The complex of triadimenol(TOL) and copper chloride was synthesized in ethanol , and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to triclinic, space group , a=...The complex of triadimenol(TOL) and copper chloride was synthesized in ethanol , and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to triclinic, space group , a=0.9861(2)nm, b=1.1930(2)nm, c=1.7140(3)nm, α =71.53(3)° , β =81.94(3)° , γ =75.56(3)° , V=1.848(6)nm3, Z=1, Dc=1.295g· cm- 3, F(000)=755, R1=0.0692, wR2=0.1845. The results show that the coordination geometry around copper? in the complex is slightly distorted four coordinated square planar geometry. The title complex was also characterized by elementary analysis, IR and TG. CCDC: 210089.展开更多
文摘The complex of triadimenol(TOL) and copper chloride was synthesized in ethanol , and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to triclinic, space group , a=0.9861(2)nm, b=1.1930(2)nm, c=1.7140(3)nm, α =71.53(3)° , β =81.94(3)° , γ =75.56(3)° , V=1.848(6)nm3, Z=1, Dc=1.295g· cm- 3, F(000)=755, R1=0.0692, wR2=0.1845. The results show that the coordination geometry around copper? in the complex is slightly distorted four coordinated square planar geometry. The title complex was also characterized by elementary analysis, IR and TG. CCDC: 210089.
