As a part of the systematical investigation of the phase relationships of the Zn-Al base alloys,decomposi- tion of the supersaturated phase β_S in a eutectoid Zn-Al-Cu-Si alloy was studied by hardness testing,opti- c...As a part of the systematical investigation of the phase relationships of the Zn-Al base alloys,decomposi- tion of the supersaturated phase β_S in a eutectoid Zn-Al-Cu-Si alloy was studied by hardness testing,opti- cal,electron microscopy and X-ray diffraction.Com- pared to the monotectoid Zn-Al-Cu-Si alloy,a similar sequence of decomposition was found to consist of three stages of phase transformation,which were in accordance to various equilibrium reactions at the temperatures above the ageing temperatures.展开更多
In present investigation exchange interactions of Pr_(n+1)Co_(3n+5)B_(2n)-type compounds have been evalu- ated in the light of molecular-field theory. The exchange interactions and ferromagnetism in these compounds ar...In present investigation exchange interactions of Pr_(n+1)Co_(3n+5)B_(2n)-type compounds have been evalu- ated in the light of molecular-field theory. The exchange interactions and ferromagnetism in these compounds are discussed in terms of lattice parameters and interatomic distance between Co atom.展开更多
A study has been made of the fatigue crack growth in an Al-Li alloy 2091 in 3.5%NaCl solu- tion and at an elevated temperature of 130℃.The aging and environmental effects on the crack growth behaviour were examined.I...A study has been made of the fatigue crack growth in an Al-Li alloy 2091 in 3.5%NaCl solu- tion and at an elevated temperature of 130℃.The aging and environmental effects on the crack growth behaviour were examined.It is shown that the fatigue crack growth resistance decreases with aging.The specimen with underaged structures shows the highest resistance to fatigue crack growth due to more deflected crack paths and the resulting high crack closure levels.As compared to laborato- ry air,both 3.5% NaCl solution and elevated tem- perature of 130℃ cause an increase of near-thresh- old crack growth rates and a decrease of threshold levels.The elevated temperature is more effective. The effect of elevated temperature is mainly due to the precipitate coarsening which results in an enhancement of slip irreversibility.Hydrogen embritttlement is supposed to be responsible for the degradation of fatigue crack growth resistance in 3.5%NaCl solution展开更多
The authors regret there are some errors in the author information of the Supplementary Material.The correct author information of the Supplementary Material should be as follows.
The microstructure and tensile properties of Al_4C_3 dispersion strengthened Al composite fabricated by reaction milling technique were investigated.It is indicated that the rod-like Al_4C_3 dispersoids having a diame...The microstructure and tensile properties of Al_4C_3 dispersion strengthened Al composite fabricated by reaction milling technique were investigated.It is indicated that the rod-like Al_4C_3 dispersoids having a diameter of 0.02-0.03 μm and a length of 0.1-0.3μm are formed by reaction of C with Al, and uniformly distributed in the Al matrix.The interface between Al_4C_3 and Al is clean and the interfacial bonding is good.The matrix consists of the subgrains which have the size of 0.3-0.4μm, and most of the Al_4C_3 dispersoids are distributed on the subgrain boundaries.The 11 vol.-% Al_4C_3/Al composite exhibits an UTS (ultimate tensile strength) of 400 MPa and an elongation-to-failure of 8.0%.展开更多
The origin of low ductility at elevated tempera- ture in the cryogenic and non-magnetic steel Fe-23Mn-4Al-5Cr-0.3C was investigated by means of impact test at elevated temperatures,opti- cal microscope,SEM and TEM.The...The origin of low ductility at elevated tempera- ture in the cryogenic and non-magnetic steel Fe-23Mn-4Al-5Cr-0.3C was investigated by means of impact test at elevated temperatures,opti- cal microscope,SEM and TEM.The experimental results indicate that the impact toughness lowers with increasing testing temperature,and exhibits a low trough of ductility from 865℃ to 1050℃ and a peak value at 1150℃.The intergranular fracture occurs in the temperature region of low ductility and the transgranular ductile rupture below this re- gion principally.There is a process of precipitating, gathering,growing,and dissolution of carbide (FeMnCr)_(23)C_6 and AlN between 500℃ and 1000℃.The coalescence of microvoids caused by the process at grain boundaries results in the intergranular fracture and the low ductility at ele- vated temperatures.展开更多
