A composite polymer electrolyte of Polyethylene oxide (PEO) LiClO 4 containing fine Al 2O 3 particles was studied by using differential scanning calorimetry, infrared spectroscopy and electrochemical impedance spectro...A composite polymer electrolyte of Polyethylene oxide (PEO) LiClO 4 containing fine Al 2O 3 particles was studied by using differential scanning calorimetry, infrared spectroscopy and electrochemical impedance spectroscopy. Compared with the polymer electrolyte without Al 2O 3 particles, the glass transition temperature and the degree of crystallinity were decreased, and the room temperature conductivity of PEO LiClO 4 Al 2O 3 composite polymer electrolyte was considerably enhanced. Moreover, the equivalent circuits and the effect of dc potential on impedance spectroscopy were discussed.展开更多
In order to solve the methanol crossover problem caused by the poor alcohol rejecting ability of the Nafion TM membranes currently used in direct methanol fuel cell (DMFC),polyvinylidene fluoride(PVDF)was blended with...In order to solve the methanol crossover problem caused by the poor alcohol rejecting ability of the Nafion TM membranes currently used in direct methanol fuel cell (DMFC),polyvinylidene fluoride(PVDF)was blended with Nafion material to prepare a new type of membrane for DMFC and its ionic conductivity and the methanol permeability was investigated.PVDF was used here to regulate the ratio between hydrophilic group and the hydrophobic group exist in the blend membranes according to the hydrophilic hydrophobic balance theory proposed in pervaporation.The adding of PVDF lead to a great improvement of the membrane’s MeOH rejection.When PVDF content was increased from 25% to 75%,the MeOH permeability was reduced from～10 -7 to ～10 -9 cm 2/s,1 to 3 orders of magnitude lower than that of Nafion117.The membrane conductivity decreased,although remaining at high value(～10 -4 S/cm),with the increase of PVDF content.Compared with the Nafion117 membrane,the PVDF Nafion blend membrane with only 25% of Nafion showed an improvement in performance by about 40 times,if the ratio( σ/P ) was adopted to characterize the performance of a membrane for DMFC.Percolation theory,cocontinuous morphology features and phase transition model were applied to explain the behavior of membrane conduction.展开更多
离子注入导电聚合物在电子和电气工程中有着巨大的潜在应用价值.正确使用其导电性,不仅应查明电导机理,而且应了解使用这种导体给连接器件带来的影响,迄今后者尚未引起人们的注意.本文以聚酯为试样,经不同剂量 As 离子注入后,研究了薄...离子注入导电聚合物在电子和电气工程中有着巨大的潜在应用价值.正确使用其导电性,不仅应查明电导机理,而且应了解使用这种导体给连接器件带来的影响,迄今后者尚未引起人们的注意.本文以聚酯为试样,经不同剂量 As 离子注入后,研究了薄膜的导电和介电性能,试验结果表明,电导的机理是导电微粒之间的隧道效应,电导率的温度关系可用σ=σ。exp(-b/T^(1/2))表示;离子注入聚酯薄膜的介质损耗具有松驰特性,损耗角正切的最大值达到0.45,松驰频率随着离子注入剂量的增加而增加.最后作者以等效电路和电子迁移速度分别讨论了松弛损耗的机理.展开更多
文摘A composite polymer electrolyte of Polyethylene oxide (PEO) LiClO 4 containing fine Al 2O 3 particles was studied by using differential scanning calorimetry, infrared spectroscopy and electrochemical impedance spectroscopy. Compared with the polymer electrolyte without Al 2O 3 particles, the glass transition temperature and the degree of crystallinity were decreased, and the room temperature conductivity of PEO LiClO 4 Al 2O 3 composite polymer electrolyte was considerably enhanced. Moreover, the equivalent circuits and the effect of dc potential on impedance spectroscopy were discussed.
文摘In order to solve the methanol crossover problem caused by the poor alcohol rejecting ability of the Nafion TM membranes currently used in direct methanol fuel cell (DMFC),polyvinylidene fluoride(PVDF)was blended with Nafion material to prepare a new type of membrane for DMFC and its ionic conductivity and the methanol permeability was investigated.PVDF was used here to regulate the ratio between hydrophilic group and the hydrophobic group exist in the blend membranes according to the hydrophilic hydrophobic balance theory proposed in pervaporation.The adding of PVDF lead to a great improvement of the membrane’s MeOH rejection.When PVDF content was increased from 25% to 75%,the MeOH permeability was reduced from～10 -7 to ～10 -9 cm 2/s,1 to 3 orders of magnitude lower than that of Nafion117.The membrane conductivity decreased,although remaining at high value(～10 -4 S/cm),with the increase of PVDF content.Compared with the Nafion117 membrane,the PVDF Nafion blend membrane with only 25% of Nafion showed an improvement in performance by about 40 times,if the ratio( σ/P ) was adopted to characterize the performance of a membrane for DMFC.Percolation theory,cocontinuous morphology features and phase transition model were applied to explain the behavior of membrane conduction.
文摘离子注入导电聚合物在电子和电气工程中有着巨大的潜在应用价值.正确使用其导电性,不仅应查明电导机理,而且应了解使用这种导体给连接器件带来的影响,迄今后者尚未引起人们的注意.本文以聚酯为试样,经不同剂量 As 离子注入后,研究了薄膜的导电和介电性能,试验结果表明,电导的机理是导电微粒之间的隧道效应,电导率的温度关系可用σ=σ。exp(-b/T^(1/2))表示;离子注入聚酯薄膜的介质损耗具有松驰特性,损耗角正切的最大值达到0.45,松驰频率随着离子注入剂量的增加而增加.最后作者以等效电路和电子迁移速度分别讨论了松弛损耗的机理.
