Electrically conductive carbide ceramics with high hardness and fracture toughness are promising for advanced applications.However,enhancing both electrical conductivity and fracture toughness simultaneous is challeng...Electrically conductive carbide ceramics with high hardness and fracture toughness are promising for advanced applications.However,enhancing both electrical conductivity and fracture toughness simultaneous is challenging.This study reports the synthesis of(Ti_(0.2)W_(0.2)Ta_(0.2)Hf_(0.2)Mo_(0.2))C-diamond composites with varying densities using high-pressure and high-temperature(HPHT)method.The carbides are uniformly dispersed in a titanium carbide matrix,forming conductive channels that reduce resistivity to 4.6×10^(-7)W·m.These composite materials exhibit metallic conductivity with a superconducting transition at 8.5 K.Superconducting behavior may result from d-p orbital hybridization and electron-phonon coupling in transition metal carbides,such as TaC,Mo_(2)C,and MoC.Optimizing intergranular bonding improves the fracture toughness without compromising hardness.The highest indentation toughness value is 10.1±0.4 MPa·m^(1/2),a 130%increase compare to pure TiC.Enhanced toughness arises from transgranular and intergranular fracture modes,multiple crack bridging,and large-angle crack deflection,which dissipate fracture energy and inhibit crack propagation.This study introduces a novel microstructure engineering strategy for carbide ceramics to achieve superior mechanical and electrical properties.展开更多
Large-volume presses(LVPs)providing large volumes,liquid media,deformation capability,jump compression,and in situ measurements are in great demand for high-pressure research,particularly in the fields of geoscience,c...Large-volume presses(LVPs)providing large volumes,liquid media,deformation capability,jump compression,and in situ measurements are in great demand for high-pressure research,particularly in the fields of geoscience,condensed matter physics,material science,chemistry,and biology.A high-pressure and high-temperature(HPHT)platform with different LVP subsystems,both solid-state and liquid environments,and nonequilibrium subsystems,has been constructed at the Synergetic Extreme Condition User Facility,Jilin University.This article describes the construction of the different subsystems and provides an overview of the capabilities and characteristics of the different HPHT subsystems.A large sample volume(1000 mm^(3))at 20 GPa is achieved through the use of a belt-type apparatus in the solid-state subsystem.HPHT conditions(1.8 GPa and 1000 K)are realized in the liquid subsystem through the use of a piston-cylinder-type LVP with optical diamond windows for in situ spectroscopic measurements.A maximum pressure jump to 10.2 GPa can be reached within 20 ms in the nonequilibrium subsystem with the use of an improved bladder-pressurization jump press.Some typical results obtained with different LVPs are briefly reviewed to illustrate the applications and advantages of these presses.In summary,the platform described here has the potential to contribute greatly to high-pressure research and to innovations in high-pressure technology.展开更多
The Seebeck effect measures the electric potential built up in materials under a temperature gradient.For organic thermoelectric materials,the Seebeck coefficient shows more complicated temperature dependence than con...The Seebeck effect measures the electric potential built up in materials under a temperature gradient.For organic thermoelectric materials,the Seebeck coefficient shows more complicated temperature dependence than conventional systems,with both monotonic increases and nonmonotonic behavior,that is,first increasing and then decreasing.The mechanism behind the phenomenon is intriguing.Through first-principles calculations coupled with the Boltzmann transport equation,we demonstrate typical trends of the Seebeck coefficient with respect to temperature through band structure analysis.展开更多
基金support from the Science and Technology Development Project of Jilin Province(Grant No.SKL202402004)the Program for the Development of Science and Technology of Jilin Province(Grant No.YDZJ202201ZYTS308)the Open Research Fund of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry(Jilin University,Grant Nos.2022-16 and 2022-23).
文摘Electrically conductive carbide ceramics with high hardness and fracture toughness are promising for advanced applications.However,enhancing both electrical conductivity and fracture toughness simultaneous is challenging.This study reports the synthesis of(Ti_(0.2)W_(0.2)Ta_(0.2)Hf_(0.2)Mo_(0.2))C-diamond composites with varying densities using high-pressure and high-temperature(HPHT)method.The carbides are uniformly dispersed in a titanium carbide matrix,forming conductive channels that reduce resistivity to 4.6×10^(-7)W·m.These composite materials exhibit metallic conductivity with a superconducting transition at 8.5 K.Superconducting behavior may result from d-p orbital hybridization and electron-phonon coupling in transition metal carbides,such as TaC,Mo_(2)C,and MoC.Optimizing intergranular bonding improves the fracture toughness without compromising hardness.The highest indentation toughness value is 10.1±0.4 MPa·m^(1/2),a 130%increase compare to pure TiC.Enhanced toughness arises from transgranular and intergranular fracture modes,multiple crack bridging,and large-angle crack deflection,which dissipate fracture energy and inhibit crack propagation.This study introduces a novel microstructure engineering strategy for carbide ceramics to achieve superior mechanical and electrical properties.
基金supported by the Major National Science and Technology Infrastructurethe National Natural Science Foundation of China(Grant No.12204254)the National Major Science Facility Synergetic Extreme Condition User Facility Achievement Transformation Platform Construction(Grant No.2021FGWCXNLJSKJ01)。
文摘Large-volume presses(LVPs)providing large volumes,liquid media,deformation capability,jump compression,and in situ measurements are in great demand for high-pressure research,particularly in the fields of geoscience,condensed matter physics,material science,chemistry,and biology.A high-pressure and high-temperature(HPHT)platform with different LVP subsystems,both solid-state and liquid environments,and nonequilibrium subsystems,has been constructed at the Synergetic Extreme Condition User Facility,Jilin University.This article describes the construction of the different subsystems and provides an overview of the capabilities and characteristics of the different HPHT subsystems.A large sample volume(1000 mm^(3))at 20 GPa is achieved through the use of a belt-type apparatus in the solid-state subsystem.HPHT conditions(1.8 GPa and 1000 K)are realized in the liquid subsystem through the use of a piston-cylinder-type LVP with optical diamond windows for in situ spectroscopic measurements.A maximum pressure jump to 10.2 GPa can be reached within 20 ms in the nonequilibrium subsystem with the use of an improved bladder-pressurization jump press.Some typical results obtained with different LVPs are briefly reviewed to illustrate the applications and advantages of these presses.In summary,the platform described here has the potential to contribute greatly to high-pressure research and to innovations in high-pressure technology.
基金supported by the National Natural Science Foundation of China through the project“Science Center for Luminescence from Molecular Aggregates”(SCELMAgrant no.201788102)the Ministry of Science and Technology of China through the National Key R&D Plan(grant no.2017YFA0204501).
文摘The Seebeck effect measures the electric potential built up in materials under a temperature gradient.For organic thermoelectric materials,the Seebeck coefficient shows more complicated temperature dependence than conventional systems,with both monotonic increases and nonmonotonic behavior,that is,first increasing and then decreasing.The mechanism behind the phenomenon is intriguing.Through first-principles calculations coupled with the Boltzmann transport equation,we demonstrate typical trends of the Seebeck coefficient with respect to temperature through band structure analysis.
