A CFD-based numerical model was employed to quantitatively analyze the flow characteristics of double-side-blown gas−liquid flow.Key parameters were extracted,and Spearman correlation analysis was used to quantify the...A CFD-based numerical model was employed to quantitatively analyze the flow characteristics of double-side-blown gas−liquid flow.Key parameters were extracted,and Spearman correlation analysis was used to quantify the relationships among bubble behavior,circulating flow,and liquid oscillations.The results show that periodic bubble behavior under steady injection drives the circulating flow of the liquid on both sides.The asynchronism of bubble behavior on both sides results in the alternation of circulating intensity,which significantly enhances gas−liquid mixing efficiency at certain liquid levels of 200 and 220 mm.Flow patterns of the double-side-blown process are classified into weak circulation,strong−weak alternating circulation,and strong circulation modes based on the influence of circulating flows on the penetration depth.The penetration depth in the strong−weak alternating circulation mode is generally greater than that in the single-side-blown process.The imbalance of circulating intensities on both sides primarily leads to the stable fluctuation in the injecting direction,which reveals the appearance of periodic oscillations in the molten bath.The effect of control parameters such as liquid level and gas flow rate on the liquid oscillations were discussed.展开更多
In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics...In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics.Given copper's extensive industrial applications,sustainable recovery from low-grade ores is critical.Five key parameters-acid concentration,leaching time,particle size,temperature,and solids percentage-were identified as major influences on copper recovery.The results revealed that leaching time and solids percentage,along with interactions between temperature-time and temperature-solids percentage,had the most significant effects.Optimal conditions for 80% copper recovery while minimizing iron recovery below 3% included an acid concentration of 1.21 mol L^(-1),a leaching time of 108 min,a particle size of 438μm,a temperature of 45℃,and a solids percentage of 18.2%.Leaching kinetics were analyzed using shrinking core models,with the Dickinson model best describing the process,showing an activation energy of 32.63 kJ mol^(-1),indicative of mixed diffusion and chemical reaction control.The final kinetic model effectively predicted the influence of key parameters.These findings highlight the importance of optimizing process variables and selecting suitable kinetic models to enhance extraction efficiency,reduce costs,and improve sustainability in copper recovery.展开更多
A series of leaching and electrochemical experiments were conducted to elucidate the critical role of hydrogen sulfide(H_(2)S)in copper-driven reduction of chalcopyrite.Results demonstrate that in the absence of H_(2)...A series of leaching and electrochemical experiments were conducted to elucidate the critical role of hydrogen sulfide(H_(2)S)in copper-driven reduction of chalcopyrite.Results demonstrate that in the absence of H_(2)S,metallic copper converts chalcopyrite into bornite(Cu_(5)FeS_(4)).However,the introduction of H_(2)S promotes the formation of chalcocite(Cu_(2)S)by altering the oxidation pathway of copper.Electrochemical analysis demonstrates that the presence of H₂S significantly reduces the corrosion potential of copper from 0.251 to−0.223 V(vs SHE),reaching the threshold necessary for the formation of Cu_(2)S.Nevertheless,excessive H_(2)S triggers sulfate reduction via the reaction of 8Cu+H_(2)SO_(4)+3H_(2)S=4Cu_(2)S+4H_(2)O(ΔG=−519.429 kJ/mol at 50℃),leading to inefficient copper utilization.展开更多
基金financial support for this research work from the National Key Research and Development Program of China(No.2022YFB3304901)。
文摘A CFD-based numerical model was employed to quantitatively analyze the flow characteristics of double-side-blown gas−liquid flow.Key parameters were extracted,and Spearman correlation analysis was used to quantify the relationships among bubble behavior,circulating flow,and liquid oscillations.The results show that periodic bubble behavior under steady injection drives the circulating flow of the liquid on both sides.The asynchronism of bubble behavior on both sides results in the alternation of circulating intensity,which significantly enhances gas−liquid mixing efficiency at certain liquid levels of 200 and 220 mm.Flow patterns of the double-side-blown process are classified into weak circulation,strong−weak alternating circulation,and strong circulation modes based on the influence of circulating flows on the penetration depth.The penetration depth in the strong−weak alternating circulation mode is generally greater than that in the single-side-blown process.The imbalance of circulating intensities on both sides primarily leads to the stable fluctuation in the injecting direction,which reveals the appearance of periodic oscillations in the molten bath.The effect of control parameters such as liquid level and gas flow rate on the liquid oscillations were discussed.
基金Open Access funding enabled and organized by Projekt DEAL.
文摘In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics.Given copper's extensive industrial applications,sustainable recovery from low-grade ores is critical.Five key parameters-acid concentration,leaching time,particle size,temperature,and solids percentage-were identified as major influences on copper recovery.The results revealed that leaching time and solids percentage,along with interactions between temperature-time and temperature-solids percentage,had the most significant effects.Optimal conditions for 80% copper recovery while minimizing iron recovery below 3% included an acid concentration of 1.21 mol L^(-1),a leaching time of 108 min,a particle size of 438μm,a temperature of 45℃,and a solids percentage of 18.2%.Leaching kinetics were analyzed using shrinking core models,with the Dickinson model best describing the process,showing an activation energy of 32.63 kJ mol^(-1),indicative of mixed diffusion and chemical reaction control.The final kinetic model effectively predicted the influence of key parameters.These findings highlight the importance of optimizing process variables and selecting suitable kinetic models to enhance extraction efficiency,reduce costs,and improve sustainability in copper recovery.
基金financially supported by the National Key Research and Development Program of China (No. 2022YFC2105300)。
文摘A series of leaching and electrochemical experiments were conducted to elucidate the critical role of hydrogen sulfide(H_(2)S)in copper-driven reduction of chalcopyrite.Results demonstrate that in the absence of H_(2)S,metallic copper converts chalcopyrite into bornite(Cu_(5)FeS_(4)).However,the introduction of H_(2)S promotes the formation of chalcocite(Cu_(2)S)by altering the oxidation pathway of copper.Electrochemical analysis demonstrates that the presence of H₂S significantly reduces the corrosion potential of copper from 0.251 to−0.223 V(vs SHE),reaching the threshold necessary for the formation of Cu_(2)S.Nevertheless,excessive H_(2)S triggers sulfate reduction via the reaction of 8Cu+H_(2)SO_(4)+3H_(2)S=4Cu_(2)S+4H_(2)O(ΔG=−519.429 kJ/mol at 50℃),leading to inefficient copper utilization.
