FAPbI3 has been extensively employed in high-performance perovskite solar cells(PSCs)owing to its optimal bandgap and outstanding optoelectronic properties.Nevertheless,it readily undergoes the formation of a photo-in...FAPbI3 has been extensively employed in high-performance perovskite solar cells(PSCs)owing to its optimal bandgap and outstanding optoelectronic properties.Nevertheless,it readily undergoes the formation of a photo-inactiveδ-phase during crystallization,and achieving high-qualityα-phase films becomes even more challenging in antisolvent-free fabrication processes.This study introduces a crystallization control strategy based on 2-dimethylaminopyridine(2-DMAP)ligand engineering to establish a“fast nucleation-slow growth”dual-time-domain crystallization mechanism.2-DMAP facilitates the formation of a functional intermediate phase(2-DMAP·PbI_(2)·DMSO)that enables a direct transformation to theα-FAPbI3 phase and effectively suppresses theδ-phase pathway.Theoretical calculations and systematic experimental characterizations demonstrate that 2-DMAP exhibits stronger binding affinity and a greater charge polarization effect than dimethylsulfoxide(DMSO).This promotes the formation of high-density nuclei during spin coating and delays excessive grain growth during annealing,leading to perovskite films with improved crystallinity,fewer defects,and longer carrier lifetimes.As a result,an antisolvent-free PSC device was successfully fabricated,achieving a power conversion efficiency(PCE)of 25.10%,one of the highest reported for antisolvent-free spin-coating systems.Under ISOS-L-1 standard conditions,the device retained 84.78%of its initial efficiency after 1500 h of continuous illumination,demonstrating excellent operational stability.Moreover,it exhibited remarkable long-term stability under harsh humid and thermal conditions.This work offers a valuable strategy for the large-scale fabrication of high-performance and antisolvent-free PSCs.展开更多
Titanium alloys,usually known as non-corrodible material,are susceptible to microbiologically influenced corrosion(MIC)in marine environment.While titanium-zirconium(TiZr)alloys have been extensively studied in medica...Titanium alloys,usually known as non-corrodible material,are susceptible to microbiologically influenced corrosion(MIC)in marine environment.While titanium-zirconium(TiZr)alloys have been extensively studied in medical applications,the influence of microorganisms,especially marine microorganisms,on their corrosion behavior has not been explored.In this work,a TiZrCu alloy with a combination of excel-lent mechanical,anti-corrosion,and antibacterial properties was developed by optimizing the Cu content and grain refinement.Its MIC and antibacterial mechanisms against Pseudomonas aeruginosa,a represen-tative marine microorganism,were systematically investigated.5.5 wt%was determined as the optimal copper content.The fine-grained Ti-15Zr-5.5Cu(TZC-5.5FG)alloy maintained high MIC resistance,exhibit-ing a corrosion current of 5.7±0.1 nA/cm^(2) and an antibacterial rate of 91.8% against P.aeruginosa.The mechanism of improved corrosion resistance was attributed to the denser passive film with high TiO2 content and the lower surface potential differenceΔE.The release of Cu^(2+)ions,ΔE,and the generation of ROS are three major factors that contribute to the antibacterial performance of TiZrCu alloys.Com-pared to other available marine metals,TZC-5.5FG alloy exhibited superior comprehensive performance,including excellent mechanical properties and anti-MIC capacity,which make it a promising material for load-bearing applications in marine environment.展开更多
To improve the corrosion resistance of biodegradable Mg alloys,WE43 alloys were implanted with Fe,Ti,Zn and Zr ions at the same implantation dose.The surface morphology,valence state of elements,nano-hardness(NH),elas...To improve the corrosion resistance of biodegradable Mg alloys,WE43 alloys were implanted with Fe,Ti,Zn and Zr ions at the same implantation dose.The surface morphology,valence state of elements,nano-hardness(NH),elastic modulus(EM),degradation rate and in vitro cell experiments of the modified WE43 alloys were systematically studied.A modified layer composed of Mg,MgO,the implanted elements and their oxides was formed on the modified alloys.Since high-speed metal ions caused severe surface lattice damage,the surface hardness of the substrate considerable increased.Electrochemical tests demonstrated a substantial enhancement in the corrosion resistance of the modified alloys via the implantation of Ti and Zr ions,resulting in a reduction of the corrosion current density to 88.1±9.9 and 15.6±11.4μA cm^(−2),respectively,compared with the implantation of Fe and Zn ions.Biocompatibility tests showed that the implantation of Fe,Ti,Zn and Zr ions enhanced the anticoagulant and hemolytic resistance of the WE43 alloy.All surface-modified samples showed negligible cytotoxicity(0-1)at 12.5%extract concentration.Moreover,the alloys implanted with Fe,Ti and Zn ions significantly promoted proliferation of human umbilical vein endothelial cells(HUVEC)compared with the unmodified alloy.The results demonstrate that Ti ion implantation is the best choice for WE43 alloy modification to achieve outstanding corrosion resistance and biocompatibility.展开更多
[Objectives]To investigate the content and distribution of inorganic elements in Astragalus membranaceus sourced from various regions in Gansu Province.[Methods]28 batches of A.membranaceus samples were collected and ...[Objectives]To investigate the content and distribution of inorganic elements in Astragalus membranaceus sourced from various regions in Gansu Province.[Methods]28 batches of A.membranaceus samples were collected and subsequently digested using the Multiwave 7000 super microwave digestion system.The contents of aluminum(Al),barium(Ba),beryllium(Be),cobalt(Co),chromium(Cr),iron(Fe),gallium(Ga),magnesium(Mg),manganese(Mn),nickel(Ni),antimony(Sb),tin(Sn),strontium(Sr),titanium(Ti),thallium(Tl),vanadium(V),and zinc(Zn)were quantified utilizing a PerkinElmer 2000 inductively coupled plasma mass spectrometer.Principal component analysis was performed utilizing SPSS 25.0 to identify the distinctive characteristic elements of A.membranaceus.Additionally,systematic cluster analysis was conducted using these characteristic elements as variables to investigate the relationship between the primary inorganic elements and the geographical origin of A.membranaceus.[Results]17 inorganic elements were identified in A.membranaceus specimens collected from Gansu Province,with characteristic elements including Ba,Co,Fe,Ga,Mn,Zn,and Sn.The contents of inorganic elements in various sources of A.membranaceus exhibited significant variability and demonstrated distinct clustering characteristics.[Conclusions]A.membranaceus,originating from Gansu Province,exhibits a high content of inorganic elements.However,variations in ecological environments can lead to differences in the specific inorganic elements that are enriched.This study aims to provide a reference for the further development and application of A.membranaceus.展开更多
