Given the considerable global interest in the preparation of Ti and TiC,a novel reduction method for TiO_(2) in a CH_(4)-H_(2) atmosphere was proposed,and the reduction thermodynamic behavior,phase equilibrium,and ene...Given the considerable global interest in the preparation of Ti and TiC,a novel reduction method for TiO_(2) in a CH_(4)-H_(2) atmosphere was proposed,and the reduction thermodynamic behavior,phase equilibrium,and energy consumption of TiO_(2) during its reaction with a CH_(4)-H_(2) gas mixture were investigated.The results indicate that the reaction proceeds via a stepwise reduction pathway from TiO_(2) to Ti(C,O),with the Magnéli phase(TinO_(2n-1))and Ti_(3)O_(5) serving as intermediate phases.Notably,the reduction of TiO_(2) by H_(2) is more challenging than that by CH_(4),which may be attributed to the inhibitory effect of H_(2) on the surface carbon precipitation.For the complete carbonization of 1 mol TiO_(2),the total energy required at 1000,1100,and 1200℃is 1159,925,and 977 kJ/mol,respectively,which may be related to the shift of gas-phase equilibrium and the increase in side reactions at high temperatures.展开更多
针对X-Y平台中模型误差和扰动未知等问题,本文以夹胶玻璃自动切膜为应用背景,设计自动切膜恒力控制系统,并对系统中的交互力进行分析与建模。提出了一种改进线性自抗扰(linear active disturbance rejection controller,LADRC)力控制器...针对X-Y平台中模型误差和扰动未知等问题,本文以夹胶玻璃自动切膜为应用背景,设计自动切膜恒力控制系统,并对系统中的交互力进行分析与建模。提出了一种改进线性自抗扰(linear active disturbance rejection controller,LADRC)力控制器,将滑模控制嵌入到基于预报的线性跟踪微分器(tracking differentiator,TD)中,平衡滤波与相位滞后间的矛盾,利用分数阶比例微分(fractional order proportion differentiation,FOPD)快速响应跟踪力误差,并通过Lyapunov函数对改进线性跟踪微分器进行稳定性证明。通过与线性自抗扰进行比较,对所设计的控制器进行了仿真分析与实验验证。实验结果表明,当玻璃位置等参数发生变化时,基于改进跟踪微分器的线性自抗扰控制系统仍能较好地实现对切刀的交互力控制,有效保证切膜效果,证明了提出方法的有效性与实用性。展开更多
文摘Given the considerable global interest in the preparation of Ti and TiC,a novel reduction method for TiO_(2) in a CH_(4)-H_(2) atmosphere was proposed,and the reduction thermodynamic behavior,phase equilibrium,and energy consumption of TiO_(2) during its reaction with a CH_(4)-H_(2) gas mixture were investigated.The results indicate that the reaction proceeds via a stepwise reduction pathway from TiO_(2) to Ti(C,O),with the Magnéli phase(TinO_(2n-1))and Ti_(3)O_(5) serving as intermediate phases.Notably,the reduction of TiO_(2) by H_(2) is more challenging than that by CH_(4),which may be attributed to the inhibitory effect of H_(2) on the surface carbon precipitation.For the complete carbonization of 1 mol TiO_(2),the total energy required at 1000,1100,and 1200℃is 1159,925,and 977 kJ/mol,respectively,which may be related to the shift of gas-phase equilibrium and the increase in side reactions at high temperatures.
文摘针对X-Y平台中模型误差和扰动未知等问题,本文以夹胶玻璃自动切膜为应用背景,设计自动切膜恒力控制系统,并对系统中的交互力进行分析与建模。提出了一种改进线性自抗扰(linear active disturbance rejection controller,LADRC)力控制器,将滑模控制嵌入到基于预报的线性跟踪微分器(tracking differentiator,TD)中,平衡滤波与相位滞后间的矛盾,利用分数阶比例微分(fractional order proportion differentiation,FOPD)快速响应跟踪力误差,并通过Lyapunov函数对改进线性跟踪微分器进行稳定性证明。通过与线性自抗扰进行比较,对所设计的控制器进行了仿真分析与实验验证。实验结果表明,当玻璃位置等参数发生变化时,基于改进跟踪微分器的线性自抗扰控制系统仍能较好地实现对切刀的交互力控制,有效保证切膜效果,证明了提出方法的有效性与实用性。