The acoustic emission(AE)characteristics from the fatigue crack propagation in SM50B-Zc steel were strongly affected by the environment me- dium.The AE feature from the fatigue process both in air and in 3.5% NaCl aqu...The acoustic emission(AE)characteristics from the fatigue crack propagation in SM50B-Zc steel were strongly affected by the environment me- dium.The AE feature from the fatigue process both in air and in 3.5% NaCl aqueous solution mani- fested a periodicity which indicated the fatigue ex- tension was discontinuous.The fatigue striation and secondary cracking were the main AE sources during the fatigue crack growth in air.In contrast, AE during the fatigue crack propagation in 3.5% NaCl solution was released from the intergranular fracture and quasicleavage cracking.展开更多
As a part of the systematic investigation on phase relationships of Zn-Al based alloys containing Cu and/or Si, the equilibrium phase transformations of the quaternary Zn-Al-Cu-Si system at 285℃ were investigated by ...As a part of the systematic investigation on phase relationships of Zn-Al based alloys containing Cu and/or Si, the equilibrium phase transformations of the quaternary Zn-Al-Cu-Si system at 285℃ were investigated by using X-ray diffracti on, scanning electron microscopy and electron probe microanalysis techniques. A five-phase of (α+β+εT'+σ) and a four- phase of (β+ε+η+σ) were detected separately coexisting in the Zn-Al-Cu-Si system at 285℃. Then the 285℃ isothermal section of Zn-Al-Cu-Si system (with 0.1% -Si content) was established, and an equilibrium reaction was determined at 286℃ as the following pattern, β+T'=α+ε展开更多
The thermal stability of amorphous ternary hydrides Mg_(50)Ni_(50)H_(54) and Mg_(30)Ni_(70)H_(45) and their corre- sponding amorphous binary alloys Mg_(50)Ni_(50) and Mg_(30)Ni_(70) were studied with X-ray diffraction...The thermal stability of amorphous ternary hydrides Mg_(50)Ni_(50)H_(54) and Mg_(30)Ni_(70)H_(45) and their corre- sponding amorphous binary alloys Mg_(50)Ni_(50) and Mg_(30)Ni_(70) were studied with X-ray diffraction (XRD) and differential scanning calorimetry(DSC). Samples of the amorphous alloys were prepared by mechanical alloying and the amorphous hydrides were obtained by charging the alloys with gas- eous hydrogen at 3.0 MPa and 423 K. It was found that the amorphous hydrides released most of their hydrogen before the crystallization of the essentially hydrogen depleted amorphous alloy. The crystallization temperature of amorphous Mg_(50)Ni_(50)H_(54) elevated and that of amorphous Mg_(30)Ni_(70)H_(45) did not change in relation to the original binary amorphous alloy. This is very excep- tional for amorphous hydrides. The reason for the effects of hydrogen absorption/desorption on the crystallization of amorphous alloys was discussed.展开更多
1.IntroductionZirconia doped with MgO,CaO,YO,and other rare earth oxides is a re-markable material due to its technologicalimportance,basic scientific interest as wellas superior synthetic properties[1].In orderto imp...1.IntroductionZirconia doped with MgO,CaO,YO,and other rare earth oxides is a re-markable material due to its technologicalimportance,basic scientific interest as wellas superior synthetic properties[1].In orderto improve the properties of the material,in-展开更多
An investigation has been made of the disloca- tion distribution and dislocation free zone near the crack tip in bulk Fe-3% Si single crystal during deformation in SEM.It has been found that a number of dislocations w...An investigation has been made of the disloca- tion distribution and dislocation free zone near the crack tip in bulk Fe-3% Si single crystal during deformation in SEM.It has been found that a number of dislocations were emitted from the crack tip during deformation.After that,the dislocations moved rapidly away from the crack tip,which indi- cated that they were strongly repelled by the stress field at the crack tip.Between the crack tip and the plastic zone there is a region of dislocation-free, which is referred to as dislocation-free zone (DFZ). The length of DFZs is roughly estimated 100 μm which is much longer than that found in thin foil specimen.The variation of dislocation density as a function of the distance from the crack tip was measured,which showed that the dislocations are inversely piled up in the plastic zone.The length of DFZs increased with both the length of pre-crack and the amplitude of applied stress.展开更多