Kirkendall voids(KVs)at the Cu/Sn interface are a typical failure in integrated circuits,leading to solder joint cracking and electrical disconnection.Although the formation of KVs has been attributed to the differenc...Kirkendall voids(KVs)at the Cu/Sn interface are a typical failure in integrated circuits,leading to solder joint cracking and electrical disconnection.Although the formation of KVs has been attributed to the difference in atomic diffusion rates at the Cu/Sn interface,the role of Cu intrinsic"quality"parameters(crystal defects)in this process remains unclear.This work systematically investigated the effects of Cu crystal defects on KVs:Cu substrates with different lattice defects and grain boundaries were prepared using proprietary electrodeposition additives,and the number of defects was quantitatively characterized by micro-strain,geometric dislocation density,and geometric phase analysis.The thermal aging experiments further showed that the formation of intermetallic compounds and KVs was related to crystal defect energy.When the grain boundary energy was higher than the lattice energy,the additional driving force resulted in short-circuit diffusion,causing local Cu depletion and voids.The lowcrystal-defect samples maintained the local Cu/Sn interdiffusion equilibrium,resulting in fewer voids after 1000 h.This study emphasizes that regulating the crystal defects can reduce KVs and provides a new insight for improving the integrated solder joint's reliability.展开更多
As droughts become more frequent and severer,understanding tree resilience and its role in mediating drought legacy effects(LEs)is critical for predicting forest ecosystem responses to future droughts and informing fo...As droughts become more frequent and severer,understanding tree resilience and its role in mediating drought legacy effects(LEs)is critical for predicting forest ecosystem responses to future droughts and informing forest management.Both Pinus tabuliformis and Populus davidiana are widely distributed in the Loess Plateau region of western China and play important roles in provision of ecosystem services.In this study we quantified the LEs and resilience,including resistance(Rt)and recovery(Rc),of radial growth(BAI,basal area increment)and intrinsic water use efficiency(iWUE)of the two species,determined the external and internal factors influencing Rt and Rc,and disentangled the respective contribution of Rt and Rc to LEs in the these two tree species.We found either negative or positive legacy effects in BAI(LEBAI)and iWUE(LEiWUE)in both species,mostly lasting for 1-3 years.Species differences were only detected in LEiWUE during the severer drought event.But species variation in resilience did not differ.P.tabuliformis exhibited lower Rt but higher Rc than P.davidiana.Tree diameter and drought intensity were negatively correlated with Rt and Rc;whereas tree age and growth variability positively influenced both resilience components.In P.tabulaeformis,the influence of Rt was stronger on LE than on Rc during the milder droughts,whereas during the severer droughts LE was affected by Rc.The reversed patterns of the effects were exhibited by P.davidiana.Our findings help advance current understanding on the factors driving resilience and how trees use different resilience strategies under different drought conditions to alleviate negative LEs.展开更多
In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8...In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8wt.%Li alloy was investigated.It revealed that after being hydrogen charged at 50 mA/cm2 for respectively 3 h,6 h and 18 h in 0.1 M NaCl solution,obvious HID occurred and the damage degree was gradually increased with the hydrogen charging time.For the sample being hydrogen charged for 3 h,micro pores with the diameter ranging from 10~30µm were formed and preferentially present inα-Mg phase.Moreover,micro cracks with the length ranging from 10~50µm mainly initiated inα-Mg phase,atα-Mg/β-Li interfaces and the peripheries of pores.With the increase of hydrogen charging time,the numbers of pores and cracks were obviously increased.Tensile results revealed that the hydrogen charging can simultaneously decrease the tensile strength and ductility of the alloy.Compared with the uncharged sample,the tensile yield strength,ultimate tensile strength and the elongation ratio to failure were respectively reduced by 5.7%,7.3%,31.7%for the 3h-charged sample and 24.6%,24.8%,67.0%for the 18h-charged sample.Failure analysis indicated that hydrogen charging can induce the brittle cracking of the alloy and the size of brittle cracking region being composed of quasi-cleavage facets and interfacial cracks on the fracture surfaces was increased with the hydrogen charging time.展开更多
Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during ...Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during winter using a high-resolution aerosol mass spectrometer and electrospray ionization high-resolution orbitrap mass spectrometer(ESI-HRMS).Our results show that the mass concentration of WSOA was significantly higher than that observed in Beijing in winter 2020,contributing about 56%of OA on average.CHO compounds(56%-74%)and CHN compounds(66%-80%)dominated in negative mode and positive mode,respectively,while CHON accounted for 15%-41%across both modes.The chemical characteristics of WSOA varied with polluted levels and between day and night.As pollution intensified,the abundance of CHO-compounds with condensed aromatics increased by 9%and the number of highly oxygenated molecules(HOMs)molecular formula detected in server haze was more than double that of clean days.CHO-compounds with ten carbon atoms(C_(10))were more abundant at night while those with nine carbon atoms(C_(9))were higher during the day.High levels of CHN+compounds were linked to nighttime biomass burning,whereas CHON compounds were more abundant during the day.Increased pollution also led to the formation of more complex CHON-compounds,indicating that organonitrates continue to play a significant role in rural pollution.展开更多
