease coverage while tailoring costs to patient income and facility type.This approach alleviates demand on high-tier hospitals,promoting primary care utilization and enabling balanced resource distribution.The study’s findings provide a reference for policymakers and healthcare administrators by presenting a scalable framework that is aligned with China’s development goals with the aim of fostering an efficient,sustainable healthcare system that is adaptable to regional needs.展开更多
Dry reforming of methane(DRM)has gained significant attention as a promising route to convert two major greenhouse gases(CO_(2) and CH4)to syngas.The development of efficient catalysts is critical for the engineering ...Dry reforming of methane(DRM)has gained significant attention as a promising route to convert two major greenhouse gases(CO_(2) and CH4)to syngas.The development of efficient catalysts is critical for the engineering applications.In this study,the Ce_(x)Zr_(1-x)O_(2)/ZSM-5 composites with different oxygen vacancy concentrations were synthesized by tuning the Ce/Zr ratio,followed by the deposition of metal Ni to island-like Ce_(x)Zr_(1-x)O_(2)on ZSM-5,forming a variety of Ni-Ce_(x)Zr_(1-x)O_(2)/ZSM-5 catalysts,which were applied for the DRM reaction under 750◦C.Combined with various characterizations,it was found that the oxygen vacancy concentration illustrated the volcanic tendency with the decreased Ce/Zr ratio,and the interaction between metal Ni and Ce_(x)Zr_(1-x)O_(2)exhibited a positive relationship with oxygen vacancy concentration.The enhanced between Ni and Ce_(x)Zr_(1-x)O_(2)interaction could improve the strength and amount of Ni-O-M(M=Ce/Zr)species,making the d-band centers of catalysts closer to the Fermi energy level,which was beneficial to the CH4 and CO_(2) activation,along with the improved capacity to resist sintering and coking.Especially,the C1Z3(Ni-Ce0.25Zr0.75O_(2)/ZSM-5)catalyst with the Ce/Zr ratio of 1/3 demonstrated the optimal catalytic performance with 91.9%CH4 and 93.8%CO_(2) conversions within 50 h,accompanied by the best structural and catalytic stability after 100 h.In-situ DRIFTS was employed to study the reaction path and mechanism,discovering that significant amounts of strengthened Ni-O-M species were conducive to activating adsorbed CH4 and CO_(2),and desorbing the linear CO species.展开更多
The objective of this study is to propose an optimal plant design for blue hydrogen production aboard a liquefiednatural gas(LNG)carrier.This investigation focuses on integrating two distinct processes—steam methaner...The objective of this study is to propose an optimal plant design for blue hydrogen production aboard a liquefiednatural gas(LNG)carrier.This investigation focuses on integrating two distinct processes—steam methanereforming(SMR)and ship-based carbon capture(SBCC).The first refers to the common practice used to obtainhydrogen from methane(often derived from natural gas),where steam reacts with methane to produce hydrogenand carbon dioxide(CO_(2)).The second refers to capturing the CO_(2) generated during the SMR process on boardships.By capturing and storing the carbon emissions,the process significantly reduces its environmental impact,making the hydrogen production“blue,”as opposed to“grey”(which involves CO_(2) emissions without capture).For the SMR process,the analysis reveals that increasing the reformer temperature enhances both the processperformance and CO_(2) emissions.Conversely,a higher steam-to-carbon(s/c)ratio reduces hydrogen yield,therebydecreasing thermal efficiency.The study also shows that preheating the air and boil-off gas(BOG)before theyenter the combustion chamber boosts overall efficiency and curtails CO_(2) emissions.In the SBCC process,puremonoethanolamine(MEA)is employed to capture the CO_(2) generated by the exhaust gases from the SMR process.The results indicate that with a 90%CO_(2) capture rate,the associated heat consumption amounts to 4.6 MJ perkilogram of CO_(2) captured.This combined approach offers a viable pathway to produce blue hydrogen on LNGcarriers while significantly reducing the carbon footprint.展开更多
CeO_(2) based semiconductor are widely used in solar-driven photothermal catalytic dry reforming of methane(DRM)reaction,but still suffer from low activity and low light utilization efficiency.This study developed gra...CeO_(2) based semiconductor are widely used in solar-driven photothermal catalytic dry reforming of methane(DRM)reaction,but still suffer from low activity and low light utilization efficiency.This study developed graphite-CeO_(2) interfaces to enhance solar-driven photothermal catalytic DRM.Compared with carbon nanotubes-modified CeO_(2)(CeO_(2)-CNT),graphite-modified CeO_(2)(CeO_(2)-GRA)constructed graphite-CeO_(2) interfaces with distortion in CeO_(2),leading to the formation abundant oxygen vacancies.These graphite-CeO_(2) interfaces with oxygen vacancies enhanced optical absorption and promoted the generation and separation of photogenerated carriers.The high endothermic capacity of graphite elevated the catalyst surface temperature from 592.1−691.3℃,boosting light-to-thermal conversion.The synergy between photogenerated carriers and localized heat enabled Ni/CeO_(2)-GRA to achieve a CO production rate of 9985.6 mmol/(g·h)(vs 7192.4 mmol/(g·h)for Ni/CeO_(2))and a light-to-fuel efficiency of 21.8%(vs 13.8%for Ni/CeO_(2)).This work provides insights for designing graphite-semiconductor interfaces to advance photothermal catalytic efficiency.展开更多
