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Scalable synthesis of high-purity Ti_(4)N_(3)T_(x)MXene via saturated salt solution(S^(3))etching
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作者 Yujin Chae Shi-Hyun Seok +8 位作者 Yeoseon Sim Ju-Hyoung Han Jaeeun Park Younggeun Jang Mincheal Kim Young Ho Jin EunMi Choi Zonghoon Lee Soon-Yong Kwon 《Advanced Powder Materials》 2025年第6期41-49,共9页
Two-dimensional(2D)nitride MXenes are predicted to exhibit exceptional metallic properties and high polarity;however,their synthesis remains challenging.Research has relied on traditional molten salt etching,highlight... Two-dimensional(2D)nitride MXenes are predicted to exhibit exceptional metallic properties and high polarity;however,their synthesis remains challenging.Research has relied on traditional molten salt etching,highlighting the need for a scalable,high-purity approach.Here,we present the first solution-based synthesis of Ti_(4)N_(3)T_(x)MXene via a novel saturated salt solution(S^(3))etching technique employing alkali metal salts.By optimizing the sintering process for high-purity Ti_(4)AlN_(3)MAX and refining the S^(3)etching route,we significantly reduced the etch pit density to 1.2×10^(6)cm^(-2)and lowered the etch pit formation rate to 4%,yielding high-quality,phasepure Ti_(4)N_(3)T_(x)MXene.Our study highlights the critical role of alkali metal ions in selective A-layer removal and demonstrates the impressive electrical conductivity and electromagnetic interference shielding performance of 2D nitride MXene,setting a new benchmark for this underexplored material.These findings pave the way for advancing 2D nitride MXenes and their diverse applications. 展开更多
关键词 Nitride MXene Nitride MAX precursor SINTERING solution process saturated salt solution(S^(3))etching HIGH-PURITY Physical property
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Long-term stability of gentamicin sulfate-ethylenediaminetetraacetic acid disodium salt (EDTA-Na_2) solution for catheter locks 被引量:3
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作者 Anne-Sophie Fiolet Elise Jandot +7 位作者 Pauline Doucey Coralie Crétet Célia Brunel Christine Pivot Jean-Marc Ghigo Christophe Beloin David Lebeaux Fabrice Pirot 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2018年第6期386-393,共8页
A lock solution composed of gentamicin sulfate(5 mg/mL) and ethylenediaminetetraacetic acid disodium salt(EDTA-Na2, 30 mg/mL) could fully eradicate in vivo bacterial biofilms in totally implantable venous access ports... A lock solution composed of gentamicin sulfate(5 mg/mL) and ethylenediaminetetraacetic acid disodium salt(EDTA-Na2, 30 mg/mL) could fully eradicate in vivo bacterial biofilms in totally implantable venous access ports(TIVAP). In this study, fabrication, conditioning and sterilization processes of antimicrobial lock solution(ALS) were detailed and completed by a stability study. Stability of ALS was conducted for12 months in vial(25 °C 7 2 °C, 60% 7 5% relative humidity(RH), and at 40 °C 7 2 °C, RH 75% 7 5%)and for 24 h and 72 h in TIVAP(40 °C 7 2 °C, RH 75% 7 5%). A stability indicating HPLC assay with UV detection for simultaneous quantification of gentamicin sulfate and EDTA-Na2 was developed. ALS was assayed by ion-pairing high performance liquid chromatography(HPLC) needing gentamicin derivatization, EDTA-Na2 metallocomplexation of samples and gradient mobile phase. HPLC methods to separate four gentamicin components and EDTA-Na2 were validated. Efficiency of sterility procedure and conditioning of ALS was confirmed by bacterial endotoxins and sterility tests. Physicochemical stability of ALS was determined by visual inspection, osmolality, pH, and sub-visible particle counting. Results confirmed that the stability of ALS in vials was maintained for 12 months and 24 h and 72 h in TIVAP. 展开更多