In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 k...In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 kg/(m2 s),saturation temperatures of 293,298,and 303 K,and inlet sub-cooling of 5,10,and 15 K.The analysis of the experimental results provides the following conclusions:a reduced mass flux and lower subcooling correspond to a diminished degree of superheat at the boiling inception wall;conversely,an elevated saturation temperature results in a reduced amount of superheat at the boiling inception wall.Furthermore,an increase in sub-cooling and saturation temperature will enhance heat transfer efficiency.The wall temperature is mostly influenced by variations in saturation temperature and is minimally related to changes in mass flux and subcooling degree.An increase in mass flux results in a greater pressure drop attributed to heightened frictional pressure loss.The variation in pressure drop with respect to sub-cooling is minimal,while an increased saturation temperature correlates with a reduced pressure drop due to the formation of smaller bubbles and lowered frictional pressure loss at high saturation pressures.This study thoroughly examines and summarizes the effects of mass flow rate,saturation temperature,and subcooling on the flow-boiling heat transfer and pressure drop characteristics of R1234yf.Furthermore,the new correlation has 93.42%of the predicted values fall within a 15%mean absolute error,exhibiting a mean absolute error of 5.75%.It provides a superior method for predicting the flow-boiling heat transfer coefficients of R1234yf in the heat sink of parallel microchannels compared to existing correlations.展开更多
Exploring secondary organic aerosol(SOA)processes is crucial for understanding climate and air pollution in megacities.This study introduces a new method using positive matrix factorization(PMF)to investigate the SOA ...Exploring secondary organic aerosol(SOA)processes is crucial for understanding climate and air pollution in megacities.This study introduces a new method using positive matrix factorization(PMF)to investigate the SOA process by integrating the OA and associated ions previously misidentified as inorganic aerosol in high-resolution aerosol mass spectrometry data.The mass spectra and time series of primary OA(POA)and less oxidized oxygenated OA(OOA)identified by this new method resembled those resolved by traditional PMF.However,more oxidized OOA(MO-OOA)identified by traditional PMF can be further subdivided into multiple OA factors,including nitrogen-enriched OA(ON-OA)and sulfur-enriched OA(OS-OA)in summer,and ON-OA,OS-OA,and OOA in winter.Our findings highlight the significant role of photochemical processes in the formation of OS-OA compared to ON-OA.The compositions of reconstructed MO-OOA varied under different Ox(=O_(3)+NO_(2))and relative humidity conditions,emphasizing the limitations of using a constant mass spectrum.Aged biomass burning OA(BBOA)and coal combustion OA(CCOA),previously misattributed as POA,contributed 9.2%(0.43μg m^(−3))and 7.0%(0.33μg m^(−3))to SOA,respectively.Aged BBOA was more prone to forming OS-OA,whereas ON-OA showed higher correlations with aged CCOA,indicating distinct molecular compositions of SOA from different aged POA sources.Compared to aged BBOA,aged CCOA was more subject to conversion during aqueous phase processing.These results suggest that the variations in mass spectra and compositions need to be considered when simulating SOA processes.展开更多
Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for ...Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for catalyst optimization.Herein,two main types of Pd-Cu bimetallic nanocrystal structures,heterostructure and intermetallic,were prepared and characterized using high-resolution transmission electron microscopy(HRTEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that two individual Pd and Cu nanocrystals with a mixed interface exist in the heterostructure nanocrystals,while Pd and Cu atoms are uniformly distributed across the intermetallic Pd-Cu nanocrystals.The catalytic nitrate reduction experiments were carried out in a semibatch reactor under constant hydrogen flow.The nitrate conversion rate of the heterostructure Pd-Cu nanocrystals supported onα-Al_(2)O_(3),γ-Al_(2)O_(3),SBA-15,and XC-72R exhibited 3.82-,6.76-,4.28-,2.44-fold enhancements relative to the intermetallic nanocrystals,and the nitrogen and nitrite were the main products for the heterostructure and intermetallic Pd-Cu nanocrystals,respectively.This indicates that the catalytic nitrate reduction over Pd-Cu catalyst is sensitive to the bimetallic structures of the catalysts,and heterostructure bimetallic nanocrystals exhibit better catalytic performances on both the activity and selectivity,which may provide new insights into the design and optimization of catalysts to improve catalytic activity and selectivity for nitrate reduction in water.展开更多
Melanoma is characterized by high malignancy,ranking the third among skin malignancies,and is associated with lack of specific treatment options and poor prognosis.Therefore,the development of effective therapies for ...Melanoma is characterized by high malignancy,ranking the third among skin malignancies,and is associated with lack of specific treatment options and poor prognosis.Therefore,the development of effective therapies for melanoma is imperative.A critical challenge in addressing subcutaneous disease lies in overcoming the skin barrier.In this study,we engineered a microneedle(MN)system that in-tegrates chemotherapy,photothermal therapy(PTT),and targeted therapy to enhance anti-tumor effi-cacy while effectively penetrating the skin barrier.In vitro studies have demonstrated that the MN drug delivery system(DDS)can effectively penetrate the stratum corneum of the skin,deliver therapeutics to subcutaneous tumor sites,and establish a drug reservoir at these locations to exert anti-tumor effects.Cellular experiments indicated that the engineered PTT chemotherapy-targeted MNs can be internalized by tumor cells,exhibiting enhanced cytotoxicity against them.In vivo pharmacological investigations revealed that the combination of PITT and chemotherapy delivered via this MN DDS produced synergistic anti-tumor effects,achieving a tumor inhibition rate of up to 98.15%.This in situ DDS minimizes involvement with other organs,significantly reducing chemotherapy-related side effects.In summary,the PTT chemotherapy-targeted MNs developed in this study demonstrate promising application po-tential by enhancing anti-tumor efficacy while minimizing adverse effects.展开更多
Bio-fuel can be used to help transition from a petroleum-based society to a bio-based society. Ever since the China Development and Reform Commission suspended the approval of crop processing programs, second-generati...Bio-fuel can be used to help transition from a petroleum-based society to a bio-based society. Ever since the China Development and Reform Commission suspended the approval of crop processing programs, second-generation bio-ethanol research and industrialization processes have attracted significant attention. In 2020, bio-ethanol production is predicted to reach 10 million tons. Currently, there are a few domestic enterprises that have established different scaled pilot or demonstration bases for cellulosic ethanol, which reduce the cost of ethanol by continuously improving pretreatment and hydrolysis techniques. In the next three years, these enterprises will realize large-scale commercial production. Given the practical problems in cellulosic ethanol plant construction and operation(e.g., marketing price variation and difficulties in feedstock collection), this paper began with the concept of a "whole-crop refinery" and presented a solution to the integration of industry and agriculture as well as multi-crop refining. This paper then took the whole-crop refining system of corn as an example and presented an analysis of the logistics, energy flow, and economical efficiency of the system. The results demonstrated that the integrated system could properly reduce the required fixed investments in production equipment,shared utilities, and wastewater treatment facilities, as well as reduction of energy consumption. Although the proposed system has several problems, it brings the long-term goal of large-scale commercial application closer than ever.展开更多
