Mesoproterozoic Shennongjia Group in Shennongjia Area can be divided into three subgroups in ascender order. Of which the lower subgroup includes Yingwodong, Dayanping, Macaoyuan, Luanshigou, Dawokeng and Kuangshishan...Mesoproterozoic Shennongjia Group in Shennongjia Area can be divided into three subgroups in ascender order. Of which the lower subgroup includes Yingwodong, Dayanping, Macaoyuan, Luanshigou, Dawokeng and Kuangshishan formations;the middle subgroup is formed by Yemahe, Wenshuihe and Shicaohe formations;the upper subgroup consists of Songziyuan and Wagangxi formations. Stromatolites developed very well in the carbonate rocks of each subgroup in Shennongjia Group. Based on descriptions of stromatolites macrotypes and their characteristics, this paper studied the formation environments, discussed the relationship among types, sizes, abundance of stromatolites and sedimentary environment, and established the formation and development pattern of stromatolites. As a result, this research also reveals the paleoenvironment and paleoclimate during the period of the Shennongjia Group deposited, which is beneficial to the study of paleoenvironment, paleogeography and paleoclimate, stratigraphic succession and regional correlation of the northern edge of Yangtze block. Stromatolites of Shennongjia Group are mainly conical, columnar, domal, wavy, stratiform and stromatolite reefs. The columnar and conical stromatolites are well developed. Conical stromatolites are mainly monomers, with a variety of pyramidal types, ranging in diameter from a few millimeters to several meters and formed in the high energy subtidal zone and tidal lagoon environment. Most of the columnar stromatolites are medium to small sizes implied a wide and gentle slope environment at that time. Stratiform (including wavy) stromatolites are larger scales and extends far away and distributed most widely in almost every horizon in the carbonate rocks. Stratiform stromatolites can be formed in low energy environments such as subtidal and intertidal zones and supratidal belts. Wavy stromatolites often developed in the hydrodynamic energy condition from weak energy intertidal zone gradually strengthened to the below of the high energy supratidal. Although stromatolite reefs can be a single or multiform combination, they developed mainly consisted of laminar or small walled columnar and large domal stromatolites. Shicaohe Formation also partially developed large domical stromatolites, the depositional environment is from the upper intertidal to supratidal zone. Stromatolite in Shennongjia Group usually appears as a combination of “Stratiform (wavy)-dome-columnar-coniform ” or “stratiform-dome-coniform-columnar-dome-stratiform ” vertieally, which represents the seawater depth from shallower to deeper or from shallow to deep and then to shallow again. These phenomenons generally reflected a stable sea level and companied with a high frequency oscillation. Comprehensive researches on the stratigraphy, sedimentary facies, sedimentary environment and the stromatolite types and their characteristics in the Shennongjia Group indicated that the Shennongjia Area is located on a gentle slope of carbonate platform in the passive continental edge, generally, i.e., one of warm and humid climate shallow water zone or/and a cold-drought climate, and had been experienced with eustatic cycles during the Shennongjia Group deposited.展开更多