关键词 Gentamicin-EDTA-Na2 loaded antimicrobial lock solution Pharmaceutical COMPOUNDING Stability indicating HPLC assay method Totally implantable VENOUS access ports
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Decay Mode Solutions to (2 + 1)-Dimensional Burgers Equation, Cylindrical Burgers Equation and Spherical Burgers Equation 被引量:1
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作者 Xiangzheng Li Jinliang Zhang Mingliang Wang 《Journal of Applied Mathematics and Physics》 2017年第5期1009-1015,共7页
Three (2 + 1)-dimensional equations—Burgers equation, cylindrical Burgers equation and spherical Burgers equation, have been reduced to the classical Burgers equation by different transformation of variables respecti... Three (2 + 1)-dimensional equations—Burgers equation, cylindrical Burgers equation and spherical Burgers equation, have been reduced to the classical Burgers equation by different transformation of variables respectively. The decay mode solutions of the Burgers equation have been obtained by using the extended -expansion method, substituting the solutions obtained into the corresponding transformation of variables, the decay mode solutions of the three (2 + 1)-dimensional equations have been obtained successfully. 展开更多
关键词 DECAY mode solution (2 %PLUS% 1)-Burgers EQUATION (2 %PLUS% 1)-Cylindrical BURGERS EQUATION (2 %PLUS% 1)-Spherical BURGERS EQUATION Transformation of Variables Extended (G'/G)-Expansion Method
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Biologically inspired silk fibroin grafted polyacrylonitrile filtration membrane prepared in ZnCl_2 aqueous solution 被引量:2
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作者 Jingang Li Shuwen Li +5 位作者 Xiaohui Wang Fan Fan Kongyin Zhao Junfu Wei Linhua Zhang Dunwan Zhu 《Chinese Chemical Letters》 SCIE CAS CSCD 2019年第1期239-242,共4页
In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion oc... In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion occurred when Zn^(2+)and Cl-ions gradually diffused into water, creating a well-connected ion channel network and the SF-g-PAN filtration membrane was obtained. The membranes were observed by SEM and 3D ultra-depth microscope. The hydrophilic property, pore size distribution and dye rejection of the membrane were investigated. Results showed that the membrane has no finger hole formation because ZnCl_2 aqueous solution has a lower curing rate parameter compared with organic solvents. SF-gPAN membrane possessed good anti-fouling properties and pH sensitivity. The pore size distribution of the SF-g-PAN membrane was 0.25–1.04 nm. The rejection of direct yellow 27(Mw = 662.6) and amaranth(Mw = 604.5) was 96.51% and 30.63%, with the flux of 72.32 L m^(-2) h^(-1) and 73.83 L m^(-2) h^(-1) respectively at0.1 MPa. The SF-g-PAN membrane has a wide range of applications prospect in fine separation, dye desalination, waste water treatment and biomedical fields. 展开更多
关键词 Biologically inspired MEMBRANE SILK grafted POLYACRYLONITRILE ZNCL2 aqueous solution Narrow pore size distribution PH-SENSITIVITY ANTI-FOULING
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Navigating the Blockchain Trilemma:A Review of Recent Advances and Emerging Solutions in Decentralization,Security,and Scalability Optimization
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作者 Saha Reno Koushik Roy 《Computers, Materials & Continua》 2025年第8期2061-2119,共59页