Purpose: We aimed to analyze the pregnancy outcomes and perinatal follow-up of mosaic embryo transfer in the preimplantation genetic testing (PGT) cycles. Method: We retrospectively selected 27 mosaic embryo transfer ...Purpose: We aimed to analyze the pregnancy outcomes and perinatal follow-up of mosaic embryo transfer in the preimplantation genetic testing (PGT) cycles. Method: We retrospectively selected 27 mosaic embryo transfer cycles as the study group and 97 euploid embryo transfer cycles as the control group after propensity score matching, which were performed in the reproductive medicine center of the Sixth Affiliated Hospital, Sun Yat-sen University, from March 2019 to September 2023. The biopsy cells from blastocyst were undertaken next generation sequencing (NGS). Results: No significant difference in pregnancy outcomes compared between the two groups. According to the size of aneuploid, fragment the level of mosaicism or blastocyst morphological gradings, there were no significant difference in mosaic embryo transfers. Conclusion: Mosaic embryo detected in the PGT cycle can lead to clinical pregnancy and live birth of healthy offspring, which can be considerate suitable for transfer.展开更多
Due to lattice reorientation,grain segmentation,induced recrystallization,twins play a very important role in regulating texture,refining grains,improving mechanical properties and corrosion resistance,and has receive...Due to lattice reorientation,grain segmentation,induced recrystallization,twins play a very important role in regulating texture,refining grains,improving mechanical properties and corrosion resistance,and has received more extensive attention.Numerous studies have shown that{10-12}<10-11>tensile twins(TTWs)are easily activated in large quantities due to the lower critical resolve shear stresses(CRSS).Introduction of TTWs under uniaxial compression improved the strength,ductility,and formability of magnesium(Mg)alloys.Moreover,TTWs produced by multi-directional impact forging(MDIF)can optimize the microstructure by dividing grains and promoting recrystallization,resulting in significant improvement of mechanical properties.Although{10-11}<10-12>compressive twins(CTWs)and{10-11}-{10-12}double twins(DTWs)can promote dynamic recrystallization(DRX),they are also favorable nucleation sites for cracks.In addition,the type and volume fraction of twins can affect the corrosion resistance,and they also play different roles in the corrosion process of different Mg alloys.Twins have shown great potential for improving structure and properties,but a comprehensive and critical discussion of twins in Mg alloys is still lacking.Therefore,based on previous studies,this article reviews the common types and variants of twins in Mg alloys,influencing factors,and their effects on the microstructure,mechanical properties and corrosion resistance.In addition,some interesting ideas are being proposed for further research.展开更多
An X-by-wire chassis can improve the kinematic characteristics of human-vehicle closed-loop system and thus active safety especially under emergency scenarios via enabling chassis coordinated control.This paper aims t...An X-by-wire chassis can improve the kinematic characteristics of human-vehicle closed-loop system and thus active safety especially under emergency scenarios via enabling chassis coordinated control.This paper aims to provide a complete and systematic survey on chassis coordinated control methods for full X-by-wire vehicles,with the primary goal of summarizing recent reserch advancements and stimulating innovative thoughts.Driving condition identification including driver’s operation intention,critical vehicle states and road adhesion condition and integrated control of X-by-wire chassis subsystems constitute the main framework of a chassis coordinated control scheme.Under steering and braking maneuvers,different driving condition identification methods are described in this paper.These are the trigger conditions and the basis for the implementation of chassis coordinated control.For the vehicles equipped with steering-by-wire,braking-by-wire and/or wire-controlled-suspension systems,state-of-the-art chassis coordinated control methods are reviewed including the coordination of any two or three chassis subsystems.Finally,the development trends are discussed.展开更多
The constant m_(i) in the Hoek-Brown(H-B) criterion is a fundamental parameter required for determining the compressive strength of rock. In this paper, drilling parameters provide a new basis for determining the cons...The constant m_(i) in the Hoek-Brown(H-B) criterion is a fundamental parameter required for determining the compressive strength of rock. In this paper, drilling parameters provide a new basis for determining the constant mi. An analytical relationship between the drilling parameters and constant miis established in consideration of the contact response between the drilling bit and the cut rock in the crushed zone.New models are developed to predict the triaxial compressive strength(TCS), internal friction angle φand cohesion c of rock. Drilling tests are carried out on 6 rock types to study the correlation between φ and m_(i). A comparison between the predicted values of rock mechanical properties and the measured values from the laboratory is performed to verify the accuracy of the proposed model(yielding an error less than 10%). The TCSs and constant m_(i) values of fifteen rocks are cited to validate the accuracy of the proposed model. The result shows that the proposed model predicts the TCS and constant m_(i) within a maximum error of 20%. The method can be conveniently applied to the rock mechanical properties.展开更多
基金supported by the National Natural Science Foundation of China(62374104,62374103)the Taishan Scholar Foundation of Shandong Province(tsqn2023120051105)+2 种基金the Natural Science Foundation of Shandong Province(ZR2023QE321)the Shandong University-Muerhls Joint LaboratoryThe authors also appreciate the analysis help from the Analytical Center for Structural Constituent and Physical Property of Core Facilities Sharing Platform,Shandong University,for the femtosecond transient absorption spectroscopy system(TAS,2104573S).
