The current study conducted the psychological capital profiles and the relation between profile memberships and learning burnout among undergraduates.Participants were 541 Chinese undergraduates ranging from 18 to 21 ...The current study conducted the psychological capital profiles and the relation between profile memberships and learning burnout among undergraduates.Participants were 541 Chinese undergraduates ranging from 18 to 21 years old(48.2%male;Mean years=19.54,SD=1.09 years).Latent profile analysis revealed three categories of psychological capital profile consistent high psychological capital profile(50.5%),consistent low psychological capital profile(38.1%),and dominate loss-orientated psychological capital profile(11.4%).The undergraduates in consistent high profile reported high self-efficacy,resilience,hope,and optimism.Consistent low profile characterized by a little low(~0.50 SD below the M)self-efficacy,resilience,hope,and optimism.Dominant loss-orientated profile displayed low self-efficacy,hope,optimism,but a little relatively high resilience.Specifically,undergraduates in consistent high profile exhibited low level of learning burnout;while undergraduates with low level of psychological capital(i.e.,consistent low profile and dominate loss-orientated profile)reported high level of learning burnout.The findings have theoretical significance which provides important knowledge about psychological capital profile among Chinese undergraduates.They have practical implications for student counselling and development providing person-centric support to students based on their individual psychological profiles.展开更多
Environmental pollution from persistent pharmaceuticals like carbamazepine(CBZ)poses severe risks to aquatic ecosystems and human health,yet conventional treatments struggle with low concentrations and secondary pollu...Environmental pollution from persistent pharmaceuticals like carbamazepine(CBZ)poses severe risks to aquatic ecosystems and human health,yet conventional treatments struggle with low concentrations and secondary pollution.Piezo-photocatalysis,which harnesses mechanical and solar energies to drive charge separation,offers a promising alternative using materials such as molybdenum disulfide(MoS_(2)),whose layered structure enables tunable piezoelectricity but is hindered by rapid electron-hole recombination and structural instability.However,the mechanistic role of oxygen doping in repairing sulfur vacancies and enhancing symmetry-breaking for improved performance remains underexplored.Here we show that hydrothermally synthesized oxygen-doped MoS_(2)(O 5-MoS_(2))fully degrades 2 mg L^(-1)CBZ in 25 min under combined ultrasound and visible light,achieving a rate constant(k obs)of 0.13 min^(-1)—11.4 times higher than undoped MoS_(2).This stems from oxygen substitution narrowing the bandgap to 1.94 eV,boosting the piezoelectric coefficient to 63 p.m.V^(-1)(versus 26 p.m.V^(-1)),and generating a 0.19 V built-in potential that drives charge separation,as confirmed by 4.18μA cm^(-2)synergistic photocurrents,density functional theory calculations revealing heightened Mo-O charge transfer(2.08-2.36 e^(-)),and finite element simulations of deformation-induced fields.Over five cycles,O 5-MoS_(2)retains 100%efficiency with minimal Mo leaching(1.9%),reducing product toxicity across fish,daphnid,and algal models.These findings delineate oxygen doping's dual role in defect mitigation and polarization enhancement,paving the way for robust piezo-photocatalytic systems in real-world water purification.展开更多
基金supported by Hunan Province Education Department Outstanding Youth Project(23B1131)Hunan Province Education Science Fourteenth Five-Year Plan Project(XJK24BXL003).
文摘The current study conducted the psychological capital profiles and the relation between profile memberships and learning burnout among undergraduates.Participants were 541 Chinese undergraduates ranging from 18 to 21 years old(48.2%male;Mean years=19.54,SD=1.09 years).Latent profile analysis revealed three categories of psychological capital profile consistent high psychological capital profile(50.5%),consistent low psychological capital profile(38.1%),and dominate loss-orientated psychological capital profile(11.4%).The undergraduates in consistent high profile reported high self-efficacy,resilience,hope,and optimism.Consistent low profile characterized by a little low(~0.50 SD below the M)self-efficacy,resilience,hope,and optimism.Dominant loss-orientated profile displayed low self-efficacy,hope,optimism,but a little relatively high resilience.Specifically,undergraduates in consistent high profile exhibited low level of learning burnout;while undergraduates with low level of psychological capital(i.e.,consistent low profile and dominate loss-orientated profile)reported high level of learning burnout.The findings have theoretical significance which provides important knowledge about psychological capital profile among Chinese undergraduates.They have practical implications for student counselling and development providing person-centric support to students based on their individual psychological profiles.
基金supported by the National Natural Science Foundation of China(Grant No.52270055)the Fundamental Research Funds for the Central Universities(Grant No.BUCTRC202209).
文摘Environmental pollution from persistent pharmaceuticals like carbamazepine(CBZ)poses severe risks to aquatic ecosystems and human health,yet conventional treatments struggle with low concentrations and secondary pollution.Piezo-photocatalysis,which harnesses mechanical and solar energies to drive charge separation,offers a promising alternative using materials such as molybdenum disulfide(MoS_(2)),whose layered structure enables tunable piezoelectricity but is hindered by rapid electron-hole recombination and structural instability.However,the mechanistic role of oxygen doping in repairing sulfur vacancies and enhancing symmetry-breaking for improved performance remains underexplored.Here we show that hydrothermally synthesized oxygen-doped MoS_(2)(O 5-MoS_(2))fully degrades 2 mg L^(-1)CBZ in 25 min under combined ultrasound and visible light,achieving a rate constant(k obs)of 0.13 min^(-1)—11.4 times higher than undoped MoS_(2).This stems from oxygen substitution narrowing the bandgap to 1.94 eV,boosting the piezoelectric coefficient to 63 p.m.V^(-1)(versus 26 p.m.V^(-1)),and generating a 0.19 V built-in potential that drives charge separation,as confirmed by 4.18μA cm^(-2)synergistic photocurrents,density functional theory calculations revealing heightened Mo-O charge transfer(2.08-2.36 e^(-)),and finite element simulations of deformation-induced fields.Over five cycles,O 5-MoS_(2)retains 100%efficiency with minimal Mo leaching(1.9%),reducing product toxicity across fish,daphnid,and algal models.These findings delineate oxygen doping's dual role in defect mitigation and polarization enhancement,paving the way for robust piezo-photocatalytic systems in real-world water purification.