The blockchain trilemma—balancing decentralization,security,and scalability—remains a critical challenge in distributed ledger technology.Despite significant advancements,achieving all three attributes simultaneousl... The blockchain trilemma—balancing decentralization,security,and scalability—remains a critical challenge in distributed ledger technology.Despite significant advancements,achieving all three attributes simultaneously continues to elude most blockchain systems,often forcing trade-offs that limit their real-world applicability.This review paper synthesizes current research efforts aimed at resolving the trilemma,focusing on innovative consensus mechanisms,sharding techniques,layer-2 protocols,and hybrid architectural models.We critically analyze recent breakthroughs,including Directed Acyclic Graph(DAG)-based structures,cross-chain interoperability frameworks,and zero-knowledge proof(ZKP)enhancements,which aimto reconcile scalability with robust security and decentralization.Furthermore,we evaluate the trade-offs inherent in these approaches,highlighting their practical implications for enterprise adoption,decentralized finance(DeFi),and Web3 ecosystems.By mapping the evolving landscape of solutions,this review identifies gaps in currentmethodologies and proposes future research directions,such as adaptive consensus algorithms and artificial intelligence-driven(AI-driven)governance models.Our analysis underscores that while no universal solution exists,interdisciplinary innovations are progressively narrowing the trilemma’s constraints,paving the way for next-generation blockchain infrastructures. 展开更多
关键词 Blockchain trilemma SCALABILITY DECENTRALIZATION SECURITY consensus algorithms sharding layer-2 solutions DAG-based architectures cross-chain interoperability blockchain optimization
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Resonant multiple wave solutions to some integrable soliton equations
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作者 Jian-Gen Liu Xiao-Jun Yang Yi-Ying Feng 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第11期92-98,共7页
To transform the exponential traveling wave solutions to bilinear differential equations, a sufficient and necessary condition is proposed. Motivated by the condition, we extend the results to the(2+1)-dimensional Kad... To transform the exponential traveling wave solutions to bilinear differential equations, a sufficient and necessary condition is proposed. Motivated by the condition, we extend the results to the(2+1)-dimensional Kadomtsev–Petviashvili(KP) equation, the(3+1)-dimensional generalized Kadomtsev–Petviashvili(g-KP) equation, and the B-type Kadomtsev–Petviashvili(BKP) equation. Aa a result, we obtain some new resonant multiple wave solutions through the parameterization for wave numbers and frequencies via some linear combinations of exponential traveling waves. Finally, these new resonant type solutions can be displayed in graphs to illustrate the resonant behaviors of multiple wave solutions. 展开更多
关键词 linear superposition principle RESONANT MULTIPLE wave solutions (2%PLUS%1)-dimensional KadomtsevPetviashvili(KP) equation (3%PLUS%1)-dimensional g-KP and BKP equations
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Synthesis and Magnetic Properties of Mn/Fe/Co Binary Solid Solution in the A-site of V_(2)SnC-MAX Phases
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作者 YAN Ming DENG Yuxiao +2 位作者 YAN Zhuanlong LI Hongyu CAO Mengyang 《Journal of Wuhan University of Technology(Materials Science)》 2026年第2期353-363,共11页