文摘FAPbI3 has been extensively employed in high-performance perovskite solar cells(PSCs)owing to its optimal bandgap and outstanding optoelectronic properties.Nevertheless,it readily undergoes the formation of a photo-inactiveδ-phase during crystallization,and achieving high-qualityα-phase films becomes even more challenging in antisolvent-free fabrication processes.This study introduces a crystallization control strategy based on 2-dimethylaminopyridine(2-DMAP)ligand engineering to establish a“fast nucleation-slow growth”dual-time-domain crystallization mechanism.2-DMAP facilitates the formation of a functional intermediate phase(2-DMAP·PbI_(2)·DMSO)that enables a direct transformation to theα-FAPbI3 phase and effectively suppresses theδ-phase pathway.Theoretical calculations and systematic experimental characterizations demonstrate that 2-DMAP exhibits stronger binding affinity and a greater charge polarization effect than dimethylsulfoxide(DMSO).This promotes the formation of high-density nuclei during spin coating and delays excessive grain growth during annealing,leading to perovskite films with improved crystallinity,fewer defects,and longer carrier lifetimes.As a result,an antisolvent-free PSC device was successfully fabricated,achieving a power conversion efficiency(PCE)of 25.10%,one of the highest reported for antisolvent-free spin-coating systems.Under ISOS-L-1 standard conditions,the device retained 84.78%of its initial efficiency after 1500 h of continuous illumination,demonstrating excellent operational stability.Moreover,it exhibited remarkable long-term stability under harsh humid and thermal conditions.This work offers a valuable strategy for the large-scale fabrication of high-performance and antisolvent-free PSCs.
基金supported by the National Key Research and Development Program of China(No.2022YFB3808800)the National Natural Science Foundation of China(No.52425112 and 52401178)+1 种基金the IMR Innovation Fund(No.2024-PY06)the CAS-WEGO Research and Development Plan Project.
文摘Titanium alloys,usually known as non-corrodible material,are susceptible to microbiologically influenced corrosion(MIC)in marine environment.While titanium-zirconium(TiZr)alloys have been extensively studied in medical applications,the influence of microorganisms,especially marine microorganisms,on their corrosion behavior has not been explored.In this work,a TiZrCu alloy with a combination of excel-lent mechanical,anti-corrosion,and antibacterial properties was developed by optimizing the Cu content and grain refinement.Its MIC and antibacterial mechanisms against Pseudomonas aeruginosa,a represen-tative marine microorganism,were systematically investigated.5.5 wt%was determined as the optimal copper content.The fine-grained Ti-15Zr-5.5Cu(TZC-5.5FG)alloy maintained high MIC resistance,exhibit-ing a corrosion current of 5.7±0.1 nA/cm^(2) and an antibacterial rate of 91.8% against P.aeruginosa.The mechanism of improved corrosion resistance was attributed to the denser passive film with high TiO2 content and the lower surface potential differenceΔE.The release of Cu^(2+)ions,ΔE,and the generation of ROS are three major factors that contribute to the antibacterial performance of TiZrCu alloys.Com-pared to other available marine metals,TZC-5.5FG alloy exhibited superior comprehensive performance,including excellent mechanical properties and anti-MIC capacity,which make it a promising material for load-bearing applications in marine environment.
基金supported by National Natural Science Foundation of China(52271117)Educational Commission of Hunan Province of China(23A0107)High Technology Research and Development Program of Hunan Province of China(2022GK4038).
文摘To improve the corrosion resistance of biodegradable Mg alloys,WE43 alloys were implanted with Fe,Ti,Zn and Zr ions at the same implantation dose.The surface morphology,valence state of elements,nano-hardness(NH),elastic modulus(EM),degradation rate and in vitro cell experiments of the modified WE43 alloys were systematically studied.A modified layer composed of Mg,MgO,the implanted elements and their oxides was formed on the modified alloys.Since high-speed metal ions caused severe surface lattice damage,the surface hardness of the substrate considerable increased.Electrochemical tests demonstrated a substantial enhancement in the corrosion resistance of the modified alloys via the implantation of Ti and Zr ions,resulting in a reduction of the corrosion current density to 88.1±9.9 and 15.6±11.4μA cm^(−2),respectively,compared with the implantation of Fe and Zn ions.Biocompatibility tests showed that the implantation of Fe,Ti,Zn and Zr ions enhanced the anticoagulant and hemolytic resistance of the WE43 alloy.All surface-modified samples showed negligible cytotoxicity(0-1)at 12.5%extract concentration.Moreover,the alloys implanted with Fe,Ti and Zn ions significantly promoted proliferation of human umbilical vein endothelial cells(HUVEC)compared with the unmodified alloy.The results demonstrate that Ti ion implantation is the best choice for WE43 alloy modification to achieve outstanding corrosion resistance and biocompatibility.
基金Supported by Project of NMPA Key Laboratory for Quality Control of Traditional Chinese Medicine(2023GSMPA-KL06,2024GSMPA-KL16).
文摘[Objectives]To investigate the content and distribution of inorganic elements in Astragalus membranaceus sourced from various regions in Gansu Province.[Methods]28 batches of A.membranaceus samples were collected and subsequently digested using the Multiwave 7000 super microwave digestion system.The contents of aluminum(Al),barium(Ba),beryllium(Be),cobalt(Co),chromium(Cr),iron(Fe),gallium(Ga),magnesium(Mg),manganese(Mn),nickel(Ni),antimony(Sb),tin(Sn),strontium(Sr),titanium(Ti),thallium(Tl),vanadium(V),and zinc(Zn)were quantified utilizing a PerkinElmer 2000 inductively coupled plasma mass spectrometer.Principal component analysis was performed utilizing SPSS 25.0 to identify the distinctive characteristic elements of A.membranaceus.Additionally,systematic cluster analysis was conducted using these characteristic elements as variables to investigate the relationship between the primary inorganic elements and the geographical origin of A.membranaceus.[Results]17 inorganic elements were identified in A.membranaceus specimens collected from Gansu Province,with characteristic elements including Ba,Co,Fe,Ga,Mn,Zn,and Sn.The contents of inorganic elements in various sources of A.membranaceus exhibited significant variability and demonstrated distinct clustering characteristics.[Conclusions]A.membranaceus,originating from Gansu Province,exhibits a high content of inorganic elements.However,variations in ecological environments can lead to differences in the specific inorganic elements that are enriched.This study aims to provide a reference for the further development and application of A.membranaceus.