College students’safety education is an important part of the fundamental task of fostering virtue through education in colleges and universities.A questionnaire survey at J University shows that the popularization d...College students’safety education is an important part of the fundamental task of fostering virtue through education in colleges and universities.A questionnaire survey at J University shows that the popularization degree and teaching satisfaction of college students’safety education are relatively high,but the teaching content and teaching forms still need improvement.With the rapid development of artificial intelligence technology and considering the char-acteristics of college students’online learning in the new era,carrying out the SPOC+PBL blended teaching reform not only helps to enhance the effectiveness of theoretical and practical teaching but also contributes to optimizing the teach-ing evaluation and feedback mechanism and strengthening students’problem-solving abilities.Therefore,we should adhere to the goal orientation,meticulously design the teaching plan,highlight the student-centered approach,focus on integrating teaching resources,strengthen process management,promptly provide feedback and guidance,empower with data,and continuously improve teaching evaluation.Thus,a student-centered SPOC+PBL blended teaching sys-tem can be constructed to empower the transformation and innovation of talent cultivation in higher education.展开更多
When the G20 was created in 1999 in the wake of the Asian financial crisis,few imagined it would one day become the nerve centre of global governance.Twenty-six years later,the G20 members,which represent 85 percent o...When the G20 was created in 1999 in the wake of the Asian financial crisis,few imagined it would one day become the nerve centre of global governance.Twenty-six years later,the G20 members,which represent 85 percent of the global GDP and two-thirds of the world population,are once again navigating a turbulent era marked by geopolitical rivalry,economic fragmentation and widening inequality.展开更多
High density polyethylene(HDPE)pyrolysis and in-line oxidative steam reforming was carried out in a two-step reaction system consisting of a conical spouted bed reactor and a fluidized bed reactor.Continuous plastic p...High density polyethylene(HDPE)pyrolysis and in-line oxidative steam reforming was carried out in a two-step reaction system consisting of a conical spouted bed reactor and a fluidized bed reactor.Continuous plastic pyrolysis was conducted at 550℃ and the volatiles formed were fed in-line to the oxidative steam reforming step(space-time 3.12 gcat min gHDPE−1;ER=0.2 and steam/plastic=3)operating at 700℃.The influence Ni based reforming catalyst support(Al_(2)O_(3),ZrO_(2),SiO_(2))and promoter(CeO_(2),La_(2)O_(3))have on HDPE pyrolysis volatiles conversion and H_(2) production was assessed.The catalysts were prepared by the wet impregnation and they were characterized by means of N_(2) adsorption-desorption,X-ray fluorescence,temperature-programmed reduction and X-ray powder diffraction.A preliminary study on coke deposition and the deterioration of catalysts properties was carried out,by analyzing the tested catalysts through temperature programmed oxidation of coke,transmission electron microscopy,and N_(2) adsorption-desorption.Among the supports tested,ZrO_(2) showed the best performance,attaining conversion and H_(2) production values of 92.2% and 12.8 wt%,respectively.Concerning promoted catalysts,they led to similar conversion values(around 90%),but significant differences were observed in H_(2) production.Thus,higher H_(2) productions were obtained on the Ni/La_(2)O_(3)-Al_(2)O_(3) catalyst(12.1 wt%)than on CeO_(2) promoted catalysts due to La_(2)O_(3) capability for enhancing water adsorption on the catalyst surface.展开更多
It is economical to perform methane and carbon dioxide reforming(DRM)under industrially relevant high-pressure conditions,but the harsh operation condition poses a grand challenge for coke-resistant catalyst design.He...It is economical to perform methane and carbon dioxide reforming(DRM)under industrially relevant high-pressure conditions,but the harsh operation condition poses a grand challenge for coke-resistant catalyst design.Here,we propose to boost the coke-tolerance of Co catalyst by applying a contact potential introduced by immiscible Ag clusters.We demonstrate that Co clusters separated by neighboring Ag on Yttria-stabilized zirconia(YSZ)support can serve as a coke-and sintering-resistant DRM catalyst under diluent gas-free,stoichiometric CH_(4) and CO_(2) feeding,1123 K and 20 bar.Since immiscible metals are ubiquitous and metal contact influences surface work function in general,this new design concept may have general implications for tailoring catalytic properties of metals.展开更多
