Aqueous alkali metal-ion batteries(AAMIBs)have been recognized as emerging electrochemical energy storage technologies for grid-scale applications owning to their intrinsic safety,cost-effectiveness,and environmental ...Aqueous alkali metal-ion batteries(AAMIBs)have been recognized as emerging electrochemical energy storage technologies for grid-scale applications owning to their intrinsic safety,cost-effectiveness,and environmental sustainability.However,the practical application of AAMIBs is still severely constrained by the tendency of aqueous electrolytes to freeze at low temperatures and decompose at high temperatures,limiting their operational temperature range.Considering the urgent need for energy systems with higher adaptability and resilience at various application scenarios,designing novel electrolytes via structure modulation has increasingly emerged as a feasible and economical strategy for the performance optimization of wide-temperature AAMIBs.In this review,the latest advancement of wide-temperature electrolytes for AAMIBs is systematically and comprehensively summarized.Specifically,the key challenges,failure mechanisms,correlations between hydrogen bond behaviors and physicochemical properties,and thermodynamic and kinetic interpretations in aqueous electrolytes are discussed firstly.Additionally,we offer forward-looking insights and innovative design principles for developing aqueous electrolytes capable of operating across a broad temperature range.This review is expected to provide some guidance and reference for the rational design and regulation of widetemperature electrolytes for AAMIBs and promote their future development.展开更多
An artificial potential field method based on global path guidance(G-APF)is proposed for target unreachability and local minima problems of the conventional artificial potential field(APF)method in complex environment...An artificial potential field method based on global path guidance(G-APF)is proposed for target unreachability and local minima problems of the conventional artificial potential field(APF)method in complex environments with dynamic obstacles.First,for the target unreachability problem,the global path attraction is added to the APF;second,an obstacle detection optimisation method is proposed and the optimal virtual target point is selected by setting the evaluation function to improve the local minima problem;finally,based on the obstacle detection optimisation method,the gravitational and repulsive processes are improved so that the path can pass through the narrow channel smoothly and remain collision-free.Experiments show that the method optimises 40.8%of the total path corners,reduces 81.8%of the number of path oscillations,and shortens 4.3%of the path length in Map 1.It can be applied to the vehicle obstacle avoidance path planning problem in complex environments with dynamic obstacles.展开更多
基金supported by the National Natural Science Foundation of China(52002297)National Key R&D Program of China(2022VFB2404800)+1 种基金Wuhan Yellow Crane Talents Program,China Postdoctoral Science Foundation(No.2024M752495)the Postdoctoral Fellowship Program of CPSF(No.GZB20230552).
文摘Aqueous alkali metal-ion batteries(AAMIBs)have been recognized as emerging electrochemical energy storage technologies for grid-scale applications owning to their intrinsic safety,cost-effectiveness,and environmental sustainability.However,the practical application of AAMIBs is still severely constrained by the tendency of aqueous electrolytes to freeze at low temperatures and decompose at high temperatures,limiting their operational temperature range.Considering the urgent need for energy systems with higher adaptability and resilience at various application scenarios,designing novel electrolytes via structure modulation has increasingly emerged as a feasible and economical strategy for the performance optimization of wide-temperature AAMIBs.In this review,the latest advancement of wide-temperature electrolytes for AAMIBs is systematically and comprehensively summarized.Specifically,the key challenges,failure mechanisms,correlations between hydrogen bond behaviors and physicochemical properties,and thermodynamic and kinetic interpretations in aqueous electrolytes are discussed firstly.Additionally,we offer forward-looking insights and innovative design principles for developing aqueous electrolytes capable of operating across a broad temperature range.This review is expected to provide some guidance and reference for the rational design and regulation of widetemperature electrolytes for AAMIBs and promote their future development.
基金supported by the Zhejiang Province New Young Talent Plan Project in 2022 under Grant No.2022R431B021。
文摘An artificial potential field method based on global path guidance(G-APF)is proposed for target unreachability and local minima problems of the conventional artificial potential field(APF)method in complex environments with dynamic obstacles.First,for the target unreachability problem,the global path attraction is added to the APF;second,an obstacle detection optimisation method is proposed and the optimal virtual target point is selected by setting the evaluation function to improve the local minima problem;finally,based on the obstacle detection optimisation method,the gravitational and repulsive processes are improved so that the path can pass through the narrow channel smoothly and remain collision-free.Experiments show that the method optimises 40.8%of the total path corners,reduces 81.8%of the number of path oscillations,and shortens 4.3%of the path length in Map 1.It can be applied to the vehicle obstacle avoidance path planning problem in complex environments with dynamic obstacles.
