The atmospheric corrosion behavior of 510L low alloy steel subjected to acid-cleaned surface(ACS)and eco-pickled surface(EPS)treatments is systematically examined.After 1 year of atmospheric exposure,both ACS-and EPS-...The atmospheric corrosion behavior of 510L low alloy steel subjected to acid-cleaned surface(ACS)and eco-pickled surface(EPS)treatments is systematically examined.After 1 year of atmospheric exposure,both ACS-and EPS-treated samples demonstrate protective ability index values exceeding 2,indicating robust protective properties of the developed rust layers.The corrosion rates of ACS-and EPS-treated samples are similar.During the initial corrosion stage,γ-FeOOH emerges as the dominant corrosion product.With the prolonged atmospheric exposure,γ-FeOOH content progressively decreases through phase transformation into thermodynamically stableα-FeOOH and densely structured Fe_(3)O_(4),which markedly suppresses the corrosion of the steel.Notably,the corrosion rate of the coated EPS sample is obviously lower than that of the coated ACS counterpart,which is ascribed to the distinctive micro-roughness of EPS-treated surfaces that promote mechanical interlocking with protective coatings.展开更多
The atmospheric corrosion monitoring(ACM)technique has been widely employed to track the real-time corrosion behavior of metal materials.However,limited studies have applied ACM to the corrosion protection properties ...The atmospheric corrosion monitoring(ACM)technique has been widely employed to track the real-time corrosion behavior of metal materials.However,limited studies have applied ACM to the corrosion protection properties of organic coatings.This study compared a bare epoxy coating with one containing zinc phosphate corrosion inhibitors,both applied on ACM sensors,to observe their corrosion protection properties over time.Coatings with artificial damage via scratches were exposed to immersion and alternating dry and wet environments,which allowed for monitoring galvanic corrosion currents in real-time.Throughout the corrosion tests,the ACM currents of the zinc phosphate/epoxy coating were considerably lower than those of the blank epoxy coating.The trend in ACM current variations closely matched the results obtained from regular electrochemical tests and surface analysis.This alignment highlights the potential of the ACM technique in evaluating the corrosion protection capabilities of organic coatings.Compared with the blank epoxy coating,the zinc phosphate/epoxy coating showed much-decreased ACM current values that confirmed the effective inhibition of zinc phosphate against steel corrosion beneath the damaged coating.展开更多
基金support by National Natural Science Foundation of China(Grant No.52401103)Key Scientific Research Project in Shanxi Province(Grant No.202302050201015)+3 种基金Central Guiding Science and Technology Development of Local Fund(Grant No.YDZJSK20231A046)the Special Fund for Science and Technology Innovation Teams of Shanxi Province(202204051001004)Science and Technology Cooperation and Exchange Special Project of Shanxi Province(202404041101038)Postgraduate Education Innovation Project of Shanxi Province(Grant No.2024SJ304).
文摘The atmospheric corrosion behavior of 510L low alloy steel subjected to acid-cleaned surface(ACS)and eco-pickled surface(EPS)treatments is systematically examined.After 1 year of atmospheric exposure,both ACS-and EPS-treated samples demonstrate protective ability index values exceeding 2,indicating robust protective properties of the developed rust layers.The corrosion rates of ACS-and EPS-treated samples are similar.During the initial corrosion stage,γ-FeOOH emerges as the dominant corrosion product.With the prolonged atmospheric exposure,γ-FeOOH content progressively decreases through phase transformation into thermodynamically stableα-FeOOH and densely structured Fe_(3)O_(4),which markedly suppresses the corrosion of the steel.Notably,the corrosion rate of the coated EPS sample is obviously lower than that of the coated ACS counterpart,which is ascribed to the distinctive micro-roughness of EPS-treated surfaces that promote mechanical interlocking with protective coatings.
基金financially supported by the National Natural Science Foundation of China(No.52371049)the Young Elite Scientists Sponsorship Program by the China Association for Science and Technology(YESS,No.2020QNRC001)the National Science and Technology Resources Investigation Program of China(Nos.2021FY100603 and 2019FY101404)。
文摘The atmospheric corrosion monitoring(ACM)technique has been widely employed to track the real-time corrosion behavior of metal materials.However,limited studies have applied ACM to the corrosion protection properties of organic coatings.This study compared a bare epoxy coating with one containing zinc phosphate corrosion inhibitors,both applied on ACM sensors,to observe their corrosion protection properties over time.Coatings with artificial damage via scratches were exposed to immersion and alternating dry and wet environments,which allowed for monitoring galvanic corrosion currents in real-time.Throughout the corrosion tests,the ACM currents of the zinc phosphate/epoxy coating were considerably lower than those of the blank epoxy coating.The trend in ACM current variations closely matched the results obtained from regular electrochemical tests and surface analysis.This alignment highlights the potential of the ACM technique in evaluating the corrosion protection capabilities of organic coatings.Compared with the blank epoxy coating,the zinc phosphate/epoxy coating showed much-decreased ACM current values that confirmed the effective inhibition of zinc phosphate against steel corrosion beneath the damaged coating.
