The work deals with cellulose paper filled with nanocellulose and SrAl_(2)O_(4):Eu,Dy oxide phosphor.It was found that both nanocellulose and oxide improve the tensile strength of the composites obtained.The samples w...The work deals with cellulose paper filled with nanocellulose and SrAl_(2)O_(4):Eu,Dy oxide phosphor.It was found that both nanocellulose and oxide improve the tensile strength of the composites obtained.The samples with the oxide demonstrate a long-lasting photoluminescence(PL)under sunlight and ultra-violet(UV)illumination.Room-temperature the PL spectra reveal a wide multicomponent band spreading over all the visible spectral regions.The short-wavelength part of the band is ascribed to the cellulose-related luminescence,while the long-wavelength PL component with maxima near 540 nm corresponds to the luminescence of the SrAl_(2)O_(4):Eu,Dy phosphor.The dependency of the PL intensity on oxide concentration suggests the reabsorption of cellulose emission by the oxide and vice versa.The study of the dielectric properties of composite papers shows the presence of dielectric relaxations at low temperatures(T~−50℃).Similar cellulose materials to those studied can be considered as alternatives for artificial petroleum-based polymers.Low cost,eco-friendliness,biocompatibility,and the simplicity of recycling are among the main advantages of these materials.They are produced from the cellulose which is one of the most abundant renewable materials in nature.The data on the mechanical,dielectric,and optical properties indicate that the papers studied can be used in flexible lighting devices,WLEDs,coating,markers,labels,etc.展开更多
This study focuses on the fluorescent thermometric properties of CaMoO4:5%Tb3+under different temperature excitations.At the detection wavelength of 544 nm,with the temperature varying from 293 K to 563 K,there is a b...This study focuses on the fluorescent thermometric properties of CaMoO4:5%Tb3+under different temperature excitations.At the detection wavelength of 544 nm,with the temperature varying from 293 K to 563 K,there is a broadband absorption peak in the range of 250 nm to 350 nm.The results indicate that this phenomenon is caused by the superposition of the 4f-5d transition of Tb3+ and the O2--Mo6+charge transfer.It is considered that as the temperature rises,the luminescent intensity of the material shows an obvious continuous decreasing trend,which reflects a significant luminescent thermal quenching trend;thus,this quenching belongs to the“strong coupling”type.Based on the excitation spectrum results,two excitation wavelengths,312 nm and 338 nm,were specifically selected to excite the samples,which correspond to the top of the charge transfer band,the redshift intersection of the charge transfer band,and the edge of the charge transfer band at 293 K,respectively.展开更多
基金financed by the National Research Foundation of Ukraine(Project No.2022.01/0168).
文摘The work deals with cellulose paper filled with nanocellulose and SrAl_(2)O_(4):Eu,Dy oxide phosphor.It was found that both nanocellulose and oxide improve the tensile strength of the composites obtained.The samples with the oxide demonstrate a long-lasting photoluminescence(PL)under sunlight and ultra-violet(UV)illumination.Room-temperature the PL spectra reveal a wide multicomponent band spreading over all the visible spectral regions.The short-wavelength part of the band is ascribed to the cellulose-related luminescence,while the long-wavelength PL component with maxima near 540 nm corresponds to the luminescence of the SrAl_(2)O_(4):Eu,Dy phosphor.The dependency of the PL intensity on oxide concentration suggests the reabsorption of cellulose emission by the oxide and vice versa.The study of the dielectric properties of composite papers shows the presence of dielectric relaxations at low temperatures(T~−50℃).Similar cellulose materials to those studied can be considered as alternatives for artificial petroleum-based polymers.Low cost,eco-friendliness,biocompatibility,and the simplicity of recycling are among the main advantages of these materials.They are produced from the cellulose which is one of the most abundant renewable materials in nature.The data on the mechanical,dielectric,and optical properties indicate that the papers studied can be used in flexible lighting devices,WLEDs,coating,markers,labels,etc.
基金Basic Scientific Research Operating Expenses Project of Provincial Undergraduate Colleges and Universities in Heilongjiang Province:Study on Luminescent Properties and Fluorescent Temperature Characteristics of Rare Earth Luminescent Materials Based on Tungstates(YWK10236210223)Provincial General Project:College Students’Innovation and Entrepreneurship Training Program Project:Design of a Multifunctional Intelligent Car(202310236033)。
文摘This study focuses on the fluorescent thermometric properties of CaMoO4:5%Tb3+under different temperature excitations.At the detection wavelength of 544 nm,with the temperature varying from 293 K to 563 K,there is a broadband absorption peak in the range of 250 nm to 350 nm.The results indicate that this phenomenon is caused by the superposition of the 4f-5d transition of Tb3+ and the O2--Mo6+charge transfer.It is considered that as the temperature rises,the luminescent intensity of the material shows an obvious continuous decreasing trend,which reflects a significant luminescent thermal quenching trend;thus,this quenching belongs to the“strong coupling”type.Based on the excitation spectrum results,two excitation wavelengths,312 nm and 338 nm,were specifically selected to excite the samples,which correspond to the top of the charge transfer band,the redshift intersection of the charge transfer band,and the edge of the charge transfer band at 293 K,respectively.
