采用土壤中微量元素的连续浸提的分组方法,研究河北省20个表层土壤中 Cu 的形态分布。将土壤中 Cu 分为交换态、碳酸盐结合态、氧化物结合态、有机质结合态和残渣态,其平均含量分别为0.09 mg/kg,0.06 mg/kg,4.88 mg/kg,0.48 mg/kg,和9.2...采用土壤中微量元素的连续浸提的分组方法,研究河北省20个表层土壤中 Cu 的形态分布。将土壤中 Cu 分为交换态、碳酸盐结合态、氧化物结合态、有机质结合态和残渣态,其平均含量分别为0.09 mg/kg,0.06 mg/kg,4.88 mg/kg,0.48 mg/kg,和9.20 mg/kg。并讨论了土壤中 Cu 的形态分布特征及影响因素。此结果有助于评价土壤中 Cu 的背景值和了解土壤中Cu 的化学行为。展开更多
This paper is a review of some advances in the studies on 1.4-nm intergrade mineral of soils in sub-tropical China. 1) 1.4-nm intergrade mineral occurs ubiquitously in soils of subtropical China. The 1.4-nmrnineral in...This paper is a review of some advances in the studies on 1.4-nm intergrade mineral of soils in sub-tropical China. 1) 1.4-nm intergrade mineral occurs ubiquitously in soils of subtropical China. The 1.4-nmrnineral in red soil and yellow soil is mainly 1.4-nm intergrade mineral, and in acidic yellow-brown soil (pH< 5.5) is verniiculite alone or 1.4-nm intergrade mineral together with vermiculite. The distribution and thecontent of 1 .4-nm intergrade mineral in the mountain soils are more widespread and higher than those of thecorresponding soils in horizontal zone. 2) The interlayer material of 1.4-nin intergrade mineral ui these soilsappears to be hydroxy-Al polymers instead of hydroxy-Fe, proto-imogolite or kaolin-like material. There isa significant positive correlation between Al amount extracted from the soil with sodium citrate after DCBextraction and pH value of the citrate solution after the extraction. The citrate can also extract a certainamount of silicon from the soil, but the silicon may not come from interlayer of 1.4-nm intergrade mineral.3) It was seldom studied that either vermiculite or smectite did the natural 1.4-nm intergrade mineral comefrom in soil, or it was commonly thought to come from vermiculite. A recent report has revealed that itcan come from smectite. There are some different behaviors between the 1.4-nm intergrade mineral derivedfrom vermiculite and that from smectite. For example, they exert different influences on the formation ofgibbsite. The 1.4-nm intergrade mineral derived from smectite may promote the formation of gibbsite in theyellow soil. 4) The type of 1.4-nm minerals in soils. i.e., vermiculite or 1.4-nm intergrade mineral, may besignificant to soil properties, such as soil acidity, exchangeable Al, electric charge aiiiount and specific surfacearea. Therefore, the management for the soil in which 1.4-nm mineral is mainly 1.4-nm intergrade mineralor vermiculite should be dealt with differently.展开更多
The distribution of various fractions of Zn, Fe, Cu and Mn in 15 types of sods in China and its rela-tionship with plant availability were studied. Wactions of various elements were found to have some similarcharacter...The distribution of various fractions of Zn, Fe, Cu and Mn in 15 types of sods in China and its rela-tionship with plant availability were studied. Wactions of various elements were found to have some similarcharacteristic distribution regularities in wirious types of soils, but various soil types derered to varyingdegrees in the distribution of each fraction. Soil physico-chemical properties, such as pH, CEC and thecontents of OM, CaCO_3, free Fe, free Mn and P_2O_5, were signdicantly correlated with the distribution ofelemental fractions, and a significazit correlation also existed between the distribution and plant amilabilityof elemental fractions. Varfous fractions of each element were divided into two groups bed on their plantavailability. The correlation between the distribution of combination fractions aiid plaxit availability indi-cated a significantly or an extremely significantly positive correlation for Group I but a significantly or anextremely significantly negative correlation for Group II. Therefore, the fractions in Group I were primarypools of available nutrients, while those in Group II could hardly provide available nutrients for plants. Descreasing the transformation of corresponding elements into fractions of Group 11 and increasing the storagecapacity of various fractions of Group I were an important direction for regulation and controiling of soilnutrients. However, some Particular soils with too high contents of Zn, Fe, Cu and Mn should be regulatedand controlled adversely展开更多
This experiment aims to elaborate the influence of different organic manure applications on soil iron (Fe), copper (Cu), manganese (Mn) and zinc (Zn) contents in three successive seasons. Farmyard manure (FM...This experiment aims to elaborate the influence of different organic manure applications on soil iron (Fe), copper (Cu), manganese (Mn) and zinc (Zn) contents in three successive seasons. Farmyard manure (FM), chicken manure (CM) and blood meal (BM) and their mixtures and 1 control collectively 18 applications were tested under the open field conditions. All micro nutrients tended to increase with regard to the successive applications some of which were found to be statistically significant to a different extent. Considering the seasonal mean, an increase between the seasons in Fe, Cu and Mn contents were found to be statistically insignificant, whereas the Zn content was found to be statistically significant. CM gave rise to an augmentation in Cu, the Mn and Zn contents, BM also showed a tendency to increase in Fe contents of soils, but we recommend using BM only in small quantities due to the unfavorable features of the material. Summing up, 2.5 ton ha^-1 CM + 0.3 ton ha^-1 BM and 2.5 ton ha^-1 CM + 4.0 ton ha^-1 FM applications gave the better results.展开更多