A red-emitting phosphor Ca_(2.91)Si_(2)O_(7):0.09Eu^(3+) with partial Al^(3+)/P^(5+) substitution on Si^(4+) was synthesized via a simple solid-state method,and the effects of the introduction of the M^(3+/5+)(M=Al,P)...A red-emitting phosphor Ca_(2.91)Si_(2)O_(7):0.09Eu^(3+) with partial Al^(3+)/P^(5+) substitution on Si^(4+) was synthesized via a simple solid-state method,and the effects of the introduction of the M^(3+/5+)(M=Al,P)ions on the crystal structure and photoluminescence performance of Ca_(2.91)Si_(2−x)M_(x)O_(7):0.09Eu^(3+) phosphors were investigated.The X-ray diffraction(XRD),energy-dispersive X-ray spectroscopy(EDS),and X-ray photoelectron spectroscopy(XPS)results revealed that the structure of Ca_(3)Si_(2)O_(7) remained the same after the introduction of Al^(3+) and P^(5+) ions.The characteristic emission of Eu^(3+)-doped Ca_(3)Si_(2−x)M_(x)O_(7) phosphors exhibited two main peaks at 617 nm(red)and 593 nm(orange)under excitation at 394 nm,which originated from the^(5)D_(0)→^(7)F_(2)and^(5)D_(0)→^(7)F_(1) electron transitions of Eu^(3+) ions.After the partial substitution of Al^(3+) and P^(5+),the red emission intensities of the Ca_(2.91)Si_(2)O_(7):0.09Eu^(3+) phosphors were significantly enhanced by 1.88-and 1.42-fold,respectively,which is attributed to the crystal-field effect around Eu^(3+).Meanwhile,the luminescence intensities of the Ca_(2.91)Si_(1.96)Al_(0.04)O_(7):0.09Eu^(3+) and Ca_(2.91)Si_(1.94)P_(0.06)O_(7):0.09Eu^(3+) phosphors at 210℃ were 79.36%and 77.53%of those at 30°C,respectively,indicating their excellent thermal stability.Moreover,the as-prepared Ca_(2.91)Si_(1.96)Al_(0.04)O_(7):0.09Eu^(3+)and Ca_(2.91)Si_(1.94)P_(0.06)O_(7):0.09Eu^(3+) red-emitting phosphors were combined with a near-ultraviolet chip of 395 nm to fabricate red-light-emitting diode(LED)and white(w)-LED devices with excellent chromaticity features.In summary,Al^(3+)/P^(5+)-substituted Ca_(2.91)Si_(2)O_(7):0.09Eu^(3+) can serve as red-emitting phosphors for applications in w-LEDs.展开更多
基金This research was co-supported by the National Key Research and Development Program of China (2016YFC0601001),the National Natural Science Foundation of China (41472082)China Geological Survey Projects (DD20160120-01)+1 种基金Globe Geopark of Shennongjia. We are grateful to the leaders of Shennongjia National Park and Mr. Zhixian Wang,Quan Zhong gave great assistances and warmly aidsthe field survey was under careful direction by Mr. Lesheng Qu from Hubei Geological Survey,Mr. Yuansheng Geng from Institute of Geology,CAGS. Sincere thanks are also given Mr. Zejiu Wang,Xin Shang and Mrs. Xiulan Ma from Chinese Academy of Geological Sciences (CAGS) and All China Commission of Stratigraphy.
文摘Mesoproterozoic Shennongjia Group in Shennongjia Area can be divided into three subgroups in ascender order. Of which the lower subgroup includes Yingwodong, Dayanping, Macaoyuan, Luanshigou, Dawokeng and Kuangshishan formations;the middle subgroup is formed by Yemahe, Wenshuihe and Shicaohe formations;the upper subgroup consists of Songziyuan and Wagangxi formations. Stromatolites developed very well in the carbonate rocks of each subgroup in Shennongjia Group. Based on descriptions of stromatolites macrotypes and their characteristics, this paper studied the formation environments, discussed the relationship among types, sizes, abundance of stromatolites and sedimentary environment, and established the formation and development pattern of stromatolites. As a result, this research also reveals the paleoenvironment and paleoclimate during the period of the Shennongjia Group deposited, which is beneficial to the study of paleoenvironment, paleogeography and paleoclimate, stratigraphic succession and regional correlation of the northern edge of Yangtze block. Stromatolites of Shennongjia Group are mainly conical, columnar, domal, wavy, stratiform and stromatolite reefs. The columnar and conical stromatolites are well developed. Conical stromatolites are mainly monomers, with a variety of pyramidal types, ranging in diameter from a few millimeters to