基金Supported by Innovation Capability Support Program of Shaanxi(2024RS-CXTD-53,2024ZC-KJXX-096)the Key R&D Program of Shaanxi Province(2022QCY-LL-69)Xi’an Science and Technology Project(24GXFW0089)。
文摘Under the backdrop of“Carbon Peak and Carbon Neutrality”(dual carbon)goal in China,the methane-carbon dioxide reforming reaction has attracted considerable attention due to its environmental benefits of converting two greenhouse gases(methane and carbon dioxide)into syngas and its promising industrial applications.Nickel(Ni)-based catalysts,with high catalytic activity,low cost,and abundant resources,are considered ideal candidates for industrial applications.In this article,three reaction kinetic models were briefly introduced,namely the Power-Law(PL)model,the Eley-Rideal(ER)model,and the Langmuir-Hinshelwood-Hougen-Watson(LHHW)model.Based on the LHHW model,the reaction kinetics and mechanisms of different catalytic systems were systematically discussed,including the properties of supports,the doping of noble metals and transition metals,the role of promoters,and the influence of the geometric and electronic structures of Ni on the reaction mechanism.Furthermore,the kinetics of carbon deposition and elimination on various catalysts were analyzed.Based on the reaction rate expressions for carbon elimination,the reasons for the high activity of transition metal iron(Fe)-doped catalysts and core-shell structured catalysts in carbon elimination were explained.Based on the detailed collation and comparative analysis of the reaction mechanisms and kinetic characteristics across diverse Ni-based catalytic systems,a theoretical guidance for the designing of high-performance catalysts was provided in this work.
基金Supported by Scientific Research Fund Project of Yunnan Provincial Department of Education(2025J1950).
文摘Against the backdrop of integrated development between technical education and higher vocational education,the teaching of Chinese Medicine Processing Technology courses faces new opportunities and challenges.This paper analyzes the existing problems in the current teaching of Chinese Medicine Processing Technology courses,discusses the necessity of reforming the teaching model under the context of integration,and proposes the construction of a"Dual-Capability Progression,Six-Dimensional Empowerment"teaching model.The aim is to enhance the teaching quality of Chinese Medicine Processing Technology courses and cultivate high-quality skilled talents in Chinese medicine processing who can meet industry demands.
基金supported by the Thailand Research Fund(TRG 5680051)
文摘The cell performance and temperature gradient of a tubular solid oxide fuel cell with indirect internal reformer （IIR-SOFC） fuelled by natural gas, containing a typical catalytic packed-bed reformer, a catalytic coated wall reformer, a catalytic annular reformer, and a novel catalytic annular-coated wall reformer were investigated with an aim to determine the most efficient internal reformer system. Among the four reformer designs, IIR-SOFC containing an annular-coated wall reformer exhibited the highest performance in terms of cell power density （0.67 W.cm 2） and electrical efficiency （68%） with an acceptable temperature gradient and a moderate pressure drop across the reformer （3.53 × 10 5 kPa）. IIR-SOFC with an annular-coated wall reformer was then studied over a range of operating conditions： inlet fuel temperature, operating pressure, steam to carbon （S ： C） ratio, gas flow pattern （co-flow and counter-flow pattern）, and natural gas compositions. The simulation results showed that the temperature gradient across the reformer could not be decreased using a lower fuel inlet temperature （1223 K-1173 K） and both the power density and electrical efficiency of the cell also decreased by lowering fuel inlet temperature. Operating in higher pressure mode （1-10 bar） improved the temperature gradient and cell performance. Increasing the S ： C ratio from 2 ： 1 to 4：1 could decrease the temperature drop across the reformer but also decrease the cell performance. The average temperature gradient was higher and smoother in IIR-SOFC under a co-flow pattern than that under a counter-flow pattern, leading to lower overpotential and higher cell performance. Natural gas compositions significantly affected the cell performance and temperature gradient. Natural gas containing lower methane content provided smoother temperature gradient in the system but showed lower power density and electrical efficiency.
