The interaction of glucose oxidase (GOD) and four photosensitizers, ZnpcS4,ZnPc(NHCH2COOH)4, CIAIPcS, and porphyrine-like, were monitored by capillaryelectrophoresis. GOD, its degenerated products and photosensitizers...The interaction of glucose oxidase (GOD) and four photosensitizers, ZnpcS4,ZnPc(NHCH2COOH)4, CIAIPcS, and porphyrine-like, were monitored by capillaryelectrophoresis. GOD, its degenerated products and photosensitizers were simultaneouslyseparated in a buffer of 300 mmol/L borate at PH 8.5 on a commercial CE instrument. Bycomparison of the electropherograms of GOD as well as the mixture of GOD and photosensitizerswithout/with irradiation of different time, it was found that photosensitized oxidationsbetween GOD and different photosensitizers have different reaction mechanisms and kinetics.展开更多
文摘The interaction of glucose oxidase (GOD) and four photosensitizers, ZnpcS4,ZnPc(NHCH2COOH)4, CIAIPcS, and porphyrine-like, were monitored by capillaryelectrophoresis. GOD, its degenerated products and photosensitizers were simultaneouslyseparated in a buffer of 300 mmol/L borate at PH 8.5 on a commercial CE instrument. Bycomparison of the electropherograms of GOD as well as the mixture of GOD and photosensitizerswithout/with irradiation of different time, it was found that photosensitized oxidationsbetween GOD and different photosensitizers have different reaction mechanisms and kinetics.
