Three unique metal-organic framework coordination polymers, [Eu_2(bptc)(bdc)_2(H_2O)]_n(1), [Gd_2(bptc)(bdc)_2(H_2O)_4]_n(2) and [Dy_2(bptc)(bdc)_2(H_2O)_4]n(3)(1,2-H_2 BDC = 1,2-benzenedicarboylic acid, H_2 bptc = 4,...Three unique metal-organic framework coordination polymers, [Eu_2(bptc)(bdc)_2(H_2O)]_n(1), [Gd_2(bptc)(bdc)_2(H_2O)_4]_n(2) and [Dy_2(bptc)(bdc)_2(H_2O)_4]n(3)(1,2-H_2 BDC = 1,2-benzenedicarboylic acid, H_2 bptc = 4,4?-biphenyldicarboxylic acid) were synthesized by mixing two different multi-carboxylic acids with Ln2 O3(Ln = Eu, Gd and Dy) in hydrothermal condition. The three compounds are all three-dimensional and compounds 2 and 3 contain 4.289 × 6.507 ?~2 rectangularshaped one-dimensional open channels along the a direction. Additionally, the magnetic, luminescent and thermogravimetric properties were studied in detail.展开更多
基金supported by the National Natural Science Foundation of China(21571072)the Science and Technology Research Project of Hubei Provincial Department of Education(No.B2018198)
文摘Three unique metal-organic framework coordination polymers, [Eu_2(bptc)(bdc)_2(H_2O)]_n(1), [Gd_2(bptc)(bdc)_2(H_2O)_4]_n(2) and [Dy_2(bptc)(bdc)_2(H_2O)_4]n(3)(1,2-H_2 BDC = 1,2-benzenedicarboylic acid, H_2 bptc = 4,4?-biphenyldicarboxylic acid) were synthesized by mixing two different multi-carboxylic acids with Ln2 O3(Ln = Eu, Gd and Dy) in hydrothermal condition. The three compounds are all three-dimensional and compounds 2 and 3 contain 4.289 × 6.507 ?~2 rectangularshaped one-dimensional open channels along the a direction. Additionally, the magnetic, luminescent and thermogravimetric properties were studied in detail.