several meters and formed in the high energy subtidal zone and tidal lagoon environment. Most of the columnar stromatolites are medium to small sizes implied a wide and gentle slope environment at that time. Stratiform (including wavy) stromatolites are larger scales and extends far away and distributed most widely in almost every horizon in the carbonate rocks. Stratiform stromatolites can be formed in low energy environments such as subtidal and intertidal zones and supratidal belts. Wavy stromatolites often developed in the hydrodynamic energy condition from weak energy intertidal zone gradually strengthened to the below of the high energy supratidal. Although stromatolite reefs can be a single or multiform combination, they developed mainly consisted of laminar or small walled columnar and large domal stromatolites. Shicaohe Formation also partially developed large domical stromatolites, the depositional environment is from the upper intertidal to supratidal zone. Stromatolite in Shennongjia Group usually appears as a combination of “Stratiform (wavy)-dome-columnar-coniform ” or “stratiform-dome-coniform-columnar-dome-stratiform ” vertieally, which represents the seawater depth from shallower to deeper or from shallow to deep and then to shallow again. These phenomenons generally reflected a stable sea level and companied with a high frequency oscillation. Comprehensive researches on the stratigraphy, sedimentary facies, sedimentary environment and the stromatolite types and their characteristics in the Shennongjia Group indicated that the Shennongjia Area is located on a gentle slope of carbonate platform in the passive continental edge, generally, i.e., one of warm and humid climate shallow water zone or/and a cold-drought climate, and had been experienced with eustatic cycles during the Shennongjia Group deposited.
基金This work was financially supported by the Department of Science and Technology of Sichuan Province(No.2020YJ0157).
文摘A red-emitting phosphor Ca_(2.91)Si_(2)O_(7):0.09Eu^(3+) with partial Al^(3+)/P^(5+) substitution on Si^(4+) was synthesized via a simple solid-state method,and the effects of the introduction of the M^(3+/5+)(M=Al,P)ions on the crystal structure and photoluminescence performance of Ca_(2.91)Si_(2−x)M_(x)O_(7):0.09Eu^(3+) phosphors were investigated.The X-ray diffraction(XRD),energy-dispersive X-ray spectroscopy(EDS),and X-ray photoelectron spectroscopy(XPS)results revealed that the structure of Ca_(3)Si_(2)O_(7) remained the same after the introduction of Al^(3+) and P^(5+) ions.The characteristic emission of Eu^(3+)-doped Ca_(3)Si_(2−x)M_(x)O_(7) phosphors exhibited two main peaks at 617 nm(red)and 593 nm(orange)under excitation at 394 nm,which originated from the^(5)D_(0)→^(7)F_(2)and^(5)D_(0)→^(7)F_(1) electron transitions of Eu^(3+) ions.After the partial substitution of Al^(3+) and P^(5+),the red emission intensities of the Ca_(2.91)Si_(2)O_(7):0.09Eu^(3+) phosphors were significantly enhanced by 1.88-and 1.42-fold,respectively,which is attributed to the crystal-field effect around Eu^(3+).Meanwhile,the luminescence intensities of the Ca_(2.91)Si_(1.96)Al_(0.04)O_(7):0.09Eu^(3+) and Ca_(2.91)Si_(1.94)P_(0.06)O_(7):0.09Eu^(3+) phosphors at 210℃ were 79.36%and 77.53%of those at 30°C,respectively,indicating their excellent thermal stability.Moreover,the as-prepared Ca_(2.91)Si_(1.96)Al_(0.04)O_(7):0.09Eu^(3+)and Ca_(2.91)Si_(1.94)P_(0.06)O_(7):0.09Eu^(3+) red-emitting phosphors were combined with a near-ultraviolet chip of 395 nm to fabricate red-light-emitting diode(LED)and white(w)-LED devices with excellent chromaticity features.In summary,Al^(3+)/P^(5+)-substituted Ca_(2.91)Si_(2)O_(7):0.09Eu^(3+) can serve as red-emitting phosphors for applications in w-LEDs.