基金financially supported by the National Natural Science Foundation of China(Nos.62274172 and 62304143)High-level Talent Innovation and Entrepreneurship Plan of Shenzhen Key Technology Research and Development Team Funding Application(No.JSGGKQTD20221101115650008)+2 种基金Shenzhen-Hong Kong-Macao Science and Technology Plan Project(Category C)(No.SGDX20220530111004028)Macao Science and Technology Development Fund(FDCT)for funding(No.0013/2024/RIB1)the Multi-Year Research Grant(MYRG)from University of Macao(Nos.MYRG-GRG2023-00140-IAPME-UMDF and MYRG-GRG2024-00206-IAPME)
文摘Kirkendall voids(KVs)at the Cu/Sn interface are a typical failure in integrated circuits,leading to solder joint cracking and electrical disconnection.Although the formation of KVs has been attributed to the difference in atomic diffusion rates at the Cu/Sn interface,the role of Cu intrinsic"quality"parameters(crystal defects)in this process remains unclear.This work systematically investigated the effects of Cu crystal defects on KVs:Cu substrates with different lattice defects and grain boundaries were prepared using proprietary electrodeposition additives,and the number of defects was quantitatively characterized by micro-strain,geometric dislocation density,and geometric phase analysis.The thermal aging experiments further showed that the formation of intermetallic compounds and KVs was related to crystal defect energy.When the grain boundary energy was higher than the lattice energy,the additional driving force resulted in short-circuit diffusion,causing local Cu depletion and voids.The lowcrystal-defect samples maintained the local Cu/Sn interdiffusion equilibrium,resulting in fewer voids after 1000 h.This study emphasizes that regulating the crystal defects can reduce KVs and provides a new insight for improving the integrated solder joint's reliability.
基金the National Natural Science Foundation of China(No.41977149).
文摘As droughts become more frequent and severer,understanding tree resilience and its role in mediating drought legacy effects(LEs)is critical for predicting forest ecosystem responses to future droughts and informing forest management.Both Pinus tabuliformis and Populus davidiana are widely distributed in the Loess Plateau region of western China and play important roles in provision of ecosystem services.In this study we quantified the LEs and resilience,including resistance(Rt)and recovery(Rc),of radial growth(BAI,basal area increment)and intrinsic water use efficiency(iWUE)of the two species,determined the external and internal factors influencing Rt and Rc,and disentangled the respective contribution of Rt and Rc to LEs in the these two tree species.We found either negative or positive legacy effects in BAI(LEBAI)and iWUE(LEiWUE)in both species,mostly lasting for 1-3 years.Species differences were only detected in LEiWUE during the severer drought event.But species variation in resilience did not differ.P.tabuliformis exhibited lower Rt but higher Rc than P.davidiana.Tree diameter and drought intensity were negatively correlated with Rt and Rc;whereas tree age and growth variability positively influenced both resilience components.In P.tabulaeformis,the influence of Rt was stronger on LE than on Rc during the milder droughts,whereas during the severer droughts LE was affected by Rc.The reversed patterns of the effects were exhibited by P.davidiana.Our findings help advance current understanding on the factors driving resilience and how trees use different resilience strategies under different drought conditions to alleviate negative LEs.
基金supported by the National Natural Science Foundation of China Projects under grant[nos.U21A2049,52071220,51871211,51701129 and 51971054]Liaoning Province's project of“Revitalizing Liaoning Talents”(XLYC1907062)+6 种基金the Doctor Startup Fund of Natural Science Foundation Program of Liaoning Province(no.2019-BS-200)the Strategic New Industry Development Special Foundation of Shenzhen(JCYJ20170306141749970)the funds of International Joint Laboratory for Light Alloys,Liaoning BaiQianWan Talents Program,the Domain Foundation of Equipment Advance Research of 13th Five-year Plan(61409220118)National Key Research and Development Program of China under grant[nos.2017YFB0702001 and 2016YFB0301105]the Innovation Fund of Institute of Metal Research(IMR),Chinese Academy of Sciences(CAS),the National Basic Research Program of China(973 Program)project under grant no.2013CB632205the Fundamental Research Fund for the Central Universities under grant[no.N2009006]Bintech-IMR R&D Program[no.GYY-JSBU-2022-009].
文摘In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8wt.%Li alloy was investigated.It revealed that after being hydrogen charged at 50 mA/cm2 for respectively 3 h,6 h and 18 h in 0.1 M NaCl solution,obvious HID occurred and the damage degree was gradually increased with the hydrogen charging time.For the sample being hydrogen charged for 3 h,micro pores with the diameter ranging from 10~30µm were formed and preferentially present inα-Mg phase.Moreover,micro cracks with the length ranging from 10~50µm mainly initiated inα-Mg phase,atα-Mg/β-Li interfaces and the peripheries of pores.With the increase of hydrogen charging time,the numbers of pores and cracks were obviously increased.Tensile results revealed that the hydrogen charging can simultaneously decrease the tensile strength and ductility of the alloy.Compared with the uncharged sample,the tensile yield strength,ultimate tensile strength and the elongation ratio to failure were respectively reduced by 5.7%,7.3%,31.7%for the 3h-charged sample and 24.6%,24.8%,67.0%for the 18h-charged sample.Failure analysis indicated that hydrogen charging can induce the brittle cracking of the alloy and the size of brittle cracking region being composed of quasi-cleavage facets and interfacial cracks on the fracture surfaces was increased with the hydrogen charging time.
基金supported by the National Natural Science Foundation of China(No.42307139)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0760200)。
文摘Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during winter using a high-resolution aerosol mass spectrometer and electrospray ionization high-resolution orbitrap mass spectrometer(ESI-HRMS).Our results show that the mass concentration of WSOA was significantly higher than that observed in Beijing in winter 2020,contributing about 56%of OA on average.CHO compounds(56%-74%)and CHN compounds(66%-80%)dominated in negative mode and positive mode,respectively,while CHON accounted for 15%-41%across both modes.The chemical characteristics of WSOA varied with polluted levels and between day and night.As pollution intensified,the abundance of CHO-compounds with condensed aromatics increased by 9%and the number of highly oxygenated molecules(HOMs)molecular formula detected in server haze was more than double that of clean days.CHO-compounds with ten carbon atoms(C_(10))were more abundant at night while those with nine carbon atoms(C_(9))were higher during the day.High levels of CHN+compounds were linked to nighttime biomass burning,whereas CHON compounds were more abundant during the day.Increased pollution also led to the formation of more complex CHON-compounds,indicating that organonitrates continue to play a significant role in rural pollution.