70-30 brass is rolled with 90% reduction by cross shear rolling in single direction with speed ra- tio 1.39.The sheet is divided into five layers along rolling plane normal to measure macroscopic statis- tical unsymme...70-30 brass is rolled with 90% reduction by cross shear rolling in single direction with speed ra- tio 1.39.The sheet is divided into five layers along rolling plane normal to measure macroscopic statis- tical unsymmetric textures in every layer are des- cribed and analysed by means of three dimensional orientation distribution function.The results indi- cate that the main textures in every layer of brass rolled by cross shear rolling in single direction are the same as the main textures of brass rolled by conventional rolling.But the intensities,peak posi- tions and scatters of every texture component in {110}<112>are different,namely,there is a macroscopic statistical unsymmetry.It is found that the textures in every layer of brass rolled by cross shear rolling in single direction can be considered as the textures of brass rolled by common rolling in single direction at identical shear forces,the macroscopic statistical unsymmetry depends on the shear forces which are exerted on the layer.展开更多
The phase diagram of the binary system MnO-Nb_2O_5 was studied by means of the differential thermal analysis(DTA),X-ray diffraction analysis and scanning electron microscopy(SEM).Thermodynamic da- ta of the new compou...The phase diagram of the binary system MnO-Nb_2O_5 was studied by means of the differential thermal analysis(DTA),X-ray diffraction analysis and scanning electron microscopy(SEM).Thermodynamic da- ta of the new compounds 4MnO·Nb_2O_5 and MnO·Nb_2O_5were found as follows: 4MnO·Nb_2O_5:t_m=1398±2℃ △H_m=129000(J/mol) △S_m=77(J/mol,K) △G_m^o=129000-77T(J/mol) MnO·Nb_2O_5:t_m=1499±2℃ △H_m=86940(J/mol) △S_m=49.6(J/mol,K) △G_m^o=86940-49.6T(J/mol) The eutectic parameters for the system are given below: t_(E1)=1383±3℃ N_(E1(MnO))=0.896 t_(E2)=1312±2℃ N_(E2(MoO))=0.713 t_(E3)=1400±4℃ N_(E3(MnO))=0.231展开更多
The longitudinal(L),long-transverse(T) and short-transverse(S)orientated samples of precipitation-strengthened 7075-T651 aluminum alloy were examined. The acoustic emission(AE)characteristics measured during tensile d...The longitudinal(L),long-transverse(T) and short-transverse(S)orientated samples of precipitation-strengthened 7075-T651 aluminum alloy were examined. The acoustic emission(AE)characteristics measured during tensile deformation in the alloy were related to prior aging treatment and orienta- tions of samples. A rms AE peak occurred in all the samples at plastic strain greater than one percent. The heights of peaks have been measured as a function of prior heat treatment.The shift of the peak location was dependent on heat treat- ment in samples with L- and T-orientation. The pre-yield,burst-type emission(PYBE)were observed in S-orientated samples.The behaviours of PYBE were as a function of prior ageing treat- ment too. The stress and plastic strains at which the AE peak stress were generated were consistent with the peaks arising from the fracture and debonding of inclusions.Waveform frequency analysis of AE signals and fractographic observa- tions using SEM as well as data of microhardness and charpy test were also consistent with be- haviours of AE,that is,high stress required for the rms peak or the initiation of the PYBE, was higher for the heat treatment,at which the interface between inclusion and matrix was weaker.展开更多
The slow relaxation of resistance and memory effect in TisoNi_(47)Fe_3 shape memory alloy(SMA) are found for the first time.An evidence for CDW mechanism of incommensurate and commensurate phases in SMA was provided.
