Intracrystalline diffusivities for aromatic carbon in ZSM 5 were measured by ZLC method. Experiments were analyzed by two traditional methods (LT method and ST method) and a new full range method. The traditional math...Intracrystalline diffusivities for aromatic carbon in ZSM 5 were measured by ZLC method. Experiments were analyzed by two traditional methods (LT method and ST method) and a new full range method. The traditional mathematical description of the ZLC technique by LT method or ST method will cause deviation unavoidably. The new full range method avoids the problems caused by the traditional methods, so it is more suitable to analying ZLC experiments. Diffusion coefficients calculated by FR method are greater than those by LT method, but smaller than by ST method.展开更多
B-ZSM-5 molecular sieve was prepared with gas-solid replacement reaction. The parent zeolite, silicalite-Ⅰ was treated by BBr<sub>3</sub> vapour at 550℃. XRD, IR, XPS, and <sup>29</sup>Si MAS...B-ZSM-5 molecular sieve was prepared with gas-solid replacement reaction. The parent zeolite, silicalite-Ⅰ was treated by BBr<sub>3</sub> vapour at 550℃. XRD, IR, XPS, and <sup>29</sup>Si MAS NMR techniques show that boron is introduced into the framework of silicalite-Ⅰzeolite.展开更多
文摘Intracrystalline diffusivities for aromatic carbon in ZSM 5 were measured by ZLC method. Experiments were analyzed by two traditional methods (LT method and ST method) and a new full range method. The traditional mathematical description of the ZLC technique by LT method or ST method will cause deviation unavoidably. The new full range method avoids the problems caused by the traditional methods, so it is more suitable to analying ZLC experiments. Diffusion coefficients calculated by FR method are greater than those by LT method, but smaller than by ST method.
文摘B-ZSM-5 molecular sieve was prepared with gas-solid replacement reaction. The parent zeolite, silicalite-Ⅰ was treated by BBr<sub>3</sub> vapour at 550℃. XRD, IR, XPS, and <sup>29</sup>Si MAS NMR techniques show that boron is introduced into the framework of silicalite-Ⅰzeolite.
