An innovative photoelectrode, TiO_2/Ti mesh electrode, was prepared by anodisation. In anodisation, 0.5 mol/L H_2SO_4 was used as electrolytic solution, the current had been constantly 1A from the beginning of the oxi...An innovative photoelectrode, TiO_2/Ti mesh electrode, was prepared by anodisation. In anodisation, 0.5 mol/L H_2SO_4 was used as electrolytic solution, the current had been constantly 1A from the beginning of the oxidation until reaching a designed voltage. Results showed that the photocatalytic activity of electrode was better when the designed voltage was 160 V. The morphology and the crystalline texture of the TiO_2 film on mesh electrode were examined by scanning electronic microscopy and Raman spectroscopy respectively. The examination results indicated that the structure and properties of the film depended on anodisation rate, and the anatase was the dominant component under the controlled experimental conditions. Degradation of Rhodamine B in photocatalytic (PC) and photoelectrocatalytic (PEC) reaction was investigated.展开更多
An innovative photoelectrode, TiO 2/Ti mesh electrode, was prepared by galvanostaticanodisation. The morphology and the crystalline texture of the TiO 2 film on mesh electrode were examined by scanning electronic mi...An innovative photoelectrode, TiO 2/Ti mesh electrode, was prepared by galvanostaticanodisation. The morphology and the crystalline texture of the TiO 2 film on mesh electrode were examined by scanning electronic microscopy and Raman spectroscopy respectively. The examination results indicated that the structure and properties of the film depended on anodisation rate, and the anatase was the dominant component under the controlled experimental conditions. Degradation of Rose Bengal(RB) in photocatalytic(PC) and photoelectrocatalytic(PEC) reaction was investigated, the results demonstrated that electric biasing could improve the efficiency of photocatalytic reaction. The measurement results of TOC in photoelectrocatalytic degradation showed that the mineralisation of RB was complete relatively. The comparison between the degradation efficiency of RB in PEC process and that in aqueous TiO 2 dispersion was conducted. The results showed that the apparent first order rate constant of RB degradation in PEC process was larger than that in aqueous dispersion with 0 1%—0 3% TiO 2 powder, but was smaller than that in aqueous dispersion with 1 0% TiO 2展开更多
The indirect electro synthesis of p tolualdehyde was studied using Mn 3+ /Mn 2+ redox couple and Mn 2+ was changes into Mn 3+ on the Pb/Sb electrode.The effects of temperature,current density,elec...The indirect electro synthesis of p tolualdehyde was studied using Mn 3+ /Mn 2+ redox couple and Mn 2+ was changes into Mn 3+ on the Pb/Sb electrode.The effects of temperature,current density,electrolytic time on current efficiency,and the electrolytic and reaction conditions of oxidiazing p xylene were also studied.The results showed that the yields of p tolualdehyde were 74 90% and the current recovery was 65 50%.The reaction solution can be used repeatedly and no wastes were produced during the p tolualdehyde production process.展开更多
基金TheScientificResearchFoundationofHarbinInstituteofTechnology (No .HIT .2 0 0 1.5 6)
文摘An innovative photoelectrode, TiO_2/Ti mesh electrode, was prepared by anodisation. In anodisation, 0.5 mol/L H_2SO_4 was used as electrolytic solution, the current had been constantly 1A from the beginning of the oxidation until reaching a designed voltage. Results showed that the photocatalytic activity of electrode was better when the designed voltage was 160 V. The morphology and the crystalline texture of the TiO_2 film on mesh electrode were examined by scanning electronic microscopy and Raman spectroscopy respectively. The examination results indicated that the structure and properties of the film depended on anodisation rate, and the anatase was the dominant component under the controlled experimental conditions. Degradation of Rhodamine B in photocatalytic (PC) and photoelectrocatalytic (PEC) reaction was investigated.
文摘An innovative photoelectrode, TiO 2/Ti mesh electrode, was prepared by galvanostaticanodisation. The morphology and the crystalline texture of the TiO 2 film on mesh electrode were examined by scanning electronic microscopy and Raman spectroscopy respectively. The examination results indicated that the structure and properties of the film depended on anodisation rate, and the anatase was the dominant component under the controlled experimental conditions. Degradation of Rose Bengal(RB) in photocatalytic(PC) and photoelectrocatalytic(PEC) reaction was investigated, the results demonstrated that electric biasing could improve the efficiency of photocatalytic reaction. The measurement results of TOC in photoelectrocatalytic degradation showed that the mineralisation of RB was complete relatively. The comparison between the degradation efficiency of RB in PEC process and that in aqueous TiO 2 dispersion was conducted. The results showed that the apparent first order rate constant of RB degradation in PEC process was larger than that in aqueous dispersion with 0 1%—0 3% TiO 2 powder, but was smaller than that in aqueous dispersion with 1 0% TiO 2
文摘The indirect electro synthesis of p tolualdehyde was studied using Mn 3+ /Mn 2+ redox couple and Mn 2+ was changes into Mn 3+ on the Pb/Sb electrode.The effects of temperature,current density,electrolytic time on current efficiency,and the electrolytic and reaction conditions of oxidiazing p xylene were also studied.The results showed that the yields of p tolualdehyde were 74 90% and the current recovery was 65 50%.The reaction solution can be used repeatedly and no wastes were produced during the p tolualdehyde production process.
