A new three-dimensional indium phosphite,[In2(HPO3)4](NH3CH2CH2NH3),was prepared under hydrothermal conditions via using ethylenediamine as a template.Its structure was solved by singlecrys-tal X-ray diffraction.The c...A new three-dimensional indium phosphite,[In2(HPO3)4](NH3CH2CH2NH3),was prepared under hydrothermal conditions via using ethylenediamine as a template.Its structure was solved by singlecrys-tal X-ray diffraction.The compound crystallizes in a monoclinic system,space group P2/n,with cell parameters a=0.91405(5)nm,b=0.91984(5)nm,c=0.96120(5)nm,β=115.9950(10)°,V=0.72640(7)nm3,Z=2,R1=0.0249,wR2=0.0650,GOF=1.044.The inorganic topological structure is built up from the vertex linking of InO6 octahedral and HPO3 pyramidal tetrahedral units,forming eight-membered ring channels along the [506] direction.The diprontonated ethylenediamine molecules are entrapped in eight-membered ring channels.展开更多
文摘A new three-dimensional indium phosphite,[In2(HPO3)4](NH3CH2CH2NH3),was prepared under hydrothermal conditions via using ethylenediamine as a template.Its structure was solved by singlecrys-tal X-ray diffraction.The compound crystallizes in a monoclinic system,space group P2/n,with cell parameters a=0.91405(5)nm,b=0.91984(5)nm,c=0.96120(5)nm,β=115.9950(10)°,V=0.72640(7)nm3,Z=2,R1=0.0249,wR2=0.0650,GOF=1.044.The inorganic topological structure is built up from the vertex linking of InO6 octahedral and HPO3 pyramidal tetrahedral units,forming eight-membered ring channels along the [506] direction.The diprontonated ethylenediamine molecules are entrapped in eight-membered ring channels.
