Because of the unique reactivity of sulfonyl fluoride(SO_(2)F)group,such compound has found increasing applications in the areas of organic synthesis,new drug development,pesticide,material science and click chemistry...Because of the unique reactivity of sulfonyl fluoride(SO_(2)F)group,such compound has found increasing applications in the areas of organic synthesis,new drug development,pesticide,material science and click chemistry,etc.It is of current interest to develop novel strategies and methods for the facile preparation of sulfonyl fluorides in a green and highly efficient manner[1,2].Although the traditional approach for the synthesis of sulfonyl fluorides relies on the nucleophilic substitution of fluoride atom with sulfonyl chlorides.展开更多
文摘Because of the unique reactivity of sulfonyl fluoride(SO_(2)F)group,such compound has found increasing applications in the areas of organic synthesis,new drug development,pesticide,material science and click chemistry,etc.It is of current interest to develop novel strategies and methods for the facile preparation of sulfonyl fluorides in a green and highly efficient manner[1,2].Although the traditional approach for the synthesis of sulfonyl fluorides relies on the nucleophilic substitution of fluoride atom with sulfonyl chlorides.