Inorganic perovskite solar cells(IPSCs),due to their suitable bandgap and superior thermal stability,are ideal candidates for tandem solar cells combined with silicon.However,the development of inorganic perovskite so...Inorganic perovskite solar cells(IPSCs),due to their suitable bandgap and superior thermal stability,are ideal candidates for tandem solar cells combined with silicon.However,the development of inorganic perovskite solar cells has been hindered by suboptimal crystallization dynamics that generate detrimental defects in the perovskite lattice.Here,we propose 4-Methoxyphenylphosphonic Acid(4MPA)as a multifunctional additive to address this challenge.P=O in 4MPA establish strong coordination with undercoordinated Pb^(2+),while-OH engage in O...H-O hydrogen bonding interactions with DMSO,effectively weakening the solvent-[PbX_(6)]^(4-)octahedron interaction.This dual functionality facilitates complete and rapid DMA^(+)-to-Cs^(+)cation exchange while regulating crystallization kinetics,thereby optimizing crystal growth.Furthermore,π-π interactions between benzene rings significantly enhance the moisture resistance of the perovskite layer.The optimized device demonstrates a power conversion efficiency(PCE)of 21.35%,with unencapsulated devices retaining 93,63%of their initial efficiency after 200-hour continuous operation under ambient conditions(35%relative humidity).展开更多
基金the financial support from the Yunnan Provincial Science and Technology Project at Southwest United Graduate School(Grant No.202302A0370009)the National Natural Science Foundation Joint Fund(Grant No.U21A2072)+4 种基金the National Science Foundation(Grant No.62274099)the Key Project of Tianjin Natural Science Foundation(Grant No.24JCZDJC01360)the China Higher Education Discipline Innovation Overseas Expert Introduction Project(Grant No.B16027)Tianjin Science and Technology Project(Grant No.24ZXZSSS00160)the Special Fund for Basic Scientific Research of the Central Universities。
文摘Inorganic perovskite solar cells(IPSCs),due to their suitable bandgap and superior thermal stability,are ideal candidates for tandem solar cells combined with silicon.However,the development of inorganic perovskite solar cells has been hindered by suboptimal crystallization dynamics that generate detrimental defects in the perovskite lattice.Here,we propose 4-Methoxyphenylphosphonic Acid(4MPA)as a multifunctional additive to address this challenge.P=O in 4MPA establish strong coordination with undercoordinated Pb^(2+),while-OH engage in O...H-O hydrogen bonding interactions with DMSO,effectively weakening the solvent-[PbX_(6)]^(4-)octahedron interaction.This dual functionality facilitates complete and rapid DMA^(+)-to-Cs^(+)cation exchange while regulating crystallization kinetics,thereby optimizing crystal growth.Furthermore,π-π interactions between benzene rings significantly enhance the moisture resistance of the perovskite layer.The optimized device demonstrates a power conversion efficiency(PCE)of 21.35%,with unencapsulated devices retaining 93,63%of their initial efficiency after 200-hour continuous operation under ambient conditions(35%relative humidity).
