Suppressing the coffee ring effect(CRE)of an aqueous suspension through manipulation without affecting the remaining deposit is highly desirable for practical applications;however,this is extremely challenging.Here,we...Suppressing the coffee ring effect(CRE)of an aqueous suspension through manipulation without affecting the remaining deposit is highly desirable for practical applications;however,this is extremely challenging.Here,we demonstrate CRE suppression with undetectable disturbance of the deposit on carbon-based surfaces.This was achieved by adding ammonium bicarbonate(NH4HCO_(3)),which benefits from the dissociation of NH_(4)HCO_(3) to produce NH_(4)^(+),as well as its decomposition into NH_(3) and CO_(2) molecules.Surprisingly,NH_(4)^(+) can also function as Na^(+)/K^(+)to suppress the CRE through cation interactions,although its hydrate state is only partially positively charged.Moreover,we successfully applied this approach to enhance the morphology,resistance,and color uniformity of deposits of graphene oxide quantum dots,conductive inks,and organic dyes,respectively.This study provides a practical strategy for improving the performance of fabricated devices and paves the way for the development of high-accuracy manufacturing techniques in diverse industries.展开更多
This paper presents a comprehensive framework for analyzing phase transitions in collective models such as theVicsek model under various noise types. The Vicsek model, focusing on understanding the collective behavior...This paper presents a comprehensive framework for analyzing phase transitions in collective models such as theVicsek model under various noise types. The Vicsek model, focusing on understanding the collective behaviors of socialanimals, is known due to its discontinuous phase transitions under vector noise. However, its behavior under scalar noiseremains less conclusive. Renowned for its efficacy in the analysis of complex systems under both equilibrium and nonequilibriumstates, the eigen microstate method is employed here for a quantitative examination of the phase transitions inthe Vicsek model under both vector and scalar noises. The study finds that the Vicsek model exhibits discontinuous phasetransitions regardless of noise type. Furthermore, the dichotomy method is utilized to identify the critical points for thesephase transitions. A significant finding is the observed increase in the critical point for discontinuous phase transitions withescalation of population density.展开更多
Droplet levitation and coalescence mechanisms have consistently been a focal point in scientific research.Fromthe perspective of molecular interactions,we investigated the influence of vapor pressure on the levitation...Droplet levitation and coalescence mechanisms have consistently been a focal point in scientific research.Fromthe perspective of molecular interactions,we investigated the influence of vapor pressure on the levitation andcoalescence of droplets.The evaporation of nanodroplets and liquid pools under different initial environmentswas simulated by nonequilibrium molecular dynamics.The study analyzed the effects of evaporation during theprocesses of droplet levitation and coalescence and determined the existence of the Knudsen layer.Knudsenlayers consisting of water molecules rather than clusters are generated during the evaporation.The definition,properties,and mechanisms of the layers were investigated.展开更多
基金National Natural Science Foundation of China under Grant No.12005062(SS).National Natural Science Foundation of China under Grant No.11974366(HF).National Natural Science Foundation of China under Grant No.U1632135(HY)Fundamental Research Funds for the Central Universities,China(HF)。
文摘Suppressing the coffee ring effect(CRE)of an aqueous suspension through manipulation without affecting the remaining deposit is highly desirable for practical applications;however,this is extremely challenging.Here,we demonstrate CRE suppression with undetectable disturbance of the deposit on carbon-based surfaces.This was achieved by adding ammonium bicarbonate(NH4HCO_(3)),which benefits from the dissociation of NH_(4)HCO_(3) to produce NH_(4)^(+),as well as its decomposition into NH_(3) and CO_(2) molecules.Surprisingly,NH_(4)^(+) can also function as Na^(+)/K^(+)to suppress the CRE through cation interactions,although its hydrate state is only partially positively charged.Moreover,we successfully applied this approach to enhance the morphology,resistance,and color uniformity of deposits of graphene oxide quantum dots,conductive inks,and organic dyes,respectively.This study provides a practical strategy for improving the performance of fabricated devices and paves the way for the development of high-accuracy manufacturing techniques in diverse industries.
基金the National Natural Science Foundation of China(Grant No.62273033).
文摘This paper presents a comprehensive framework for analyzing phase transitions in collective models such as theVicsek model under various noise types. The Vicsek model, focusing on understanding the collective behaviors of socialanimals, is known due to its discontinuous phase transitions under vector noise. However, its behavior under scalar noiseremains less conclusive. Renowned for its efficacy in the analysis of complex systems under both equilibrium and nonequilibriumstates, the eigen microstate method is employed here for a quantitative examination of the phase transitions inthe Vicsek model under both vector and scalar noises. The study finds that the Vicsek model exhibits discontinuous phasetransitions regardless of noise type. Furthermore, the dichotomy method is utilized to identify the critical points for thesephase transitions. A significant finding is the observed increase in the critical point for discontinuous phase transitions withescalation of population density.
文摘Droplet levitation and coalescence mechanisms have consistently been a focal point in scientific research.Fromthe perspective of molecular interactions,we investigated the influence of vapor pressure on the levitation andcoalescence of droplets.The evaporation of nanodroplets and liquid pools under different initial environmentswas simulated by nonequilibrium molecular dynamics.The study analyzed the effects of evaporation during theprocesses of droplet levitation and coalescence and determined the existence of the Knudsen layer.Knudsenlayers consisting of water molecules rather than clusters are generated during the evaporation.The definition,properties,and mechanisms of the layers were investigated.