This study reported the synthesis of magnetic solid solutions V2(A_(x)B_(y)Sn_(1-x-y))C(where A and B are Mn,Fe,or Co)MAX phases.These materials were prepared by incorporating magnetic elements into the V_(2)SnC MAX p... This study reported the synthesis of magnetic solid solutions V2(A_(x)B_(y)Sn_(1-x-y))C(where A and B are Mn,Fe,or Co)MAX phases.These materials were prepared by incorporating magnetic elements into the V_(2)SnC MAX phase via pressure-less sintering at 1000℃for 3 hours.XRD analysis reveals that the composition with x=y=0.2 exhibits a shift of diffraction peaks to higher angles,indicating lattice parameter changes,and achieves the highest phase purity with the maximum solid solution limit,further increases in the dopant content led to the formation of impurities.While the solid solution of magnetic elements preserves the characteristic layered structure of the MAX phase,it successfully induces magnetic properties.The magnetic transition temperatures for these solid solutions ranges from 61 to 200 K.Specifically,V_(2)(Mn_(x)Co_(y)Sn_(1-x-y))C demonstrated hard magnetic characteristics,with a high saturation magnetization(6.536 emu/g)and large remanence(4.236 emu/g).In contrast,V_(2)(Mn_(x)Fe_(y)Sn_(1-x-y))C and V2(Fe_(x)Co_(y)Sn_(1-x-y))C exhibits soft magnetic behavior,evidenced by their narrow hysteresis loops and low coercivity.Their saturation magnetization values are 3.80 and 1.784 emu/g,respectively.The distinctly"S"-shaped hysteresis loop of V_(2)(Fe_(x)Co_(y)Sn_(1-x-y))C further confirms its soft magnetic nature. 展开更多
关键词 V2SnC solid solution pressure less sintering magnetic MAX phase density functional theory
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The Periodic Solitary Wave Solutions for the (2 + 1)-Dimensional Fifth-Order KdV Equation
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作者 Xianghua Meng 《Journal of Applied Mathematics and Physics》 2014年第7期639-643,共5页
The (2 + 1)-dimensional fifth-order KdV equation is an important higher-dimensional and higher-order extension of the famous KdV equation in fluid dynamics. In this paper, by constructing new test functions, we invest... The (2 + 1)-dimensional fifth-order KdV equation is an important higher-dimensional and higher-order extension of the famous KdV equation in fluid dynamics. In this paper, by constructing new test functions, we investigate the periodic solitary wave solutions for the (2 + 1)-dimensional fifth-order KdV equation by virtue of the Hirota bilinear form. Several novel analytic solutions for such a model are obtained and verified with the help of symbolic computation. 展开更多
关键词 (2 %PLUS% 1)-Dimensional Fifth-Order KDV Equation Periodic SOLITARY Wave solutions HIROTA BILINEAR Form
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Mn^(2+)对聚N鄄异丙基丙烯酰胺的性能影响 被引量:4
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作者 郭绍芬 陈明清 +2 位作者 陆天虹 周青 黄晓华 《无机化学学报》 SCIE CAS CSCD 北大核心 2005年第5期633-637,共5页
合成了聚N鄄异丙基丙烯酰胺(PNIPAM)与Mn2+的配合物,并用荧光光谱、UV鄄Vis、FTIR、XPS进行了初步表征。说明Mn2+与PNIPAM侧链羰基氧或亚氨基氮原子发生了配位作用。由于Mn2+的发射光谱与PNIPAM激发光谱部分重叠以及Mn2+位于561nm的发... 合成了聚N鄄异丙基丙烯酰胺(PNIPAM)与Mn2+的配合物,并用荧光光谱、UV鄄Vis、FTIR、XPS进行了初步表征。说明Mn2+与PNIPAM侧链羰基氧或亚氨基氮原子发生了配位作用。由于Mn2+的发射光谱与PNIPAM激发光谱部分重叠以及Mn2+位于561nm的发射峰在Mn2+鄄PNIPAM体系发射光谱中消失,说明发生了较好的F觟rster能量传递。因此,在307nm紫外区荧光强度比PNIPAM增强了314%,使该配合物表现出较好的抑菌效果,而此时少量Mn2+对其低临界溶解温度(LCST)影响不大。 展开更多
关键词 MN^2%PLUS% N- PNIPAM VIS XPS
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Tailoring oxygen vacancies in Ni-doped In_(2)O_(3) for improved thin-film transistor stability and performance via solution processing
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作者 Fakhari Alam Sara Ajmal +3 位作者 Muhammad Asim Shahzad Ghulam Dastgeer Aamir Rasheed Gang He 《Journal of Semiconductors》 2026年第2期61-71,共11页