The bio-glass in the Na2O-Ca2O-P2O5-SiO2 system involved in tins paper is highly bio-active. The hydrolization of this glass with calcium phosphate and low silica is studied. The structure-composition-property relatio...The bio-glass in the Na2O-Ca2O-P2O5-SiO2 system involved in tins paper is highly bio-active. The hydrolization of this glass with calcium phosphate and low silica is studied. The structure-composition-property relation of the glass is discussed by means of IR spectrum, DTA and SEM. This study shows that: (a)the structure of the glass is mainly chain-like or layer-like; (b) the glass is separated into a calcium phosphate-rich phase and a silica-rich phase; (c)the chuin- or layer-like structure and the separation hare advantages with hydrolization.展开更多
The system of LiH-LiF-P_2O_5 ionic conductor glass is prepared in neutral atmosphere and glass -forming region is given. The structure and coor- dination of glass are analyzed by IR spectra. Raman spectra and RDF(r). ...The system of LiH-LiF-P_2O_5 ionic conductor glass is prepared in neutral atmosphere and glass -forming region is given. The structure and coor- dination of glass are analyzed by IR spectra. Raman spectra and RDF(r). The result indicates that the (PO_4), (PO_3F) and (LiF_4) tetrahedra are basical structure units of glass network and the coordina- tion number of Li is 4. The coordination number of P is 4. The glass random network structure model is given. The study on structure shows that Li^+, H^- and partial F^- are charge carriers in glass system.展开更多
The structure and electric properties of the mixed conductors of Li_(1+x)V_3O_8(x=0.1) containing dispersed second-phase α-Al_2O_3 particles have been studied in the paper. The total conductivity of the specimen cont...The structure and electric properties of the mixed conductors of Li_(1+x)V_3O_8(x=0.1) containing dispersed second-phase α-Al_2O_3 particles have been studied in the paper. The total conductivity of the specimen containing 6m/o α-Al_2O_3 is five or six times as much as that of pure Li_(1+x)V_3O_8 (x=0.1) at room temperature. By the analyses of NMR and ESR, it is known that at low temperature, the transport activation energy of Li^+ ions reduced, the transport frequency of Li^+ ions are speeded up and thus ionic conductivity increased in the specimens containing α-Al_2O_3 particles. At high temperature, diffusion effect of α-Al_2O_3 on electronic transport becomes great, the enhancement of ionic conductivity caused by α-Al_2O_3 doesn't make up the decrease of electronic conductivity caused by the diffusion effect, so that total conductivity of the specimens containing DSPP is lower than that of pure Li_(1+x)V_3O_8(x=0.1). As a result, DSPP mainly increases ionic conductivity of the mixed conductors at room temperature.展开更多
The relationship between the high-frequency magnetic properties and surface structure of the amorphous [Co_(0.94-x)Fe_(0.06)(MnMo)_x]_(77)(SiB)_(23) alloys annealed at 400-500℃ then control-cooled was investigated us...The relationship between the high-frequency magnetic properties and surface structure of the amorphous [Co_(0.94-x)Fe_(0.06)(MnMo)_x]_(77)(SiB)_(23) alloys annealed at 400-500℃ then control-cooled was investigated using XRD,TEM and XPS techniques.The results have shown that the high-frequency losses of the present alloys ob- viously reduced after suitable treatment.A crystalline layer with ultrafine grains of γ-Co formed on the surface of the amorphous ribbons.The size of the grains is 10-20 nm.The thickness of the layer is less than 0.1 μm.The sur- face of the crystalline layer is covered with an extremely thin oxide film which is very uniform and dense with thickness of less than 30 nm,the size of grains of the oxide is less than 10 nm.These ultrafine grains and the dense oxide film effectively refine the magnetic domains and increase the resistance of the layers of the magnetic core,consequently the losses at high frequency are fairly reduced.展开更多
文摘As a part of the systematical investigation of the phase relationships of the Zn-Al base alloys,decomposi- tion of the supersaturated phase β_S in a eutectoid Zn-Al-Cu-Si alloy was studied by hardness testing,opti- cal,electron microscopy and X-ray diffraction.Com- pared to the monotectoid Zn-Al-Cu-Si alloy,a similar sequence of decomposition was found to consist of three stages of phase transformation,which were in accordance to various equilibrium reactions at the temperatures above the ageing temperatures.
