he crystallization features of Fe38Hi39Si10B13 metallic glass under 100 keV and 6μA/cm2 helium ion irradiation with different doses are reported. It is found that the Fe38 Ni39Si10 B13 metallic glass crystallized und...he crystallization features of Fe38Hi39Si10B13 metallic glass under 100 keV and 6μA/cm2 helium ion irradiation with different doses are reported. It is found that the Fe38 Ni39Si10 B13 metallic glass crystallized under the helium ion irradiation at the temperature lower than the ordinary thermal crystallization temperature. The preferential precipitation phase is FeSi, and followed by the eutectic phase α-Fe. The critical dose for the formation of helium bubbles in the material is around 5x10￣16/cm2. The sensitivity of crystallization due to the temperature rising under helium ion irradiation and the mechanism of the sequence of precipitated phase are briefly discussed.展开更多
Mg63Ni22Pr15 metallic glasses are produced by a single roller melt-spinning technique. The hydrogen absorption and desorption capacities are respectively 0.38 and 0.14 wt% at 313 K obtained by pressure-composition iso...Mg63Ni22Pr15 metallic glasses are produced by a single roller melt-spinning technique. The hydrogen absorption and desorption capacities are respectively 0.38 and 0.14 wt% at 313 K obtained by pressure-composition isotherm. The amorphous structure is found to be retained after gaseous hydrogenation. The glass transition temperature, the onset crystallization temperature, and the crystallization temperature of the hydrogenated Mg63Ni22Pr15 metallic glass are 550, 570 and 577K, respectively, much higher than the corresponding values of 440, 470 and 499K of the as-quenched sample. This means that dramatic enhancement of thermal stability occurs in Mg63Ni22Pr15 metallic glass due to hydrogenation.展开更多
文摘he crystallization features of Fe38Hi39Si10B13 metallic glass under 100 keV and 6μA/cm2 helium ion irradiation with different doses are reported. It is found that the Fe38 Ni39Si10 B13 metallic glass crystallized under the helium ion irradiation at the temperature lower than the ordinary thermal crystallization temperature. The preferential precipitation phase is FeSi, and followed by the eutectic phase α-Fe. The critical dose for the formation of helium bubbles in the material is around 5x10￣16/cm2. The sensitivity of crystallization due to the temperature rising under helium ion irradiation and the mechanism of the sequence of precipitated phase are briefly discussed.
基金Supported by the National Natural Science Foundation of China under Grant No 50431030, and the Young Scholar Foundation of Nanjing University of Science and Technology under Grant No 200404.
文摘Mg63Ni22Pr15 metallic glasses are produced by a single roller melt-spinning technique. The hydrogen absorption and desorption capacities are respectively 0.38 and 0.14 wt% at 313 K obtained by pressure-composition isotherm. The amorphous structure is found to be retained after gaseous hydrogenation. The glass transition temperature, the onset crystallization temperature, and the crystallization temperature of the hydrogenated Mg63Ni22Pr15 metallic glass are 550, 570 and 577K, respectively, much higher than the corresponding values of 440, 470 and 499K of the as-quenched sample. This means that dramatic enhancement of thermal stability occurs in Mg63Ni22Pr15 metallic glass due to hydrogenation.