Doping in thin-film transistors(TFTs) plays a crucial role in tailoring material properties to enhance device performance, making them essential for advanced electronic applications. This study explores the synthesis ... Doping in thin-film transistors(TFTs) plays a crucial role in tailoring material properties to enhance device performance, making them essential for advanced electronic applications. This study explores the synthesis and characterization of TFTs fabricated using nickel(Ni)-doped indium oxide(In_(2)O_(3)) via a wet-chemical approach. The presented work investigates the effect of "Ni" incorporation in In_(2)O_(3) on the structural and electrical transport properties of In_(2)O_(3), revealing that higher "Ni" content decreases the oxygen vacancies, leading to a reduction in leakage current and a forward shift in threshold potential(V_(th)).Experimental findings reveal that Ni In O-based TFTs(with Ni = 0.5%) showcase enhanced electrical performance, achieving mobility of 7.54 cm^(2)/(V·s), an impressive ON/OFF current ratio of ~10^(7), a V_(th) of 6.26 V, reduced interfacial trap states(D_(it)) of 8.23 ×10^(12) cm^(-2) and enhanced biased stress stability. The efficacy of "Ni" incorporation is attributed to the upgraded Lewis acidity, stable Ni-O bond strength, and small ionic radius of Ni. Negative bias illumination stability(NBIS) measurements further indicate that device stability diminishes with shorter light wavelengths, likely due to the activation of oxygen vacancies. These findings validate the solution-processed techniques' potential for future large-scale, low-cost, energy-efficient, and high-performance electronics. 展开更多
关键词 thin-film transistors Ni-doped In_(2)O_(3) solution processing bias illumination stability
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Hydrogen Permeation Behaviors of X52 Pipeline Steel in NACE A Solution with Saturated H_2S/CO_2
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作者 张智 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第4期657-661,共5页
With the aid of hydrogen permeating devices, the hydrogen permeation behaviors of X52 pipeline steel in NACE A solution with saturated H2S/CO2 were studied under the conditions of different ambient temperatures and pH... With the aid of hydrogen permeating devices, the hydrogen permeation behaviors of X52 pipeline steel in NACE A solution with saturated H2S/CO2 were studied under the conditions of different ambient temperatures and pH values, and the hydrogen permeation behaviors of X52 pipeline steel in weld seam zone were comparatively studied. The experimental results show that the hydrogen permeation coefficient value is directly proportional to the time required for reaching the saturation anode current and inversely proportional to the saturation anode current, and the hydrogen permeation coefficient is influenced by the corrosion scales; the temperature is directly proportional to the saturation anode current, and the hydrogen permeation coefficient is influenced by the temperature and corrosion scales, heat-affected zone and matrix zone in NACE A solution with saturated H2S/CO2 at normal temperature. The hydrogen permeation coefficient in weld seam zone is larger than that in heat-affected zone which is further larger than that in matrix zone. 展开更多
关键词 pH value temperature NACE A solution H2S/co2 environment weld seam pipeline steel hydrogen permeation
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Solutions of the nonlocal(2+1)-D breaking solitons hierarchy and the negative order AKNS hierarchy 被引量:1