文摘In present investigation exchange interactions of Pr_(n+1)Co_(3n+5)B_(2n)-type compounds have been evalu- ated in the light of molecular-field theory. The exchange interactions and ferromagnetism in these compounds are discussed in terms of lattice parameters and interatomic distance between Co atom.
文摘A study has been made of the fatigue crack growth in an Al-Li alloy 2091 in 3.5%NaCl solu- tion and at an elevated temperature of 130℃.The aging and environmental effects on the crack growth behaviour were examined.It is shown that the fatigue crack growth resistance decreases with aging.The specimen with underaged structures shows the highest resistance to fatigue crack growth due to more deflected crack paths and the resulting high crack closure levels.As compared to laborato- ry air,both 3.5% NaCl solution and elevated tem- perature of 130℃ cause an increase of near-thresh- old crack growth rates and a decrease of threshold levels.The elevated temperature is more effective. The effect of elevated temperature is mainly due to the precipitate coarsening which results in an enhancement of slip irreversibility.Hydrogen embritttlement is supposed to be responsible for the degradation of fatigue crack growth resistance in 3.5%NaCl solution
文摘The authors regret there are some errors in the author information of the Supplementary Material.The correct author information of the Supplementary Material should be as follows.
基金This work is financially supported by the FlandersChina bilateral project (BIL 99/10) and the Science and Technology Committee of Shanghai Municipality. The authors are thankful to Prof. H.L.Lukas, offering the new version of the Lukas Program.
文摘The microstructure and tensile properties of Al_4C_3 dispersion strengthened Al composite fabricated by reaction milling technique were investigated.It is indicated that the rod-like Al_4C_3 dispersoids having a diameter of 0.02-0.03 μm and a length of 0.1-0.3μm are formed by reaction of C with Al, and uniformly distributed in the Al matrix.The interface between Al_4C_3 and Al is clean and the interfacial bonding is good.The matrix consists of the subgrains which have the size of 0.3-0.4μm, and most of the Al_4C_3 dispersoids are distributed on the subgrain boundaries.The 11 vol.-% Al_4C_3/Al composite exhibits an UTS (ultimate tensile strength) of 400 MPa and an elongation-to-failure of 8.0%.
基金The project was supported by the National Natural Science Foundation of China:Grant No.5870006
文摘The origin of low ductility at elevated tempera- ture in the cryogenic and non-magnetic steel Fe-23Mn-4Al-5Cr-0.3C was investigated by means of impact test at elevated temperatures,opti- cal microscope,SEM and TEM.The experimental results indicate that the impact toughness lowers with increasing testing temperature,and exhibits a low trough of ductility from 865℃ to 1050℃ and a peak value at 1150℃.The intergranular fracture occurs in the temperature region of low ductility and the transgranular ductile rupture below this re- gion principally.There is a process of precipitating, gathering,growing,and dissolution of carbide (FeMnCr)_(23)C_6 and AlN between 500℃ and 1000℃.The coalescence of microvoids caused by the process at grain boundaries results in the intergranular fracture and the low ductility at ele- vated temperatures.
文摘The acoustic emission(AE)characteristics from the fatigue crack propagation in SM50B-Zc steel were strongly affected by the environment me- dium.The AE feature from the fatigue process both in air and in 3.5% NaCl aqueous solution mani- fested a periodicity which indicated the fatigue ex- tension was discontinuous.The fatigue striation and secondary cracking were the main AE sources during the fatigue crack growth in air.In contrast, AE during the fatigue crack propagation in 3.5% NaCl solution was released from the intergranular fracture and quasicleavage cracking.