基金supported by the Beijing Municipal Science&Technology Commission(Z231100006123010).
文摘In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 kg/(m2 s),saturation temperatures of 293,298,and 303 K,and inlet sub-cooling of 5,10,and 15 K.The analysis of the experimental results provides the following conclusions:a reduced mass flux and lower subcooling correspond to a diminished degree of superheat at the boiling inception wall;conversely,an elevated saturation temperature results in a reduced amount of superheat at the boiling inception wall.Furthermore,an increase in sub-cooling and saturation temperature will enhance heat transfer efficiency.The wall temperature is mostly influenced by variations in saturation temperature and is minimally related to changes in mass flux and subcooling degree.An increase in mass flux results in a greater pressure drop attributed to heightened frictional pressure loss.The variation in pressure drop with respect to sub-cooling is minimal,while an increased saturation temperature correlates with a reduced pressure drop due to the formation of smaller bubbles and lowered frictional pressure loss at high saturation pressures.This study thoroughly examines and summarizes the effects of mass flow rate,saturation temperature,and subcooling on the flow-boiling heat transfer and pressure drop characteristics of R1234yf.Furthermore,the new correlation has 93.42%of the predicted values fall within a 15%mean absolute error,exhibiting a mean absolute error of 5.75%.It provides a superior method for predicting the flow-boiling heat transfer coefficients of R1234yf in the heat sink of parallel microchannels compared to existing correlations.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0760200)the National Natural Science Foundation of China(Grant No.42377101,91744207).
文摘Exploring secondary organic aerosol(SOA)processes is crucial for understanding climate and air pollution in megacities.This study introduces a new method using positive matrix factorization(PMF)to investigate the SOA process by integrating the OA and associated ions previously misidentified as inorganic aerosol in high-resolution aerosol mass spectrometry data.The mass spectra and time series of primary OA(POA)and less oxidized oxygenated OA(OOA)identified by this new method resembled those resolved by traditional PMF.However,more oxidized OOA(MO-OOA)identified by traditional PMF can be further subdivided into multiple OA factors,including nitrogen-enriched OA(ON-OA)and sulfur-enriched OA(OS-OA)in summer,and ON-OA,OS-OA,and OOA in winter.Our findings highlight the significant role of photochemical processes in the formation of OS-OA compared to ON-OA.The compositions of reconstructed MO-OOA varied under different Ox(=O_(3)+NO_(2))and relative humidity conditions,emphasizing the limitations of using a constant mass spectrum.Aged biomass burning OA(BBOA)and coal combustion OA(CCOA),previously misattributed as POA,contributed 9.2%(0.43μg m^(−3))and 7.0%(0.33μg m^(−3))to SOA,respectively.Aged BBOA was more prone to forming OS-OA,whereas ON-OA showed higher correlations with aged CCOA,indicating distinct molecular compositions of SOA from different aged POA sources.Compared to aged BBOA,aged CCOA was more subject to conversion during aqueous phase processing.These results suggest that the variations in mass spectra and compositions need to be considered when simulating SOA processes.
基金support from the National Natural Science Foundation of China(Nos.52370100,52000146,and 51978098)China Postdoctoral Science Foundation(No.2020M673351).
文摘Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for catalyst optimization.Herein,two main types of Pd-Cu bimetallic nanocrystal structures,heterostructure and intermetallic,were prepared and characterized using high-resolution transmission electron microscopy(HRTEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that two individual Pd and Cu nanocrystals with a mixed interface exist in the heterostructure nanocrystals,while Pd and Cu atoms are uniformly distributed across the intermetallic Pd-Cu nanocrystals.The catalytic nitrate reduction experiments were carried out in a semibatch reactor under constant hydrogen flow.The nitrate conversion rate of the heterostructure Pd-Cu nanocrystals supported onα-Al_(2)O_(3),γ-Al_(2)O_(3),SBA-15,and XC-72R exhibited 3.82-,6.76-,4.28-,2.44-fold enhancements relative to the intermetallic nanocrystals,and the nitrogen and nitrite were the main products for the heterostructure and intermetallic Pd-Cu nanocrystals,respectively.This indicates that the catalytic nitrate reduction over Pd-Cu catalyst is sensitive to the bimetallic structures of the catalysts,and heterostructure bimetallic nanocrystals exhibit better catalytic performances on both the activity and selectivity,which may provide new insights into the design and optimization of catalysts to improve catalytic activity and selectivity for nitrate reduction in water.
基金the Natural Science Foundation of Xiamen,China(Grant No.:3502z20227074)NaturalScience Foundation of Fujian Province,China(Grant Nos.:2022J011405, 2022J05320)+1 种基金Fujian College Student Innovation and Entrepreneurship Training Program(Program No.:202312631008)National College Student Innovation and Entrepreneurship Training Program(Program No.:202312631003).
文摘Melanoma is characterized by high malignancy,ranking the third among skin malignancies,and is associated with lack of specific treatment options and poor prognosis.Therefore,the development of effective therapies for melanoma is imperative.A critical challenge in addressing subcutaneous disease lies in overcoming the skin barrier.In this study,we engineered a microneedle(MN)system that in-tegrates chemotherapy,photothermal therapy(PTT),and targeted therapy to enhance anti-tumor effi-cacy while effectively penetrating the skin barrier.In vitro studies have demonstrated that the MN drug delivery system(DDS)can effectively penetrate the stratum corneum of the skin,deliver therapeutics to subcutaneous tumor sites,and establish a drug reservoir at these locations to exert anti-tumor effects.Cellular experiments indicated that the engineered PTT chemotherapy-targeted MNs can be internalized by tumor cells,exhibiting enhanced cytotoxicity against them.In vivo pharmacological investigations revealed that the combination of PITT and chemotherapy delivered via this MN DDS produced synergistic anti-tumor effects,achieving a tumor inhibition rate of up to 98.15%.This in situ DDS minimizes involvement with other organs,significantly reducing chemotherapy-related side effects.In summary,the PTT chemotherapy-targeted MNs developed in this study demonstrate promising application po-tential by enhancing anti-tumor efficacy while minimizing adverse effects.