文摘采用土壤中微量元素的连续浸提的分组方法,研究河北省20个表层土壤中 Cu 的形态分布。将土壤中 Cu 分为交换态、碳酸盐结合态、氧化物结合态、有机质结合态和残渣态,其平均含量分别为0.09 mg/kg,0.06 mg/kg,4.88 mg/kg,0.48 mg/kg,和9.20 mg/kg。并讨论了土壤中 Cu 的形态分布特征及影响因素。此结果有助于评价土壤中 Cu 的背景值和了解土壤中Cu 的化学行为。
文摘This paper is a review of some advances in the studies on 1.4-nm intergrade mineral of soils in sub-tropical China. 1) 1.4-nm intergrade mineral occurs ubiquitously in soils of subtropical China. The 1.4-nmrnineral in red soil and yellow soil is mainly 1.4-nm intergrade mineral, and in acidic yellow-brown soil (pH< 5.5) is verniiculite alone or 1.4-nm intergrade mineral together with vermiculite. The distribution and thecontent of 1 .4-nm intergrade mineral in the mountain soils are more widespread and higher than those of thecorresponding soils in horizontal zone. 2) The interlayer material of 1.4-nin intergrade mineral ui these soilsappears to be hydroxy-Al polymers instead of hydroxy-Fe, proto-imogolite or kaolin-like material. There isa significant positive correlation between Al amount extracted from the soil with sodium citrate after DCBextraction and pH value of the citrate solution after the extraction. The citrate can also extract a certainamount of silicon from the soil, but the silicon may not come from interlayer of 1.4-nm intergrade mineral.3) It was seldom studied that either vermiculite or smectite did the natural 1.4-nm intergrade mineral comefrom in soil, or it was commonly thought to come from vermiculite. A recent report has revealed that itcan come from smectite. There are some different behaviors between the 1.4-nm intergrade mineral derivedfrom vermiculite and that from smectite. For example, they exert different influences on the formation ofgibbsite. The 1.4-nm intergrade mineral derived from smectite may promote the formation of gibbsite in theyellow soil. 4) The type of 1.4-nm minerals in soils. i.e., vermiculite or 1.4-nm intergrade mineral, may besignificant to soil properties, such as soil acidity, exchangeable Al, electric charge aiiiount and specific surfacearea. Therefore, the management for the soil in which 1.4-nm mineral is mainly 1.4-nm intergrade mineralor vermiculite should be dealt with differently.
文摘The distribution of various fractions of Zn, Fe, Cu and Mn in 15 types of sods in China and its rela-tionship with plant availability were studied. Wactions of various elements were found to have some similarcharacteristic distribution regularities in wirious types of soils, but various soil types derered to varyingdegrees in the distribution of each fraction. Soil physico-chemical properties, such as pH, CEC and thecontents of OM, CaCO_3, free Fe, free Mn and P_2O_5, were signdicantly correlated with the distribution ofelemental fractions, and a significazit correlation also existed between the distribution and plant amilabilityof elemental fractions. Varfous fractions of each element were divided into two groups bed on their plantavailability. The correlation between the distribution of combination fractions aiid plaxit availability indi-cated a significantly or an extremely significantly positive correlation for Group I but a significantly or anextremely significantly negative correlation for Group II. Therefore, the fractions in Group I were primarypools of available nutrients, while those in Group II could hardly provide available nutrients for plants. Descreasing the transformation of corresponding elements into fractions of Group 11 and increasing the storagecapacity of various fractions of Group I were an important direction for regulation and controiling of soilnutrients. However, some Particular soils with too high contents of Zn, Fe, Cu and Mn should be regulatedand controlled adversely
文摘This experiment aims to elaborate the influence of different organic manure applications on soil iron (Fe), copper (Cu), manganese (Mn) and zinc (Zn) contents in three successive seasons. Farmyard manure (FM), chicken manure (CM) and blood meal (BM) and their mixtures and 1 control collectively 18 applications were tested under the open field conditions. All micro nutrients tended to increase with regard to the successive applications some of which were found to be statistically significant to a different extent. Considering the seasonal mean, an increase between the seasons in Fe, Cu and Mn contents were found to be statistically insignificant, whereas the Zn content was found to be statistically significant. CM gave rise to an augmentation in Cu, the Mn and Zn contents, BM also showed a tendency to increase in Fe contents of soils, but we recommend using BM only in small quantities due to the unfavorable features of the material. Summing up, 2.5 ton ha^-1 CM + 0.3 ton ha^-1 BM and 2.5 ton ha^-1 CM + 4.0 ton ha^-1 FM applications gave the better results.