Oxide dispersion strengthened(ODS)alloys are extensively used owing to high thermostability and creep strength contributed from uniformly dispersed fine oxides particles.However,the existence of these strengthening pa...Oxide dispersion strengthened(ODS)alloys are extensively used owing to high thermostability and creep strength contributed from uniformly dispersed fine oxides particles.However,the existence of these strengthening particles also deteriorates the processability and it is of great importance to establish accurate processing maps to guide the thermomechanical processes to enhance the formability.In this study,we performed particle swarm optimization-based back propagation artificial neural network model to predict the high temperature flow behavior of 0.25wt%Al2O3 particle-reinforced Cu alloys,and compared the accuracy with that of derived by Arrhenius-type constitutive model and back propagation artificial neural network model.To train these models,we obtained the raw data by fabricating ODS Cu alloys using the internal oxidation and reduction method,and conducting systematic hot compression tests between 400 and800℃with strain rates of 10^(-2)-10 S^(-1).At last,processing maps for ODS Cu alloys were proposed by combining processing parameters,mechanical behavior,microstructure characterization,and the modeling results achieved a coefficient of determination higher than>99%.展开更多
Hetero-deformation induced(HDI) strengthening generally yields a weak effect on the mechanical property improvement of particle-reinforced metal matrix composites(MMCs). In the present work, a novel strategy was repor...Hetero-deformation induced(HDI) strengthening generally yields a weak effect on the mechanical property improvement of particle-reinforced metal matrix composites(MMCs). In the present work, a novel strategy was reported to induce remarkable HDI strengthening in MMCs by selecting a reinforcing material with excellent geometrically necessary dislocation(GND) storage ability. The viability of the proposed strategy was tested on additively manufactured nickel matrix composites consisting of Inconel 625 alloy(IN625) as the matrix and high-entropy alloy VNbMoTa as the reinforcing material. It was found that the average grain size and dislocation density of the additively manufactured MMCs gradually decreased with the increase in the additional amount of VNbMoTa. All the samples possessed a similar two-layer VNbMoTa-matrix interface structure containing a high-entropy alloy layer and a Laves phase layer;however, the interface width varied. This two-layer interface could hold GND pile-ups without breaking to ensure a good load transfer effect, and ductile VNbMoTa particles demonstrated excellent GND storage capacity to induce significant HDI stress. The HDI stress for the IN625-(10 wt%)VNbMoTa sample was approximately 200 MPa higher than that for the pure IN625 alloy, resulting in an excellent strength-ductility synergy. The yield strength and elongation of the IN625-(10 wt%)VNbMoTa sample reached(1 032.5 ± 18.8)MPa and(11.8 ± 1.2)%, respectively. In addition, the IN625-(10 wt%)VNbMoTa composite also demonstrated superior mechanical properties at 650℃ that were comparable to those at room temperature, implying that VNbMoTa addition remarkably limited strength reduction caused by temperature. Deformable VNbMoTa particles effectively alleviated the stress concentration, delayed the crack initiation, generated more dislocations and pile-ups, and, in turn, improved the overall high-temperature strength of composites.展开更多
Customized heat treatment is essential for enhancing the mechanical properties of additively manufactured metallic materials,especially for alloys with complex phase constituents and heterogenous microstructure.Howeve...Customized heat treatment is essential for enhancing the mechanical properties of additively manufactured metallic materials,especially for alloys with complex phase constituents and heterogenous microstructure.However,the interrelated evolutions of different microstructure features make it difficult to establish optimal heat treatment processes.Herein,we proposed a method for customized heat treatment process exploration and establishment to overcome this challenge for such kind of alloys,and a wire arc additively manufactured(WAAM)Mg-Gd-Y-Zn-Zr alloy with layered heterostructure was used for feasibility verification.Through this method,the optimal microstructures(fine grain,controllable amount of long period stacking ordered(LPSO)structure and nano-scaleβ'precipitates)and the corresponding customized heat treatment processes(520°C/30 min+200°C/48 h)were obtained to achieve a good combination of a high strength of 364 MPa and a considerable elongation of 6.2%,which surpassed those of other state-of-the-art WAAM-processed Mg alloys.Furthermore,we evidenced that the favorable effect of the undeformed LPSO structures on the mechanical properties was emphasized only when the nano-scaleβ'precipitates were present.It is believed that the findings promote the application of magnesium alloy workpieces and help to establish customized heat treatment processes for additively manufactured materials.展开更多
