The effects of the concentration of dissolved total organic carbon (TOC), the TOC/Br- ratio, bromide ion levels, the chlorine to ammonia-N ratio (Cl:N), the monochloramine dose and the chlorine dose on the formation o...The effects of the concentration of dissolved total organic carbon (TOC), the TOC/Br- ratio, bromide ion levels, the chlorine to ammonia-N ratio (Cl:N), the monochloramine dose and the chlorine dose on the formation of trihalomethanes (THMs) (including chloroform, bromodichloromethane, chlorodibromomethane, and bromoform) from chlorination were investigated using aqueous humic acid (HA) solutions. The profile of the chloramine decay was also studied under various bromide ion concentrations. Monochloramine decayed in the presence of organic material and bromide ions. The percentage of chloroform and brominated THMs varied according to the TOC/Br- ratio. Total THMs (TTHMs) formation increased from 112 to 190 μg/L with the increase concentrations of bromide ions from 0.67 to 6.72 mg/L, but the chlorine-substituted THMs were replaced by bromine-substituted THMs. A strong linear correlation was obtained between the monochloramine dose and the formation of THMs for Cl:N ratios of 3:1 and 5:1. These ratios had a distinct effect on the formation of chloroform but had little impact on the formation of bromodichloromethane or chlorodibromomethane. The presence of bromide ions increased the rate of monochloramine decay.展开更多
The variation of water quality in water distribution system was investigated with assimilable organic carbon (AOC)and trihalomethanes(THMs) used as assessment indexes. Bacterium was identified in water distribution. T...The variation of water quality in water distribution system was investigated with assimilable organic carbon (AOC)and trihalomethanes(THMs) used as assessment indexes. Bacterium was identified in water distribution. The result showed that there were pathogenic parasites in water distribution system. The variation of AOC is related to chlorine residual and bacterium activity, and AOC concentration decreased first and then increased with the extension of water distribution system. The formation of THMs was related to the consumption of chlorine inside the distribution system, and THMs concentration increased with the extension of water pipe line.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 50878164)the Key Special Program on the S & T for the Pollution Control and Treatment of Water Bodies (No. 2008ZX07-422-005)+1 种基金the Research Fund for the Doctoral Program of Higher Education of China (No. 200802471037)the Foundation of Key Laboratory of Yangtze River Water Environment, Ministry of Edu-cation, Tongji University (No. YRWEY1001), China
文摘The effects of the concentration of dissolved total organic carbon (TOC), the TOC/Br- ratio, bromide ion levels, the chlorine to ammonia-N ratio (Cl:N), the monochloramine dose and the chlorine dose on the formation of trihalomethanes (THMs) (including chloroform, bromodichloromethane, chlorodibromomethane, and bromoform) from chlorination were investigated using aqueous humic acid (HA) solutions. The profile of the chloramine decay was also studied under various bromide ion concentrations. Monochloramine decayed in the presence of organic material and bromide ions. The percentage of chloroform and brominated THMs varied according to the TOC/Br- ratio. Total THMs (TTHMs) formation increased from 112 to 190 μg/L with the increase concentrations of bromide ions from 0.67 to 6.72 mg/L, but the chlorine-substituted THMs were replaced by bromine-substituted THMs. A strong linear correlation was obtained between the monochloramine dose and the formation of THMs for Cl:N ratios of 3:1 and 5:1. These ratios had a distinct effect on the formation of chloroform but had little impact on the formation of bromodichloromethane or chlorodibromomethane. The presence of bromide ions increased the rate of monochloramine decay.
文摘The variation of water quality in water distribution system was investigated with assimilable organic carbon (AOC)and trihalomethanes(THMs) used as assessment indexes. Bacterium was identified in water distribution. The result showed that there were pathogenic parasites in water distribution system. The variation of AOC is related to chlorine residual and bacterium activity, and AOC concentration decreased first and then increased with the extension of water distribution system. The formation of THMs was related to the consumption of chlorine inside the distribution system, and THMs concentration increased with the extension of water pipe line.
