This study investigates the influence of hydrogen concentration at grain boundaries on the sensitivity of polycrystalline iron to hydrogen embrittlement using molecular dynamics simulations.These simulations reveal th...This study investigates the influence of hydrogen concentration at grain boundaries on the sensitivity of polycrystalline iron to hydrogen embrittlement using molecular dynamics simulations.These simulations reveal the diffusion behavior of hydrogen atoms at grain boundaries and their consequential impact on the hydrogen embrittlement sensitivity of iron alloys.The findings indicate that as the hydrogen concentration increases,both the yield strength and ultimate tensile strength of Fe-H alloys exhibit a declining trend.Moreover,the capture of hydrogen atoms at the grain boundaries significantly influences the fracture toughness of the material and promotes the formation and propagation of cracks.This study provides a novel theoretical basis for understanding and predicting the hydrogen embrittlement behavior of iron-based materials in hydrogen-rich environments,offering valuable insights for the design and development of Fe alloys with enhanced resistance to hydrogen embrittlement.展开更多
Biodegradable metals(BMs)have shown significant potential for applications in the field of orthopedic implants.These materials gradually degrade after implantation,eventually disappear without residue,provide necessar...Biodegradable metals(BMs)have shown significant potential for applications in the field of orthopedic implants.These materials gradually degrade after implantation,eventually disappear without residue,provide necessary mechanical support during degradation,and closely integrate with bone tissues.Fe-based BMs are particularly notable for their good mechanical properties and biocompatibility.However,their slow degradation rate is a limitation.The emergence of Mn-incorporated Fe-based alloys(Fe-Mn alloys)offers the possibilities for addressing issues of slow degradation rate and incompatibility of magnetic resonance imaging(MRI)for Fe alloys.This review summarizes the advantages of Fe-Mn alloys as orthopedic implants,and the cutting-edge advances in degradation,mechanical and magnetic properties,and osteogenic performance.The cytotoxicity issue is addressed for the porous structured Fe-Mn alloys caused by the enrichment of manganese ions,and thus the main challenge and the development are involved for the Fe-Mn alloys to achieve a balance among biocompatibility,structure,and degradation rate.Also the perspectives are proposed for Fe-Mn alloys as orthopedic implants.展开更多
基金supported by the National Science Fund for Distinguished Young Scholars(No.52425404).
文摘This study investigates the influence of hydrogen concentration at grain boundaries on the sensitivity of polycrystalline iron to hydrogen embrittlement using molecular dynamics simulations.These simulations reveal the diffusion behavior of hydrogen atoms at grain boundaries and their consequential impact on the hydrogen embrittlement sensitivity of iron alloys.The findings indicate that as the hydrogen concentration increases,both the yield strength and ultimate tensile strength of Fe-H alloys exhibit a declining trend.Moreover,the capture of hydrogen atoms at the grain boundaries significantly influences the fracture toughness of the material and promotes the formation and propagation of cracks.This study provides a novel theoretical basis for understanding and predicting the hydrogen embrittlement behavior of iron-based materials in hydrogen-rich environments,offering valuable insights for the design and development of Fe alloys with enhanced resistance to hydrogen embrittlement.
基金financially supported by the Shandong Province Natural Science Foundation(No.ZR2023ME181)the National Natural Science Foundation of China(No.52305313)the Natural Science Foundation of Hunan Province(Nos.2023JJ40553 and 2023JJ60433)。
文摘Biodegradable metals(BMs)have shown significant potential for applications in the field of orthopedic implants.These materials gradually degrade after implantation,eventually disappear without residue,provide necessary mechanical support during degradation,and closely integrate with bone tissues.Fe-based BMs are particularly notable for their good mechanical properties and biocompatibility.However,their slow degradation rate is a limitation.The emergence of Mn-incorporated Fe-based alloys(Fe-Mn alloys)offers the possibilities for addressing issues of slow degradation rate and incompatibility of magnetic resonance imaging(MRI)for Fe alloys.This review summarizes the advantages of Fe-Mn alloys as orthopedic implants,and the cutting-edge advances in degradation,mechanical and magnetic properties,and osteogenic performance.The cytotoxicity issue is addressed for the porous structured Fe-Mn alloys caused by the enrichment of manganese ions,and thus the main challenge and the development are involved for the Fe-Mn alloys to achieve a balance among biocompatibility,structure,and degradation rate.Also the perspectives are proposed for Fe-Mn alloys as orthopedic implants.