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作者 Jing Wang Hua Wu Da-jun Zhang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2020年第4期11-22,共12页
The(2+1)-dimensional nonlocal breaking solitons AKNS hierarchy and the nonlocal negative order AKNS hierarchy are presented.Solutions in double Wronskian form of these two hierarchies are derived by means of a reducti... The(2+1)-dimensional nonlocal breaking solitons AKNS hierarchy and the nonlocal negative order AKNS hierarchy are presented.Solutions in double Wronskian form of these two hierarchies are derived by means of a reduction technique from those of the unreduced hierarchies.The advantage of our method is that we start from the known solutions of the unreduced bilinear equations,and obtain solitons and multiple-pole solutions for the variety of classical and nonlocal reductions.Dynamical behaviors of some obtained solutions are illustrated.It is remarkable that for some real nonlocal equations,amplitudes of solutions are related to the independent variables that are reversed in the real nonlocal reductions. 展开更多
关键词 NONLOCAL (2%PLUS%1)-dimensional BREAKING SOLITONS AKNS HIERARCHY NEGATIVE order AKNS HIERARCHY double Wronskian solutions reduction
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Ion Mobility in the Fluorite Solid Solutions 50PbF<sub>2</sub>–30BiF<sub>3</sub>–20K(Na)F According to <sup>19</sup>F, <sup>23</sup>Na NMR Data
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作者 V.Ya. Kavun A.B. Slobodyuk +4 位作者 I.A. Telin R.M. Yaroshenko I.G. Maslennikova V.K. Goncharuk V.I. Kharchenko 《Advances in Materials Physics and Chemistry》 2012年第4期71-73,共3页
Ion mobility in solid solutions of the fluorite structure 50Pb2–30BiF3–20KF (I) and 50Pb2–30BiF3–20NaF (II) was studied by NMR method. Analysis of 19F, 23Na NMR spectra made it possible to reveal the character of ... Ion mobility in solid solutions of the fluorite structure 50Pb2–30BiF3–20KF (I) and 50Pb2–30BiF3–20NaF (II) was studied by NMR method. Analysis of 19F, 23Na NMR spectra made it possible to reveal the character of ion motions in the fluoride and sodium sublattices with temperature variation, to determine the types and temperature ranges in which they took place. It was found that the dominant form of ionic mobility in the samples I and II above 380 K was the diffusion of fluoride and sodium ions. According to preliminary results of electro-physical studies, the conductivity reached values of ~ 2×10–2 – 10–3 S/cm above 500 K. The solid solutions I and II can be recommended as a basis for use in the development of new functional materials. 展开更多
关键词 Solid solutions 50PbF230BiF320K(Na)F Ion Mobility IONIC Conductivity 19F 23Na NMR spectra functional materials
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Soliton molecules and mixed solutions of the(2+1)-dimensional bidirectional Sawada-Kotera equation 被引量:1
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作者 Jiao-Jiao Dong Biao Li Manwai Yuen 《Communications in Theoretical Physics》 SCIE CAS CSCD 2020年第2期9-16,共8页
In this paper,we investigate some new interesting solution structures of the(2+1)-dimensional bidirectional Sawada–Kotera(bSK)equation.We obtain soliton molecules by introducing velocity resonance.On the basis of sol... In this paper,we investigate some new interesting solution structures of the(2+1)-dimensional bidirectional Sawada–Kotera(bSK)equation.We obtain soliton molecules by introducing velocity resonance.On the basis of soliton molecules,asymmetric solitons are obtained by changing the distance between two solitons of molecules.Based on the N-soliton solutions,several novel types of mixed solutions are generated,which include the mixed breather-soliton molecule solution by the module resonance of the wave number and partial velocity resonance,the mixed lump-soliton molecule solution obtained by partial velocity resonance and partial long wave limits,and the mixed solutions composed of soliton molecules(asymmetric solitons),lump waves,and breather waves.Some plots are presented to clearly illustrate the dynamic features of these solutions. 展开更多