基金Supported by the State Key Development Program for Basic Research of China(2006BAC02A17)
文摘Bio-fuel can be used to help transition from a petroleum-based society to a bio-based society. Ever since the China Development and Reform Commission suspended the approval of crop processing programs, second-generation bio-ethanol research and industrialization processes have attracted significant attention. In 2020, bio-ethanol production is predicted to reach 10 million tons. Currently, there are a few domestic enterprises that have established different scaled pilot or demonstration bases for cellulosic ethanol, which reduce the cost of ethanol by continuously improving pretreatment and hydrolysis techniques. In the next three years, these enterprises will realize large-scale commercial production. Given the practical problems in cellulosic ethanol plant construction and operation(e.g., marketing price variation and difficulties in feedstock collection), this paper began with the concept of a "whole-crop refinery" and presented a solution to the integration of industry and agriculture as well as multi-crop refining. This paper then took the whole-crop refining system of corn as an example and presented an analysis of the logistics, energy flow, and economical efficiency of the system. The results demonstrated that the integrated system could properly reduce the required fixed investments in production equipment,shared utilities, and wastewater treatment facilities, as well as reduction of energy consumption. Although the proposed system has several problems, it brings the long-term goal of large-scale commercial application closer than ever.
文摘Purpose: We aimed to analyze the pregnancy outcomes and perinatal follow-up of mosaic embryo transfer in the preimplantation genetic testing (PGT) cycles. Method: We retrospectively selected 27 mosaic embryo transfer cycles as the study group and 97 euploid embryo transfer cycles as the control group after propensity score matching, which were performed in the reproductive medicine center of the Sixth Affiliated Hospital, Sun Yat-sen University, from March 2019 to September 2023. The biopsy cells from blastocyst were undertaken next generation sequencing (NGS). Results: No significant difference in pregnancy outcomes compared between the two groups. According to the size of aneuploid, fragment the level of mosaicism or blastocyst morphological gradings, there were no significant difference in mosaic embryo transfers. Conclusion: Mosaic embryo detected in the PGT cycle can lead to clinical pregnancy and live birth of healthy offspring, which can be considerate suitable for transfer.
基金financially supported by the National Key Research and Development Program of China(Grant No.2021YFB3701004)the National Natural Science Foundation of China(Grant Nos.51971054 and 52171055)the Fundamental Research Funds for the Central Universities(N2009006 and N2107007)。
文摘Due to lattice reorientation,grain segmentation,induced recrystallization,twins play a very important role in regulating texture,refining grains,improving mechanical properties and corrosion resistance,and has received more extensive attention.Numerous studies have shown that{10-12}<10-11>tensile twins(TTWs)are easily activated in large quantities due to the lower critical resolve shear stresses(CRSS).Introduction of TTWs under uniaxial compression improved the strength,ductility,and formability of magnesium(Mg)alloys.Moreover,TTWs produced by multi-directional impact forging(MDIF)can optimize the microstructure by dividing grains and promoting recrystallization,resulting in significant improvement of mechanical properties.Although{10-11}<10-12>compressive twins(CTWs)and{10-11}-{10-12}double twins(DTWs)can promote dynamic recrystallization(DRX),they are also favorable nucleation sites for cracks.In addition,the type and volume fraction of twins can affect the corrosion resistance,and they also play different roles in the corrosion process of different Mg alloys.Twins have shown great potential for improving structure and properties,but a comprehensive and critical discussion of twins in Mg alloys is still lacking.Therefore,based on previous studies,this article reviews the common types and variants of twins in Mg alloys,influencing factors,and their effects on the microstructure,mechanical properties and corrosion resistance.In addition,some interesting ideas are being proposed for further research.
基金Supported in part by Ministry of Science and Technology of the People’s Republic of China(Grant No.2017YFB0103600)Beijing Municipal Science and Technology Commission via the Beijing Nova Program(Grant No.Z201100006820007).
文摘An X-by-wire chassis can improve the kinematic characteristics of human-vehicle closed-loop system and thus active safety especially under emergency scenarios via enabling chassis coordinated control.This paper aims to provide a complete and systematic survey on chassis coordinated control methods for full X-by-wire vehicles,with the primary goal of summarizing recent reserch advancements and stimulating innovative thoughts.Driving condition identification including driver’s operation intention,critical vehicle states and road adhesion condition and integrated control of X-by-wire chassis subsystems constitute the main framework of a chassis coordinated control scheme.Under steering and braking maneuvers,different driving condition identification methods are described in this paper.These are the trigger conditions and the basis for the implementation of chassis coordinated control.For the vehicles equipped with steering-by-wire,braking-by-wire and/or wire-controlled-suspension systems,state-of-the-art chassis coordinated control methods are reviewed including the coordination of any two or three chassis subsystems.Finally,the development trends are discussed.
基金sponsored by the National Natural Science Foundation of China (Nos. 42177158, 11902249 and 11872301)Natural Science Foundation of Shaanxi Province (Shaanxi Province Natural Science Foundation) (No. 2019JQ395)Education Bureau of Shaanxi Province | Scientific Research Plan Projects of Shaanxi Education Department in China (No. 20JS093)。
文摘The constant m_(i) in the Hoek-Brown(H-B) criterion is a fundamental parameter required for determining the compressive strength of rock. In this paper, drilling parameters provide a new basis for determining the constant mi. An analytical relationship between the drilling parameters and constant miis established in consideration of the contact response between the drilling bit and the cut rock in the crushed zone.New models are developed to predict the triaxial compressive strength(TCS), internal friction angle φand cohesion c of rock. Drilling tests are carried out on 6 rock types to study the correlation between φ and m_(i). A comparison between the predicted values of rock mechanical properties and the measured values from the laboratory is performed to verify the accuracy of the proposed model(yielding an error less than 10%). The TCSs and constant m_(i) values of fifteen rocks are cited to validate the accuracy of the proposed model. The result shows that the proposed model predicts the TCS and constant m_(i) within a maximum error of 20%. The method can be conveniently applied to the rock mechanical properties.
