[Objectives]To analyze the current status of heavy metal contamination in soils of vegetable cultivation bases located in Huichuan District,Zunyi City.[Methods]Soil samples from various depths within the vegetable cul...[Objectives]To analyze the current status of heavy metal contamination in soils of vegetable cultivation bases located in Huichuan District,Zunyi City.[Methods]Soil samples from various depths within the vegetable cultivation bases of Guanba Village,Sidu Village,and Banqiao Village in Huichuan District,Zunyi City,were selected as the subjects of this study.The concentrations of five heavy metals,including lead(Pb),mercury(Hg),cadmium(Cd),arsenic(As),and chromium(Cr),were measured at different soil depths.The Nemerow comprehensive pollution index method was employed to assess heavy metal contamination,and the analysis was conducted in accordance with the farmland environmental quality evaluation standards for edible agricultural products.[Results]The concentrations of Cd and As at the sample collection sites were relatively elevated.The pollution level of Cd reached grade III or above,indicating moderate contamination in certain topsoil areas.Most As concentrations corresponded to grade II and grade III pollution levels.In contrast,Hg,Pb,and Cr concentrations remained within the safety standards established for agricultural products.However,Cd and As levels predominantly surpassed these safety thresholds.Notably,Guanba Village and Sidu Village exhibited significant pollution levels,warranting comprehensive investigations into the sources of contamination.[Conclusions]This study offers valuable insights for advancing the sustainable development of local agriculture and for the prevention and management of soil contamination.展开更多
为合理评价污染场地风险,以我国云南省某铜堆浸场下游农田土为例,测定土壤中Cu、Pb、Cd和As等4种重金属总量,采用改进BCR(Bureau of European Communities Reference)连续提取法测定4种重金属赋存形态,分析4种重金属间的相关性,并使用...为合理评价污染场地风险,以我国云南省某铜堆浸场下游农田土为例,测定土壤中Cu、Pb、Cd和As等4种重金属总量,采用改进BCR(Bureau of European Communities Reference)连续提取法测定4种重金属赋存形态,分析4种重金属间的相关性,并使用地累积指数法、次生相与原生相比值法(RSP)和风险评价编码法(RAC)对场地土壤重金属污染和潜在风险程度进行评价。结果发现,重金属Cu、Pb、Cd和As平均的含量分别为39.50、46.98、0.16、82.67mg⋅kg^(-1),较云南省重金属背景值,4种重金属超标率分别为0、83.33%、33.33%和100.00%,其中As污染需要特别关注;提取重金属赋存形态结果显示,土样中Cu、Pb、Cd和As均以残渣态为主,占比为83.14%~95.62%,表明4种重金属均以稳定形态存在于土体中;对比3种评价方法,评价结果存在明显差异,地累积指数Igeo结果显示土壤仅As存在污染超标现象,其余3种重金属均无污染,次生相与原生相比值法结果显示,4种重金属对环境均无污染,而风险评价编码法结果显示,Cd对土壤环境存在低风险,其余3种重金属则无风险。对比发现,仅以污染场地土壤重金属总量作为评价指标会一定程度夸大污染风险,应综合重金属总量及赋存形态含量进行分析。虽然重金属元素污染总量较高,但活跃性重金属含量非常低,向环境中扩散的风险也非常低。因此,研究区重金属污染程度较轻,潜在生态风险为低风险。展开更多
基金Supported by Undergraduate Innovation and Entrepreneurship Training Program of Guizhou Province(2024106640823)Natural Science Research Project of Guizhou Provincial Department of Education(QJJ[2023]043)Zunyi Science and Technology Innovation Team Project(ZKCTD008).
文摘[Objectives]To analyze the current status of heavy metal contamination in soils of vegetable cultivation bases located in Huichuan District,Zunyi City.[Methods]Soil samples from various depths within the vegetable cultivation bases of Guanba Village,Sidu Village,and Banqiao Village in Huichuan District,Zunyi City,were selected as the subjects of this study.The concentrations of five heavy metals,including lead(Pb),mercury(Hg),cadmium(Cd),arsenic(As),and chromium(Cr),were measured at different soil depths.The Nemerow comprehensive pollution index method was employed to assess heavy metal contamination,and the analysis was conducted in accordance with the farmland environmental quality evaluation standards for edible agricultural products.[Results]The concentrations of Cd and As at the sample collection sites were relatively elevated.The pollution level of Cd reached grade III or above,indicating moderate contamination in certain topsoil areas.Most As concentrations corresponded to grade II and grade III pollution levels.In contrast,Hg,Pb,and Cr concentrations remained within the safety standards established for agricultural products.However,Cd and As levels predominantly surpassed these safety thresholds.Notably,Guanba Village and Sidu Village exhibited significant pollution levels,warranting comprehensive investigations into the sources of contamination.[Conclusions]This study offers valuable insights for advancing the sustainable development of local agriculture and for the prevention and management of soil contamination.
文摘为合理评价污染场地风险,以我国云南省某铜堆浸场下游农田土为例,测定土壤中Cu、Pb、Cd和As等4种重金属总量,采用改进BCR(Bureau of European Communities Reference)连续提取法测定4种重金属赋存形态,分析4种重金属间的相关性,并使用地累积指数法、次生相与原生相比值法(RSP)和风险评价编码法(RAC)对场地土壤重金属污染和潜在风险程度进行评价。结果发现,重金属Cu、Pb、Cd和As平均的含量分别为39.50、46.98、0.16、82.67mg⋅kg^(-1),较云南省重金属背景值,4种重金属超标率分别为0、83.33%、33.33%和100.00%,其中As污染需要特别关注;提取重金属赋存形态结果显示,土样中Cu、Pb、Cd和As均以残渣态为主,占比为83.14%~95.62%,表明4种重金属均以稳定形态存在于土体中;对比3种评价方法,评价结果存在明显差异,地累积指数Igeo结果显示土壤仅As存在污染超标现象,其余3种重金属均无污染,次生相与原生相比值法结果显示,4种重金属对环境均无污染,而风险评价编码法结果显示,Cd对土壤环境存在低风险,其余3种重金属则无风险。对比发现,仅以污染场地土壤重金属总量作为评价指标会一定程度夸大污染风险,应综合重金属总量及赋存形态含量进行分析。虽然重金属元素污染总量较高,但活跃性重金属含量非常低,向环境中扩散的风险也非常低。因此,研究区重金属污染程度较轻,潜在生态风险为低风险。
