The effect of antibacterial adhesive on the biological corrosion resistance of mortar in seawater environment was studied by means of scanning electron microscope,thermogravimetric analysis,X-ray diffraction,Fourier t...The effect of antibacterial adhesive on the biological corrosion resistance of mortar in seawater environment was studied by means of scanning electron microscope,thermogravimetric analysis,X-ray diffraction,Fourier transform infrared spectroscopy,and ultra-depth microscope.The results show that the antibacterial adhesive can effectively inhibit the growth of sulfur-oxidizing bacteria in seawater,hinder their metabolism to produce biological sulfate,and reduce the formation of destructive product gypsum.The mineral composition and thermal analysis showed that the peak value of plaster diffraction peak and the mass loss of plaster dehydration in antibacterial adhesive group were significantly lower than those in blank group(without protective coating group).In addition,the electric flux of chloride ions(>400 C)in the blank group of mortar samples was higher than that in the antibacterial adhesive group(<200 C),indicating that the antibacterial adhesive can effectively reduce the permeability of chloride ions in mortar,and thus hinder the Cl-erosion in seawater.展开更多
随着碳捕集、利用与封存(carbon capture,utilization and storage,CCUS)技术在油田的持续应用,CO_(2)腐蚀井下管柱现象引起高度重视,亟需适用于高CO_(2)分压环境下考虑腐蚀速率随时间变化影响的腐蚀速率模型。通过模拟温度80~120℃、CO...随着碳捕集、利用与封存(carbon capture,utilization and storage,CCUS)技术在油田的持续应用,CO_(2)腐蚀井下管柱现象引起高度重视,亟需适用于高CO_(2)分压环境下考虑腐蚀速率随时间变化影响的腐蚀速率模型。通过模拟温度80~120℃、CO_(2)分压15~30 MPa条件下Q125、3Cr和13Cr管材的腐蚀,建立了这3种管材考虑温度、CO_(2)分压和腐蚀时间影响的腐蚀速率预测模型,并对Q125套管进行了安全服役寿命预测。结果表明:同一CO_(2)分压下,Q125、3Cr管材腐蚀速率随温度增加呈先增后减的趋势,13Cr管材腐蚀速率随温度增加而增大;3种管材腐蚀速率均随CO_(2)分压增加而增大。Q125管材匀速和变速两种腐蚀速率模型均适用,3Cr和13Cr管材适用变速腐蚀模型。Q125套管的抗拉安全服役年限随着CO_(2)分压的增加而逐渐降低,抗拉安全服役年限最短约为12 a。展开更多
基金Funded by the National Natural Science Foundation of China(Nos.52278269,52278268,52178264)Tianjin Outstanding Young Scholars Science Fund Project(No.22JCJQJC00020)Key Project of Tianjin Natural Science Foundation(No.23JCZDJC00430)。
文摘The effect of antibacterial adhesive on the biological corrosion resistance of mortar in seawater environment was studied by means of scanning electron microscope,thermogravimetric analysis,X-ray diffraction,Fourier transform infrared spectroscopy,and ultra-depth microscope.The results show that the antibacterial adhesive can effectively inhibit the growth of sulfur-oxidizing bacteria in seawater,hinder their metabolism to produce biological sulfate,and reduce the formation of destructive product gypsum.The mineral composition and thermal analysis showed that the peak value of plaster diffraction peak and the mass loss of plaster dehydration in antibacterial adhesive group were significantly lower than those in blank group(without protective coating group).In addition,the electric flux of chloride ions(>400 C)in the blank group of mortar samples was higher than that in the antibacterial adhesive group(<200 C),indicating that the antibacterial adhesive can effectively reduce the permeability of chloride ions in mortar,and thus hinder the Cl-erosion in seawater.