文摘General Secretary Xi Jinping has emphasized that reform and opening up is a crucial move in determining the destiny of contemporary China and is also crucial for the success of Chinese modernization.General Secretary Xi Jinping and the Central Committee of the Communist Party of China(CPC)deeply care about and have high expectations for Jiangsu as a pioneer in reform and opening up.
文摘The United Nations(UN)’s 80-year development history has been marked by continuous reform.From the Cold War era to the Post-Cold War period,the UN consistently restructured its mandates,institutional functions,and working methods to adapt to shifting global landscape.Since 2020,the organization has implemented systematic transformations through multiple reform documents to address global challenges.While progress has been made in reforming its peace and security frameworks.
基金financially supported by the National Natural Science Foundation of China(No.52004339)the Key Research and Development Project of Hunan Province,China(No.2022SK2075)+1 种基金China Baowu Low Carbon Metallurgy Innovation Foundation(BWLCF202216)Central South University Graduate Student Independent Exploration and Innovation Project(2024ZZTS0378).
文摘The self-reforming of coke oven gas(COG)in a gas-based shaft furnace was investigated,employing metallized iron as a catalyst.Thermodynamic analyses,supported by FactSage 8.3 calculations and regression modeling,were used to investigate the effects of temperature(700–1100℃),CO_(2)(3%–10%),and H_(2)O(1%–9%)concentrations on CH_(4) conversion efficiency.Results indicate that CH_(4) conversion exceeds 90%at temperatures above 1000℃,with CO_(2) and H_(2)O concentrations at 9%and 5%,respectively.During the reforming process,introducing CO_(2) provides additional oxygen,facilitating the oxidation of CH_(4),while H_(2)O enhances H_(2) production through the steam reforming pathway.Experimental findings reveal a CH_(4) conversion of 85.83%with a H_(2)/CO ratio of 5.44 at 1050℃.In addition,an optimal H_(2)O concentration of 6%yields the highest CH_(4) conversion of 84.24%,while CO_(2) exhibits minimal effects on promoting the reforming process.Increasing the metallization rate of pellets from 43%to 92%significantly enhances CH_(4) reforming.This is mainly due to the fact that metallized iron is vital in promoting CH_(4) dissociation and improving syngas yield by providing active sites for the redox cycle of CO_(2) and H_(2)O.
文摘提出了一种基于PiReformer的风功率预测模型。首先,针对海量高维传感器捕获的数据,提出融合F检验、互信息与方差分析的特征筛选方法,将3类方法提取的特征融合后输入后续预测模型。进一步,在现有Reformer模型的基础上,对嵌入层进行转置改进并引入随机噪声,显著提升了模型性能;同时,提出改进的前馈层网络,基于门控线性单元(gated linear unit,GLU)改进单一全连接层,增强对非线性特征的提取能力。此外,模型具备反向残差结构及局部敏感哈希(locality sensitive Hashing,LSH)注意力模块。将所提方法应用于实际风电场的风功率预测,相较于现有模型,取得了更高精度的预测结果。
基金supported by the Natural Science Foundation of Shanxi Province(202203021221155)the Foundation of National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal(J23-24-902)。
文摘With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.
文摘The reform stems from honesty and determination. Since 2005, organ donation and transplantation in China has undergone thorough reform, which complies with legislation requirements and ethical principles established by the World Health Organization(WHO). Reform in China has demonstrated the unwavering confidence and utmost determination of the Chinese government and the Chinese transplantation community. The year 2015 marked a historic turning point when voluntary donations from Chinese citizens became the sole legitimate source for organ transplantation. Since 2015, China has gradually established and refined the “Chinese Mode” and “China System” for organ donation and transplantation, fulfilling its political pledge of reform, and has garnered international recognition, and fostered a social culture which promotes organ donation. This article reviewed the history of reform on organ donation and transplantation in China, presented a new pattern of establishment of organ donation system in the new era of the country, and the direction of advances in the future.