文摘As a part of the systematic investigation on phase relationships of Zn-Al based alloys containing Cu and/or Si, the equilibrium phase transformations of the quaternary Zn-Al-Cu-Si system at 285℃ were investigated by using X-ray diffracti on, scanning electron microscopy and electron probe microanalysis techniques. A five-phase of (α+β+εT'+σ) and a four- phase of (β+ε+η+σ) were detected separately coexisting in the Zn-Al-Cu-Si system at 285℃. Then the 285℃ isothermal section of Zn-Al-Cu-Si system (with 0.1% -Si content) was established, and an equilibrium reaction was determined at 286℃ as the following pattern, β+T'=α+ε
文摘The thermal stability of amorphous ternary hydrides Mg_(50)Ni_(50)H_(54) and Mg_(30)Ni_(70)H_(45) and their corre- sponding amorphous binary alloys Mg_(50)Ni_(50) and Mg_(30)Ni_(70) were studied with X-ray diffraction (XRD) and differential scanning calorimetry(DSC). Samples of the amorphous alloys were prepared by mechanical alloying and the amorphous hydrides were obtained by charging the alloys with gas- eous hydrogen at 3.0 MPa and 423 K. It was found that the amorphous hydrides released most of their hydrogen before the crystallization of the essentially hydrogen depleted amorphous alloy. The crystallization temperature of amorphous Mg_(50)Ni_(50)H_(54) elevated and that of amorphous Mg_(30)Ni_(70)H_(45) did not change in relation to the original binary amorphous alloy. This is very excep- tional for amorphous hydrides. The reason for the effects of hydrogen absorption/desorption on the crystallization of amorphous alloys was discussed.
文摘1.IntroductionZirconia doped with MgO,CaO,YO,and other rare earth oxides is a re-markable material due to its technologicalimportance,basic scientific interest as wellas superior synthetic properties[1].In orderto improve the properties of the material,in-
文摘An investigation has been made of the disloca- tion distribution and dislocation free zone near the crack tip in bulk Fe-3% Si single crystal during deformation in SEM.It has been found that a number of dislocations were emitted from the crack tip during deformation.After that,the dislocations moved rapidly away from the crack tip,which indi- cated that they were strongly repelled by the stress field at the crack tip.Between the crack tip and the plastic zone there is a region of dislocation-free, which is referred to as dislocation-free zone (DFZ). The length of DFZs is roughly estimated 100 μm which is much longer than that found in thin foil specimen.The variation of dislocation density as a function of the distance from the crack tip was measured,which showed that the dislocations are inversely piled up in the plastic zone.The length of DFZs increased with both the length of pre-crack and the amplitude of applied stress.
文摘70-30 brass is rolled with 90% reduction by cross shear rolling in single direction with speed ra- tio 1.39.The sheet is divided into five layers along rolling plane normal to measure macroscopic statis- tical unsymmetric textures in every layer are des- cribed and analysed by means of three dimensional orientation distribution function.The results indi- cate that the main textures in every layer of brass rolled by cross shear rolling in single direction are the same as the main textures of brass rolled by conventional rolling.But the intensities,peak posi- tions and scatters of every texture component in {110}<112>are different,namely,there is a macroscopic statistical unsymmetry.It is found that the textures in every layer of brass rolled by cross shear rolling in single direction can be considered as the textures of brass rolled by common rolling in single direction at identical shear forces,the macroscopic statistical unsymmetry depends on the shear forces which are exerted on the layer.
文摘The phase diagram of the binary system MnO-Nb_2O_5 was studied by means of the differential thermal analysis(DTA),X-ray diffraction analysis and scanning electron microscopy(SEM).Thermodynamic da- ta of the new compounds 4MnO·Nb_2O_5 and MnO·Nb_2O_5were found as follows: 4MnO·Nb_2O_5:t_m=1398±2℃ △H_m=129000(J/mol) △S_m=77(J/mol,K) △G_m^o=129000-77T(J/mol) MnO·Nb_2O_5:t_m=1499±2℃ △H_m=86940(J/mol) △S_m=49.6(J/mol,K) △G_m^o=86940-49.6T(J/mol) The eutectic parameters for the system are given below: t_(E1)=1383±3℃ N_(E1(MnO))=0.896 t_(E2)=1312±2℃ N_(E2(MoO))=0.713 t_(E3)=1400±4℃ N_(E3(MnO))=0.231
文摘The longitudinal(L),long-transverse(T) and short-transverse(S)orientated samples of precipitation-strengthened 7075-T651 aluminum alloy were examined. The acoustic emission(AE)characteristics measured during tensile deformation in the alloy were related to prior aging treatment and orienta- tions of samples. A rms AE peak occurred in all the samples at plastic strain greater than one percent. The heights of peaks have been measured as a function of prior heat treatment.The shift of the peak location was dependent on heat treat- ment in samples with L- and T-orientation. The pre-yield,burst-type emission(PYBE)were observed in S-orientated samples.The behaviours of PYBE were as a function of prior ageing treat- ment too. The stress and plastic strains at which the AE peak stress were generated were consistent with the peaks arising from the fracture and debonding of inclusions.Waveform frequency analysis of AE signals and fractographic observa- tions using SEM as well as data of microhardness and charpy test were also consistent with be- haviours of AE,that is,high stress required for the rms peak or the initiation of the PYBE, was higher for the heat treatment,at which the interface between inclusion and matrix was weaker.