关键词 (2%PLUS%1)-dimensional bSK EQUATION velocity resonance SOLITON MOLECULES asymmetric solitons MIXED solutionS
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Exact solutions of a(2+1)-dimensional extended shallow water wave equation 被引量:1
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作者 Feng Yuan Jing-Song He Yi Cheng 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第10期237-244,共8页
We give the bilinear form and n-soliton solutions of a(2+1)-dimensional [(2+1)-D] extended shallow water wave(eSWW) equation associated with two functions v and r by using Hirota bilinear method. We provide soli... We give the bilinear form and n-soliton solutions of a(2+1)-dimensional [(2+1)-D] extended shallow water wave(eSWW) equation associated with two functions v and r by using Hirota bilinear method. We provide solitons, breathers,and hybrid solutions of them. Four cases of a crucial φ(y), which is an arbitrary real continuous function appeared in f of bilinear form, are selected by using Jacobi elliptic functions, which yield a periodic solution and three kinds of doubly localized dormion-type solution. The first order Jacobi-type solution travels parallelly along the x axis with the velocity(3k12+ α, 0) on(x, y)-plane. If φ(y) = sn(y, 3/10), it is a periodic solution. If φ(y) = cn(y, 1), it is a dormion-type-Ⅰ solutions which has a maximum(3/4)k1p1 and a minimum-(3/4)k1p1. The width of the contour line is ln■. If φ(y) = sn(y, 1), we get a dormion-type-Ⅱ solution(26) which has only one extreme value-(3/2)k1p1. The width of the contour line is ln■. If φ(y) = sn(y, 1/2)/(1 + y2), we get a dormion-type-Ⅲ solution(21) which shows very strong doubly localized feature on(x, y) plane. Moreover, several interesting patterns of the mixture of periodic and localized solutions are also given in graphic way. 展开更多
关键词 (2%PLUS%1)-dimensional EXTENDED shallow water wave equation HIROTA BILINEAR method dormion-type solution
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Periodic Solitary Wave Solutions of the (2 + 1)-Dimensional Variable-Coefficient Caudrey-Dodd-Gibbon-Kotera-Sawada Equation 被引量:2
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作者 Yang Zhou 《Open Journal of Applied Sciences》 2020年第3期60-68,共9页
In this paper, through symbolic computations, we obtain two exact solitary wave solitons of the (2 + l)-dimensional variable-coefficient Caudrey-Dodd- Gibbon-Kotera-Sawada equation. We study basic properties of l-peri... In this paper, through symbolic computations, we obtain two exact solitary wave solitons of the (2 + l)-dimensional variable-coefficient Caudrey-Dodd- Gibbon-Kotera-Sawada equation. We study basic properties of l-periodic solitary wave solution and interactional properties of 2-periodic solitary wave solution by using asymptotic analysis. 展开更多
关键词 (2 %PLUS% l)-Dimensional vc-CDGKS EQUATION SOLITARY WAVE solution Period-ic SOLITARY WAVE solution Asymptotic Analysis
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Doping of Ceria-Zirconia Solid Solution with Rare-earth Elements