基金The 2024 Guangdong University of Science and Technology Teaching,Science and Innovation Project(GKJXXZ2024028)。
文摘With the rapid development of artificial intelligence(AI)technology,the teaching mode in the field of education is undergoing profound changes.Especially the design and implementation of personalized learning paths have become an important direction of intelligent teaching reform.The traditional“one-size-fits-all”teaching model has gradually failed to meet the individualized learning needs of students.However,through the advantages of data analysis and real-time feedback,AI technology can provide tailor-made teaching content and learning paths based on students’learning progress,interests,and abilities.This study explores the innovation of the personalized learning path model based on AI technology,and analyzes the potential and challenges of this model in improving teaching effectiveness,promoting the all-round development of students,and optimizing the interaction between teachers and students.Through case analysis and empirical research,this paper summarizes the implementation methods of the AI-driven personalized learning path,the innovation of teaching models,and their application prospects in educational reform.Meanwhile,the research also discussed the ethical issues of AI technology in education,data privacy protection,and its impact on the teacher-student relationship,and proposed corresponding solutions.
基金2024 Anqing Normal University University-Level Key Project(ZK2024062D)。
文摘This study examines the Big Data Collection and Preprocessing course at Anhui Institute of Information Engineering,implementing a hybrid teaching reform using the Bosi Smart Learning Platform.The proposed hybrid model follows a“three-stage”and“two-subject”framework,incorporating a structured design for teaching content and assessment methods before,during,and after class.Practical results indicate that this approach significantly enhances teaching effectiveness and improves students’learning autonomy.
基金supported by the National Key R&D Program of China(No.2024YFB4007501)the Natural Science Foundation of Jiangsu Province(No.BK20240109)the project of Jiangsu Key Laboratory for Clean Utilization of Carbon Resources(No.BM2024007).
文摘Low-concentration coal mine methane(LC-CMM),which is predominantly composed of methane,serves as a clean and low-carbon energy resource with significant potential for utilization.Utilizing LC-CMM as fuel for solid oxide fuel cells(SOFCs)represents an efficient and promising strategy for its effective utilization.However,direct application in Ni-based anodes induces carbon deposition,which severely degrades cell performance.Herein,a medium-entropy oxide Sr_(2)FeNi_(0.1)Cr_(0.3)Mn_(0.3)Mo_(0.3)O_(6−δ)(SFNCMM)was developed as an anode internal reforming catalyst.Following reduction treatment,FeNi_(3) nano-alloy particles precipitate on the surface of the material,thereby significantly enhancing its catalytic activity for LC-CMM reforming process.The catalyst achieved a methane conversion rate of 53.3%,demonstrating excellent catalytic performance.Electrochemical evaluations revealed that SFNCMM-Gd_(0.1)Ce_(0.9)O_(2−δ)(GDC)with a weight ratio of 7:3 exhibited superior electrochemical performance when employed as the anodic catalytic layer.With H_(2) and LC-CMM as fuels,the single cell achieved maximum power densities of 1467.32 and 1116.97 mW·cm^(−2) at 800℃,respectively,with corresponding polarization impedances of 0.17 and 1.35Ω·cm^(2).Furthermore,the single cell maintained stable operation for over 100 h under LC-CMM fueling without significant carbon deposition,confirming its robust resistance to carbon formation.These results underscore the potential of medium-entropy oxides as highly effective catalytic layers for mitigating carbon deposition in SOFCs.
基金The National Natural Science Foundation of China(No.72071042)。
文摘China’s healthcare system faces increasing challenges,including surging medical costs,resource allocation imbalances favoring large hospitals,and ineffective referral mechanisms.The lack of a unified strategy integrating standardized coverage with personalized payment compounds these issues.To this end,this study proposes a risk-sharing reform strategy that combines equal coverage for the same disease(ECSD)with an individualized out-of-pocket(I-OOP)model.Specifically,the study employs a Markov model to capture patient transitions across health states and care levels.The findings show that ECSD and I-OOP enhance equity by standardizing disease coverage while tailoring costs to patient income and facility type.This approach alleviates demand on high-tier hospitals,promoting primary care utilization and enabling balanced resource distribution.The study’s findings provide a reference for policymakers and healthcare administrators by presenting a scalable framework that is aligned with China’s development goals with the aim of fostering an efficient,sustainable healthcare system that is adaptable to regional needs.
