A novel microporous indium-based MOF material with unique 3-way rod-shaped secondary building units(SBUs),UTSA-22,was reported and exhibited high methane(CH_(4))and hydrogen(H_(2))storage.At 298 K and 65 bar,the total...A novel microporous indium-based MOF material with unique 3-way rod-shaped secondary building units(SBUs),UTSA-22,was reported and exhibited high methane(CH_(4))and hydrogen(H_(2))storage.At 298 K and 65 bar,the total CH_(4) volumetric uptake of UTSA-22 is 174 cm^(3)(STP)cm^(−3).Moreover,UTSA-22 shows a high CH_(4) working capacity of 146 cm^(3)(STP)cm^(−3) in a pressure range of 5–65 bar at 298 K.In addition,UTSA-22 shows a high H_(2) gravimetric storage capacity(1.2 wt%)at 298 K and 100 bar.展开更多
基金supported by the Welch Foundation(AX-1730)the Deputyship for Research&Innovation,Ministry of Education,in Saudi Arabia for funding this research work through the project number DRI-KSU-572+1 种基金the NSFC(22101307)for its supportX-ray diffraction studies at the Molecular Foundry and Advanced Light Source was supported by the Office of Science,Office of Basic Energy Sciences,of the U.S.Department of Energy(DE-AC02-05CH11231).
文摘A novel microporous indium-based MOF material with unique 3-way rod-shaped secondary building units(SBUs),UTSA-22,was reported and exhibited high methane(CH_(4))and hydrogen(H_(2))storage.At 298 K and 65 bar,the total CH_(4) volumetric uptake of UTSA-22 is 174 cm^(3)(STP)cm^(−3).Moreover,UTSA-22 shows a high CH_(4) working capacity of 146 cm^(3)(STP)cm^(−3) in a pressure range of 5–65 bar at 298 K.In addition,UTSA-22 shows a high H_(2) gravimetric storage capacity(1.2 wt%)at 298 K and 100 bar.