文摘The slow relaxation of resistance and memory effect in TisoNi_(47)Fe_3 shape memory alloy(SMA) are found for the first time.An evidence for CDW mechanism of incommensurate and commensurate phases in SMA was provided.
文摘The bio-glass in the Na2O-Ca2O-P2O5-SiO2 system involved in tins paper is highly bio-active. The hydrolization of this glass with calcium phosphate and low silica is studied. The structure-composition-property relation of the glass is discussed by means of IR spectrum, DTA and SEM. This study shows that: (a)the structure of the glass is mainly chain-like or layer-like; (b) the glass is separated into a calcium phosphate-rich phase and a silica-rich phase; (c)the chuin- or layer-like structure and the separation hare advantages with hydrolization.
文摘The system of LiH-LiF-P_2O_5 ionic conductor glass is prepared in neutral atmosphere and glass -forming region is given. The structure and coor- dination of glass are analyzed by IR spectra. Raman spectra and RDF(r). The result indicates that the (PO_4), (PO_3F) and (LiF_4) tetrahedra are basical structure units of glass network and the coordina- tion number of Li is 4. The coordination number of P is 4. The glass random network structure model is given. The study on structure shows that Li^+, H^- and partial F^- are charge carriers in glass system.
文摘The structure and electric properties of the mixed conductors of Li_(1+x)V_3O_8(x=0.1) containing dispersed second-phase α-Al_2O_3 particles have been studied in the paper. The total conductivity of the specimen containing 6m/o α-Al_2O_3 is five or six times as much as that of pure Li_(1+x)V_3O_8 (x=0.1) at room temperature. By the analyses of NMR and ESR, it is known that at low temperature, the transport activation energy of Li^+ ions reduced, the transport frequency of Li^+ ions are speeded up and thus ionic conductivity increased in the specimens containing α-Al_2O_3 particles. At high temperature, diffusion effect of α-Al_2O_3 on electronic transport becomes great, the enhancement of ionic conductivity caused by α-Al_2O_3 doesn't make up the decrease of electronic conductivity caused by the diffusion effect, so that total conductivity of the specimens containing DSPP is lower than that of pure Li_(1+x)V_3O_8(x=0.1). As a result, DSPP mainly increases ionic conductivity of the mixed conductors at room temperature.
文摘The relationship between the high-frequency magnetic properties and surface structure of the amorphous [Co_(0.94-x)Fe_(0.06)(MnMo)_x]_(77)(SiB)_(23) alloys annealed at 400-500℃ then control-cooled was investigated using XRD,TEM and XPS techniques.The results have shown that the high-frequency losses of the present alloys ob- viously reduced after suitable treatment.A crystalline layer with ultrafine grains of γ-Co formed on the surface of the amorphous ribbons.The size of the grains is 10-20 nm.The thickness of the layer is less than 0.1 μm.The sur- face of the crystalline layer is covered with an extremely thin oxide film which is very uniform and dense with thickness of less than 30 nm,the size of grains of the oxide is less than 10 nm.These ultrafine grains and the dense oxide film effectively refine the magnetic domains and increase the resistance of the layers of the magnetic core,consequently the losses at high frequency are fairly reduced.
