以己二胺为原料利用界面反应制备了双氟酰胺单体1,6-N,N′-双(4-氟苯甲酰胺)己烷(BFBH),并与硫化钠、二氯二苯砜通过溶液缩聚制备了一系列新型半芳族聚酰胺共聚改性聚芳硫醚砜(Semi-PASS/A)树脂。通过核磁氢谱(1 H NMR)和红外光谱(FTIR...以己二胺为原料利用界面反应制备了双氟酰胺单体1,6-N,N′-双(4-氟苯甲酰胺)己烷(BFBH),并与硫化钠、二氯二苯砜通过溶液缩聚制备了一系列新型半芳族聚酰胺共聚改性聚芳硫醚砜(Semi-PASS/A)树脂。通过核磁氢谱(1 H NMR)和红外光谱(FTIR)表征了单体及聚合物的化学结构。结果表明,新型单体及聚合物成功制备。Semi-PASS/A树脂的特性黏度范围为0.43~0.55 dL/g,该共聚物具有优异的热性能,其玻璃化转变温度范围为202~215℃,5%热分解温度范围为396~429℃。玻璃化转变温度、热分解温度均随着聚合物中半芳族酰胺含量的增加而下降。平板流变结果表明,Semi-PASS/A的复数黏度相比于聚芳硫醚砜树脂(PASS)下降显著,PASS树脂的25470 Pa·s降低至Semi-PASS/A-10树脂(BFBH的摩尔分数为10%)的36.9 Pa·s。随着半芳族聚酰胺含量的增加,共聚物的复数黏度降低。此外,Semi-PASS/A树脂在高温(310℃)下的时间测试中,其熔体复数黏度随时间增加基本保持稳定,表明半芳族聚酰胺引入PASS树脂结构中不仅降低了聚合物的熔体黏度,同时还有效改善了PASS的熔体稳定性,极大地改善了PASS的熔体加工性能。展开更多
Poly(phenylene oxide)(PPO)exhibits excellent dielectric properties,making it an ideal substrate for high-frequency,high-speed copper-clad laminates.The phenolic hydroxyl group at the end of PPO plays a key role in its...Poly(phenylene oxide)(PPO)exhibits excellent dielectric properties,making it an ideal substrate for high-frequency,high-speed copper-clad laminates.The phenolic hydroxyl group at the end of PPO plays a key role in its reactivity.Accurately quantifying the phenolic hydroxyl content in PPO is essential but challenging.In this study,we proposed a method for measuring the phenolic hydroxyl content of PPO using differential UV absorption spectroscopy.In alkaline solutions,the phenolic hydroxyl in PPO completely ionizes to form phenoxide ions,leading to a significant increase in UV absorbance at approximately 250 and 300 nm.Notably,the differential UV absorbance at approximately 300 nm was directly proportional to the phenolic hydroxyl concentration.Using 2,6-dimethylphenol as a standard,a calibration curve was established to relate the phenolic hydroxyl concentration to differential UV absorbance at approximately 300 nm,providing a precise and straightforward method for phenolic hydroxyl quantification in PPO with distinct advantages over conventional techniques.展开更多
基金the“Pioneer”and“Leading Goose”R&D Program of Zhejiang(No.2023C01072)the Institute of Zhejiang University-Quzhou for their financial support。
文摘Poly(phenylene oxide)(PPO)exhibits excellent dielectric properties,making it an ideal substrate for high-frequency,high-speed copper-clad laminates.The phenolic hydroxyl group at the end of PPO plays a key role in its reactivity.Accurately quantifying the phenolic hydroxyl content in PPO is essential but challenging.In this study,we proposed a method for measuring the phenolic hydroxyl content of PPO using differential UV absorption spectroscopy.In alkaline solutions,the phenolic hydroxyl in PPO completely ionizes to form phenoxide ions,leading to a significant increase in UV absorbance at approximately 250 and 300 nm.Notably,the differential UV absorbance at approximately 300 nm was directly proportional to the phenolic hydroxyl concentration.Using 2,6-dimethylphenol as a standard,a calibration curve was established to relate the phenolic hydroxyl concentration to differential UV absorbance at approximately 300 nm,providing a precise and straightforward method for phenolic hydroxyl quantification in PPO with distinct advantages over conventional techniques.
