天然气水合物饱和度是评估天然气水合物资源量的重要参数,而用来估算饱和度的速度模型则是有限的几个,它们有的为经验公式,有的是以实验数据或野外资料为基础建立起来的,需要进行实验验证和参数分析以确定其使用的适用性.本文首次利用...天然气水合物饱和度是评估天然气水合物资源量的重要参数,而用来估算饱和度的速度模型则是有限的几个,它们有的为经验公式,有的是以实验数据或野外资料为基础建立起来的,需要进行实验验证和参数分析以确定其使用的适用性.本文首次利用超声和时域反射联合探测技术,研究了沉积物中水合物饱和度与声学特性的关系.并对时间平均方程、伍德及其修正方程、李权重方程和BGTL(Biot-Gassmann Theory by Lee)理论等常用的水合物饱和度估算模型进行了验证.实验结果表明,超声和时域反射联合探测技术能有效地实时获得水合物饱和度和纵、横波速的实验数据,李权重方程和BGTL理论的速度预测值与实验值比较吻合,有广泛的适用性.展开更多
The method of Random Forest （RF） was used to classify whether rockburst will happen and the intensity of rockburst in the underground rock projects. Some main control factors of rockburst, such as the values of in-s...The method of Random Forest （RF） was used to classify whether rockburst will happen and the intensity of rockburst in the underground rock projects. Some main control factors of rockburst, such as the values of in-situ stresses, uniaxial compressive strength and tensile strength of rock, and the elastic energy index of rock, were selected in the analysis. The traditional indicators were summarized and divided into indexes I and 1I. Random Forest model and criterion were obtained through training 36 sets of rockburst samples which come from underground rock projects in domestic and abroad. Another 10 samples were tested and evaluated with the model. The evaluated results agree well with the practical records. Comparing the results of support vector machine （SVM） method, and artificial neural network （ANN） method with random forest method, the corresponding misjudgment ratios are 10%, 20%, and 0, respectively. The misjudgment ratio using index I is smaller than that using index II. It is suggested that using the index I and RF model can accurately classify rockburst grade.展开更多
蛇纹石化过程中铁的活动性影响铁氧化物的形成和体系的氧逸度。然而,关于橄榄岩蛇纹石化过程中各矿物（橄榄石、斜方辉石和单斜辉石）蚀变过程中铁的活动性仍没有详细的研究。本文报道了80～200℃、饱和蒸气压下,不同的初始流体、水岩...蛇纹石化过程中铁的活动性影响铁氧化物的形成和体系的氧逸度。然而,关于橄榄岩蛇纹石化过程中各矿物（橄榄石、斜方辉石和单斜辉石）蚀变过程中铁的活动性仍没有详细的研究。本文报道了80～200℃、饱和蒸气压下,不同的初始流体、水岩比条件下,橄榄岩蛇纹石化过程中铁的活动性。结果表明,蛇纹石化流体的铁含量较低（0.0～0.7mmol/kg）,没有形成铁氧化物或铁氢氧化物,铁主要富集在蛇纹石和未反应的初始矿物中（例如,橄榄石和辉石）。由橄榄石蚀变形成的蛇纹石和由斜方辉石蚀变生成的蛇纹石化学组成相差较大,前者富铁而贫铝,后者贫铁而富铝。但当初始流体为碱性的0.5mol/L Na Cl（aq）时,两种不同来源的蛇纹石组成相差不大。尤为重要的是,单斜辉石蚀变生成的蛇纹石铁含量较高,8.1%～10.2%Fe O,远高于单斜辉石的铁含量（2.6%Fe O）。以上表明,低温蛇纹石化过程中,铁不能够大规模、长距离的运移,但在微米尺度上是活动的。展开更多
文摘天然气水合物饱和度是评估天然气水合物资源量的重要参数,而用来估算饱和度的速度模型则是有限的几个,它们有的为经验公式,有的是以实验数据或野外资料为基础建立起来的,需要进行实验验证和参数分析以确定其使用的适用性.本文首次利用超声和时域反射联合探测技术,研究了沉积物中水合物饱和度与声学特性的关系.并对时间平均方程、伍德及其修正方程、李权重方程和BGTL(Biot-Gassmann Theory by Lee)理论等常用的水合物饱和度估算模型进行了验证.实验结果表明,超声和时域反射联合探测技术能有效地实时获得水合物饱和度和纵、横波速的实验数据,李权重方程和BGTL理论的速度预测值与实验值比较吻合,有广泛的适用性.
基金Projects (50934006, 10872218) supported by the National Natural Science Foundation of ChinaProject (2010CB732004) supported bythe National Basic Research Program of China+1 种基金Project (kjdb2010-6) supported by Doctoral Candidate Innovation Research Support Program of Science & Technology Review, ChinaProject (201105) supported by Scholarship Award for Excellent Doctoral Student,Ministry of Education, China
文摘The method of Random Forest （RF） was used to classify whether rockburst will happen and the intensity of rockburst in the underground rock projects. Some main control factors of rockburst, such as the values of in-situ stresses, uniaxial compressive strength and tensile strength of rock, and the elastic energy index of rock, were selected in the analysis. The traditional indicators were summarized and divided into indexes I and 1I. Random Forest model and criterion were obtained through training 36 sets of rockburst samples which come from underground rock projects in domestic and abroad. Another 10 samples were tested and evaluated with the model. The evaluated results agree well with the practical records. Comparing the results of support vector machine （SVM） method, and artificial neural network （ANN） method with random forest method, the corresponding misjudgment ratios are 10%, 20%, and 0, respectively. The misjudgment ratio using index I is smaller than that using index II. It is suggested that using the index I and RF model can accurately classify rockburst grade.
文摘蛇纹石化过程中铁的活动性影响铁氧化物的形成和体系的氧逸度。然而,关于橄榄岩蛇纹石化过程中各矿物（橄榄石、斜方辉石和单斜辉石）蚀变过程中铁的活动性仍没有详细的研究。本文报道了80～200℃、饱和蒸气压下,不同的初始流体、水岩比条件下,橄榄岩蛇纹石化过程中铁的活动性。结果表明,蛇纹石化流体的铁含量较低（0.0～0.7mmol/kg）,没有形成铁氧化物或铁氢氧化物,铁主要富集在蛇纹石和未反应的初始矿物中（例如,橄榄石和辉石）。由橄榄石蚀变形成的蛇纹石和由斜方辉石蚀变生成的蛇纹石化学组成相差较大,前者富铁而贫铝,后者贫铁而富铝。但当初始流体为碱性的0.5mol/L Na Cl（aq）时,两种不同来源的蛇纹石组成相差不大。尤为重要的是,单斜辉石蚀变生成的蛇纹石铁含量较高,8.1%～10.2%Fe O,远高于单斜辉石的铁含量（2.6%Fe O）。以上表明,低温蛇纹石化过程中,铁不能够大规模、长距离的运移,但在微米尺度上是活动的。