基金the following financial supports:National Natural Science Foundation of China(22075225 and 22038011)Innovative Scientific Program of CNNC,State Key Laboratory of Clean and Efficient Coal Utilization,Taiyuan University of Technology(MJNYSKL202401,MJNYSKL202404).
文摘Dry reforming of methane(DRM)has gained significant attention as a promising route to convert two major greenhouse gases(CO_(2) and CH4)to syngas.The development of efficient catalysts is critical for the engineering applications.In this study,the Ce_(x)Zr_(1-x)O_(2)/ZSM-5 composites with different oxygen vacancy concentrations were synthesized by tuning the Ce/Zr ratio,followed by the deposition of metal Ni to island-like Ce_(x)Zr_(1-x)O_(2)on ZSM-5,forming a variety of Ni-Ce_(x)Zr_(1-x)O_(2)/ZSM-5 catalysts,which were applied for the DRM reaction under 750◦C.Combined with various characterizations,it was found that the oxygen vacancy concentration illustrated the volcanic tendency with the decreased Ce/Zr ratio,and the interaction between metal Ni and Ce_(x)Zr_(1-x)O_(2)exhibited a positive relationship with oxygen vacancy concentration.The enhanced between Ni and Ce_(x)Zr_(1-x)O_(2)interaction could improve the strength and amount of Ni-O-M(M=Ce/Zr)species,making the d-band centers of catalysts closer to the Fermi energy level,which was beneficial to the CH4 and CO_(2) activation,along with the improved capacity to resist sintering and coking.Especially,the C1Z3(Ni-Ce0.25Zr0.75O_(2)/ZSM-5)catalyst with the Ce/Zr ratio of 1/3 demonstrated the optimal catalytic performance with 91.9%CH4 and 93.8%CO_(2) conversions within 50 h,accompanied by the best structural and catalytic stability after 100 h.In-situ DRIFTS was employed to study the reaction path and mechanism,discovering that significant amounts of strengthened Ni-O-M species were conducive to activating adsorbed CH4 and CO_(2),and desorbing the linear CO species.
文摘The objective of this study is to propose an optimal plant design for blue hydrogen production aboard a liquefiednatural gas(LNG)carrier.This investigation focuses on integrating two distinct processes—steam methanereforming(SMR)and ship-based carbon capture(SBCC).The first refers to the common practice used to obtainhydrogen from methane(often derived from natural gas),where steam reacts with methane to produce hydrogenand carbon dioxide(CO_(2)).The second refers to capturing the CO_(2) generated during the SMR process on boardships.By capturing and storing the carbon emissions,the process significantly reduces its environmental impact,making the hydrogen production“blue,”as opposed to“grey”(which involves CO_(2) emissions without capture).For the SMR process,the analysis reveals that increasing the reformer temperature enhances both the processperformance and CO_(2) emissions.Conversely,a higher steam-to-carbon(s/c)ratio reduces hydrogen yield,therebydecreasing thermal efficiency.The study also shows that preheating the air and boil-off gas(BOG)before theyenter the combustion chamber boosts overall efficiency and curtails CO_(2) emissions.In the SBCC process,puremonoethanolamine(MEA)is employed to capture the CO_(2) generated by the exhaust gases from the SMR process.The results indicate that with a 90%CO_(2) capture rate,the associated heat consumption amounts to 4.6 MJ perkilogram of CO_(2) captured.This combined approach offers a viable pathway to produce blue hydrogen on LNGcarriers while significantly reducing the carbon footprint.
文摘CeO_(2) based semiconductor are widely used in solar-driven photothermal catalytic dry reforming of methane(DRM)reaction,but still suffer from low activity and low light utilization efficiency.This study developed graphite-CeO_(2) interfaces to enhance solar-driven photothermal catalytic DRM.Compared with carbon nanotubes-modified CeO_(2)(CeO_(2)-CNT),graphite-modified CeO_(2)(CeO_(2)-GRA)constructed graphite-CeO_(2) interfaces with distortion in CeO_(2),leading to the formation abundant oxygen vacancies.These graphite-CeO_(2) interfaces with oxygen vacancies enhanced optical absorption and promoted the generation and separation of photogenerated carriers.The high endothermic capacity of graphite elevated the catalyst surface temperature from 592.1−691.3℃,boosting light-to-thermal conversion.The synergy between photogenerated carriers and localized heat enabled Ni/CeO_(2)-GRA to achieve a CO production rate of 9985.6 mmol/(g·h)(vs 7192.4 mmol/(g·h)for Ni/CeO_(2))and a light-to-fuel efficiency of 21.8%(vs 13.8%for Ni/CeO_(2)).This work provides insights for designing graphite-semiconductor interfaces to advance photothermal catalytic efficiency.
