4-（4-Bromobutyl）styrene was synthesized from p-chloroacetophenone. p-Chloroacetophenone was hydrogenized with potassium hydrogenborane to obtain p-chlorophenylethanol, which was then dehydrated to yield p-chlorostyr...4-（4-Bromobutyl）styrene was synthesized from p-chloroacetophenone. p-Chloroacetophenone was hydrogenized with potassium hydrogenborane to obtain p-chlorophenylethanol, which was then dehydrated to yield p-chlorostyrene in the presence of potassium bisulfate, and finally p-chlorostyrene was reacted with （magnesium） to get Grignard reagent, which was then reacted with 1,4-dibromobutane to synthesize 4-（4-（bromobutyl））styrene. MS, 1H NMR and FT-IR were used to characterize the product. The results are （consistent） with the structure of 4-（4-bromobutyl） styrene.展开更多
By laser ablating graphite in the vapor of tetrachloromethane, a series of perchlorinated polycyclic aromatic hydrocarbons were synthesized. Among them, hexachlorobenzene (C6Cl6), octachloronaphthalene (C10 Cl8), octa...By laser ablating graphite in the vapor of tetrachloromethane, a series of perchlorinated polycyclic aromatic hydrocarbons were synthesized. Among them, hexachlorobenzene (C6Cl6), octachloronaphthalene (C10 Cl8), octachloroacenaphthylene (C12 Cl8), decachloroanthracene (C14 Cl10), decachlorophenanthrene (C14 Cl10 ), decachloropyrene (C16 Cl10 ), decachlorofluoranthene (C16Cl10 ), C18 Cl10, C20Cl10, C22Cl12 and C24Cl12 were identified by HPLC-UV-MS. The results demonstrate the potential of the reaction for synthesizing the compounds with special structures.展开更多
Fluorodenitration reaction was used to synthesis fluoroaromatics. The process has the advantages of mild reaction condition, high yield and little by-reaction when tetraalkylammonium fluoride R 4NF was used as a fluor...Fluorodenitration reaction was used to synthesis fluoroaromatics. The process has the advantages of mild reaction condition, high yield and little by-reaction when tetraalkylammonium fluoride R 4NF was used as a fluorodenitration reagent.展开更多
文摘4-（4-Bromobutyl）styrene was synthesized from p-chloroacetophenone. p-Chloroacetophenone was hydrogenized with potassium hydrogenborane to obtain p-chlorophenylethanol, which was then dehydrated to yield p-chlorostyrene in the presence of potassium bisulfate, and finally p-chlorostyrene was reacted with （magnesium） to get Grignard reagent, which was then reacted with 1,4-dibromobutane to synthesize 4-（4-（bromobutyl））styrene. MS, 1H NMR and FT-IR were used to characterize the product. The results are （consistent） with the structure of 4-（4-bromobutyl） styrene.
文摘By laser ablating graphite in the vapor of tetrachloromethane, a series of perchlorinated polycyclic aromatic hydrocarbons were synthesized. Among them, hexachlorobenzene (C6Cl6), octachloronaphthalene (C10 Cl8), octachloroacenaphthylene (C12 Cl8), decachloroanthracene (C14 Cl10), decachlorophenanthrene (C14 Cl10 ), decachloropyrene (C16 Cl10 ), decachlorofluoranthene (C16Cl10 ), C18 Cl10, C20Cl10, C22Cl12 and C24Cl12 were identified by HPLC-UV-MS. The results demonstrate the potential of the reaction for synthesizing the compounds with special structures.
文摘Fluorodenitration reaction was used to synthesis fluoroaromatics. The process has the advantages of mild reaction condition, high yield and little by-reaction when tetraalkylammonium fluoride R 4NF was used as a fluorodenitration reagent.
