The spontaneously generated electrical charge of a droplet dispensed from conventional pipetting is undesirable and unpredictable for most experiments that use pipetting.Hence,a method for controlling and removing the...The spontaneously generated electrical charge of a droplet dispensed from conventional pipetting is undesirable and unpredictable for most experiments that use pipetting.Hence,a method for controlling and removing the electrical charge needs to be developed.In this study,by using the electrode-deposited pipet tip(E-pipet tip),the charge-controlling system is newly developed and the electrical charge of a droplet is precisely controlled.The effect of electrolyte concentration and volume of the transferred solution to the electrical charge of a dispensed droplet is theoretically and experimentally investigated by using the equivalent capacitor model.Furthermore,a proof-of-concept example of the self-alignment and self-assembly of sequentially dispensed multiple droplets is demonstrated as one of the potential applications.Given that the electrical charge of the various aqueous droplets can be precisely and simply controlled,the fabricated E-pipet tip can be broadly utilized not only as a general charge-controlling platform of aqueous droplets but also as a powerful tool to explore fundamental scientific research regarding electrical charge of a droplet,such as the surface oscillation and evaporation of charged droplets.展开更多
In this paper a new chemical oscillating reaction in the pyruvic acid-BrO-H2SO4 - [CuL](ClO4)2 system, where L is 5, 7, 12, 14-tetraethyl-7, 14-dimethyl-1, 4, 8, 11 -tetraazacyclotetradeca-4, 11-diene, is reported. Th...In this paper a new chemical oscillating reaction in the pyruvic acid-BrO-H2SO4 - [CuL](ClO4)2 system, where L is 5, 7, 12, 14-tetraethyl-7, 14-dimethyl-1, 4, 8, 11 -tetraazacyclotetradeca-4, 11-diene, is reported. The features of the oscillations are studied in detail. The effects of Ag+,Hg2+,CCl4, Vc, H2O2, acrylonitrile, and temperature on the oscillation system are also discussed.展开更多
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIP).(No.2014R1A2A1A010065272011-0030075+1 种基金2012R1A2A2A06047424)supported by the convergence technology development program for bionic arm through the National Research Foundation of Korea(NRF)funded by the Ministry of Science,ICT&Future Planning(No.2014M3C1B2048632)
文摘The spontaneously generated electrical charge of a droplet dispensed from conventional pipetting is undesirable and unpredictable for most experiments that use pipetting.Hence,a method for controlling and removing the electrical charge needs to be developed.In this study,by using the electrode-deposited pipet tip(E-pipet tip),the charge-controlling system is newly developed and the electrical charge of a droplet is precisely controlled.The effect of electrolyte concentration and volume of the transferred solution to the electrical charge of a dispensed droplet is theoretically and experimentally investigated by using the equivalent capacitor model.Furthermore,a proof-of-concept example of the self-alignment and self-assembly of sequentially dispensed multiple droplets is demonstrated as one of the potential applications.Given that the electrical charge of the various aqueous droplets can be precisely and simply controlled,the fabricated E-pipet tip can be broadly utilized not only as a general charge-controlling platform of aqueous droplets but also as a powerful tool to explore fundamental scientific research regarding electrical charge of a droplet,such as the surface oscillation and evaporation of charged droplets.
文摘In this paper a new chemical oscillating reaction in the pyruvic acid-BrO-H2SO4 - [CuL](ClO4)2 system, where L is 5, 7, 12, 14-tetraethyl-7, 14-dimethyl-1, 4, 8, 11 -tetraazacyclotetradeca-4, 11-diene, is reported. The features of the oscillations are studied in detail. The effects of Ag+,Hg2+,CCl4, Vc, H2O2, acrylonitrile, and temperature on the oscillation system are also discussed.