基金“Research on Mental Health Education of Poor College Students-Based on the Perspective of‘New Campus’”Philosophy and Social Science Research Project of Universities in Jiangsu Province(2019SJB912)“Research on Mental Health Education of Poor College Students-Based on the Perspective of‘New Campus’”Special Topic of Ideological and Political Education for College Students in 2018(JDXGXB201801)“Research on College English Teaching Strategies from the Perspective of the Theory of Multiple Intelligences”Jiangsu Provincial University Philosophy and Social Sciences Research Project(2023SJYB2216)。
文摘College students’safety education is an important part of the fundamental task of fostering virtue through education in colleges and universities.A questionnaire survey at J University shows that the popularization degree and teaching satisfaction of college students’safety education are relatively high,but the teaching content and teaching forms still need improvement.With the rapid development of artificial intelligence technology and considering the char-acteristics of college students’online learning in the new era,carrying out the SPOC+PBL blended teaching reform not only helps to enhance the effectiveness of theoretical and practical teaching but also contributes to optimizing the teach-ing evaluation and feedback mechanism and strengthening students’problem-solving abilities.Therefore,we should adhere to the goal orientation,meticulously design the teaching plan,highlight the student-centered approach,focus on integrating teaching resources,strengthen process management,promptly provide feedback and guidance,empower with data,and continuously improve teaching evaluation.Thus,a student-centered SPOC+PBL blended teaching sys-tem can be constructed to empower the transformation and innovation of talent cultivation in higher education.
文摘When the G20 was created in 1999 in the wake of the Asian financial crisis,few imagined it would one day become the nerve centre of global governance.Twenty-six years later,the G20 members,which represent 85 percent of the global GDP and two-thirds of the world population,are once again navigating a turbulent era marked by geopolitical rivalry,economic fragmentation and widening inequality.
文摘High density polyethylene(HDPE)pyrolysis and in-line oxidative steam reforming was carried out in a two-step reaction system consisting of a conical spouted bed reactor and a fluidized bed reactor.Continuous plastic pyrolysis was conducted at 550℃ and the volatiles formed were fed in-line to the oxidative steam reforming step(space-time 3.12 gcat min gHDPE−1;ER=0.2 and steam/plastic=3)operating at 700℃.The influence Ni based reforming catalyst support(Al_(2)O_(3),ZrO_(2),SiO_(2))and promoter(CeO_(2),La_(2)O_(3))have on HDPE pyrolysis volatiles conversion and H_(2) production was assessed.The catalysts were prepared by the wet impregnation and they were characterized by means of N_(2) adsorption-desorption,X-ray fluorescence,temperature-programmed reduction and X-ray powder diffraction.A preliminary study on coke deposition and the deterioration of catalysts properties was carried out,by analyzing the tested catalysts through temperature programmed oxidation of coke,transmission electron microscopy,and N_(2) adsorption-desorption.Among the supports tested,ZrO_(2) showed the best performance,attaining conversion and H_(2) production values of 92.2% and 12.8 wt%,respectively.Concerning promoted catalysts,they led to similar conversion values(around 90%),but significant differences were observed in H_(2) production.Thus,higher H_(2) productions were obtained on the Ni/La_(2)O_(3)-Al_(2)O_(3) catalyst(12.1 wt%)than on CeO_(2) promoted catalysts due to La_(2)O_(3) capability for enhancing water adsorption on the catalyst surface.
文摘It is economical to perform methane and carbon dioxide reforming(DRM)under industrially relevant high-pressure conditions,but the harsh operation condition poses a grand challenge for coke-resistant catalyst design.Here,we propose to boost the coke-tolerance of Co catalyst by applying a contact potential introduced by immiscible Ag clusters.We demonstrate that Co clusters separated by neighboring Ag on Yttria-stabilized zirconia(YSZ)support can serve as a coke-and sintering-resistant DRM catalyst under diluent gas-free,stoichiometric CH_(4) and CO_(2) feeding,1123 K and 20 bar.Since immiscible metals are ubiquitous and metal contact influences surface work function in general,this new design concept may have general implications for tailoring catalytic properties of metals.