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作者 HU Yu-cai FENG Chang-gen WANG Li-qiong WANG Ya-jun 《合成化学》 CAS CSCD 2004年第z1期136-136,共1页
关键词 CERIA-ZIRCONIA SOLID solution doping Ce0.6Zr0.3M0.1O2 (M=Y La Pr Tb) three- WAY CATALYST
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New Strategy for Chemically Attachment of Imine Group on Multi-Walled Carbon Nanotubes Surfaces: Synthesis, Characterization and Study of DC Electrical Conductivity
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作者 Omar Al-Shuja’a Abeer Obeid +2 位作者 Yousuf El-Shekeil Mohamed Hashim Zinab Al-Washali 《Journal of Materials Science and Chemical Engineering》 2017年第2期11-21,共11页
This paper used a new approach of preparing poly-composites by covalent linkage between the MWCNT’s by imine group. The Poly (Imine)/MWCNT Composite was synthesized by the solution blending method from reacted amino ... This paper used a new approach of preparing poly-composites by covalent linkage between the MWCNT’s by imine group. The Poly (Imine)/MWCNT Composite was synthesized by the solution blending method from reacted amino multi-walled carbon nanotubes (MWCNT-NH2) with Terephthalaldehyde (TPAL). The obtained poly-composite was characterized by FT-IR, UV-Vis, XRD, TEM, SEM, TGA, DSC and DC electrical conductivity. The formation of Poly (Imine)/MWCNT composite was confirmed. The DC electrical conductivity of poly-composites was within the range 2.3 × 10–4 - 5.3 × 10–4 S/cm due to the interaction between the nanotubes. 展开更多
关键词 Amino Multi-Walled Carbon Nanotubes (MWCNT-NH2) Polymer Nanocomposites FUNCTIONALIZATION solution Blending IMINE Terephthalaldehyde FTIR SEM TEM XRD UV DSC TGA and DC Electrical Conductivity
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添加水蒸气对CH_4-CO_2重整催化剂Ni/CeO_2-ZrO_2-Al_2O_3中Ni组分结构影响的EXAFS研究 被引量:3
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作者 李春林 伏义路 +4 位作者 孟明 卞国柱 谢亚宁 胡天斗 张静 《核技术》 CAS CSCD 北大核心 2002年第10期879-882,共4页
采用水热合成法制备了Ni/CeO2 -ZrO2 -Al2 O3催化剂。进行了添加和不添加水蒸气的CH4 -CO2 催化重整反应 ,测量了积碳量 ,并用EXAFS手段测试了催化剂Ni的K吸收边。结果表明 ,反应前后最近邻Ni-Ni配位距离无明显变化 ,而配位数却变化明... 采用水热合成法制备了Ni/CeO2 -ZrO2 -Al2 O3催化剂。进行了添加和不添加水蒸气的CH4 -CO2 催化重整反应 ,测量了积碳量 ,并用EXAFS手段测试了催化剂Ni的K吸收边。结果表明 ,反应前后最近邻Ni-Ni配位距离无明显变化 ,而配位数却变化明显。无水蒸气反应后Ni-Ni配位数有较大幅度的减少 ;而添加了水蒸气 ,Ni-Ni配位数比反应前减少幅度小。水蒸气的添加能减少积碳量 ,稳定催化剂中Ni的结构 。 展开更多
关键词 CH4 co2 CEO2 ZRO2 Al2O3 Ni EXAFS
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补肾止颤方对帕金森病模型大鼠多巴胺能神经元铁死亡及Nrf2调控SLC7A11/GSH/GPX4信号通路的影响
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作者 胡玉英 陈伟营 +3 位作者 宋曦 黎晓东 刘姗姗 罗智慧 《中医杂志》 北大核心 2026年第2期188-195,共8页
目的从铁死亡角度探讨补肾止颤方治疗帕金森病(PD)的可能作用机制。方法70只SD大鼠随机分为对照组、模型组、核转录因子E2相关因子2(Nrf2)抑制剂组、多巴丝肼组及补肾止颤方低、中、高剂量组,每组10只。除对照组外,其余各组大鼠采用蛋... 目的从铁死亡角度探讨补肾止颤方治疗帕金森病(PD)的可能作用机制。方法70只SD大鼠随机分为对照组、模型组、核转录因子E2相关因子2(Nrf2)抑制剂组、多巴丝肼组及补肾止颤方低、中、高剂量组,每组10只。除对照组外,其余各组大鼠采用蛋白酶抑制因子皮下注射建立PD大鼠模型。造模2周后,Nrf2抑制剂组大鼠予ML385小分子化合物50 mg/kg腹腔注射,隔日1次,共3次,其余各组大鼠于同时间点予2 ml/kg生理盐水腹腔注射。造模4周后,补肾止颤方低、中、高剂量组分别给予补肾止颤方颗粒剂溶液1.0、1.5、2.0 ml/(100 g·d)灌胃,多巴丝肼组则予多巴丝肼片200 mg/(100 g·d)灌胃,对照组、模型组、Nrf2抑制剂组大鼠均以生理盐水按2.0 ml/(100 g·d)灌胃。各组大鼠灌胃3周后,采用网格实验、爬杆实验进行行为学检测,对PD大鼠的运动功能进行评估;采用qRT-PCR法检测大鼠中脑黑质Nrf2 mRNA表达,Western Blot法检测Nrf2、溶质载体家族7成员(SLC7A11)、谷胱甘肽过氧化物酶4(GPX4)蛋白水平,ELISA法检测谷胱甘肽(GSH)、丙二醛(MDA)含量、亚铁离子(Fe^(2+))、GPX4含量,荧光酶标仪检测活性氧(ROS)水平。结果与对照组比较,模型组大鼠网格实验移动潜伏期、爬杆时间均增加,中脑黑质区GSH、GPX4含量降低,Fe^(2+)、MDA含量升高,Nrf2、SLC7A11、GPX4蛋白水平均降低,ROS水平升高,Nrf2 mRNA表达下降(P<0.05);Nrf2抑制剂组上述各指标与模型组变化趋势相同,且程度较模型组更显著,与模型组、对照组比较差异均有统计学意义(P<0.05)。与模型组比较,多巴丝肼组和补肾止颤方低、中、高各剂量组各指标均改善(P<0.05),且补肾止颤方高剂量组和多巴丝肼组各指标均较补肾止颤方低、中剂量组改善更为显著(P<0.05);补肾止颤方高剂量组和多巴丝肼组改善情况差异均无统计学意义(P>0.05)。结论补肾止颤方可能通过激活中脑黑质Nrf2表达,调控SLC7A11/GSH/GPX4信号通路,从而抑制脂质过氧化和铁死亡,达到治疗PD的目的。 展开更多
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