Hafnium-based ferroelectric films,remaining their ferroelectricity down to nanoscale thickness,present a promising application for low-power logic devices and nonvolatile memories.It has been appealing for researchers...Hafnium-based ferroelectric films,remaining their ferroelectricity down to nanoscale thickness,present a promising application for low-power logic devices and nonvolatile memories.It has been appealing for researchers to reduce the required temperature to obtain the ferroelectric phase in hafnium-based ferroelectric films for applications such as flexible and wearable electronics.This work demonstrates that a remanent polarization(P_(r))value of>5μC/cm^(2)can be obtained in asdeposited Hf_(0.5)Zr_(0.5)O_(2)(HZO)films that are fabricated by thermal atomic layer deposition(TALD)under low temperature of 250℃.The ferroelectric orthorhombic phase(o-phase)in the as-deposited HZO films is detected by scanning transmission electron microscopy(STEM).This low fabrication temperature further extends the compatibility of ferroelectric HZO films to flexible electronics and avoids the cost imposed by following high-temperature annealing treatments.展开更多
基金financial support of the National Natural Science Foundation of China(No.52371103)the Fundamental Research Funds for the Central Universities,China(No.2242023K40028)+1 种基金the Open Research Fund of Jiangsu Key Laboratory for Advanced Metallic Materials,China(No.AMM2023B01).financial support of the Research Fund of Shihezi Key Laboratory of AluminumBased Advanced Materials,China(No.2023PT02)financial support of Guangdong Province Science and Technology Major Project,China(No.2021B0301030005)。
文摘Oxide dispersion strengthened(ODS)alloys are extensively used owing to high thermostability and creep strength contributed from uniformly dispersed fine oxides particles.However,the existence of these strengthening particles also deteriorates the processability and it is of great importance to establish accurate processing maps to guide the thermomechanical processes to enhance the formability.In this study,we performed particle swarm optimization-based back propagation artificial neural network model to predict the high temperature flow behavior of 0.25wt%Al2O3 particle-reinforced Cu alloys,and compared the accuracy with that of derived by Arrhenius-type constitutive model and back propagation artificial neural network model.To train these models,we obtained the raw data by fabricating ODS Cu alloys using the internal oxidation and reduction method,and conducting systematic hot compression tests between 400 and800℃with strain rates of 10^(-2)-10 S^(-1).At last,processing maps for ODS Cu alloys were proposed by combining processing parameters,mechanical behavior,microstructure characterization,and the modeling results achieved a coefficient of determination higher than>99%.
基金supported by National Natural Science Foundation of China(Grant No.52305419)Aeronautical Science Foundation Funded by Chinese Aeronautical Establishment(Grant No.2022Z0490T6001)+5 种基金Research Start-up Project of Xi’an University of Technology(Grant No.101-256082204)Technology Foundation for Selected Overseas Chinese Scholar(Grant No.2023-010)International Science and Technology Cooperation Program of Shaanxi Province(Grant No.2023-GHZD-50)Projects of Major Innovation Platforms for Scientific and Technological and Local Transformation of Scientific and Technological Achievements of Xi’an(Grant No.20GXSF0003)Higher Education Institution Discipline Innovation and Intelligence Base of Shaanxi Provincial(Grant No.S2021-ZCGXYZ-0011)Natural Science Basic Research Program of Shaanxi(Grant No.2023-JC-YB-412).
文摘Hetero-deformation induced(HDI) strengthening generally yields a weak effect on the mechanical property improvement of particle-reinforced metal matrix composites(MMCs). In the present work, a novel strategy was reported to induce remarkable HDI strengthening in MMCs by selecting a reinforcing material with excellent geometrically necessary dislocation(GND) storage ability. The viability of the proposed strategy was tested on additively manufactured nickel matrix composites consisting of Inconel 625 alloy(IN625) as the matrix and high-entropy alloy VNbMoTa as the reinforcing material. It was found that the average grain size and dislocation density of the additively manufactured MMCs gradually decreased with the increase in the additional amount of VNbMoTa. All the samples possessed a similar two-layer VNbMoTa-matrix interface structure containing a high-entropy alloy layer and a Laves phase layer;however, the interface width varied. This two-layer interface could hold GND pile-ups without breaking to ensure a good load transfer effect, and ductile VNbMoTa particles demonstrated excellent GND storage capacity to induce significant HDI stress. The HDI stress for the IN625-(10 wt%)VNbMoTa sample was approximately 200 MPa higher than that for the pure IN625 alloy, resulting in an excellent strength-ductility synergy. The yield strength and elongation of the IN625-(10 wt%)VNbMoTa sample reached(1 032.5 ± 18.8)MPa and(11.8 ± 1.2)%, respectively. In addition, the IN625-(10 wt%)VNbMoTa composite also demonstrated superior mechanical properties at 650℃ that were comparable to those at room temperature, implying that VNbMoTa addition remarkably limited strength reduction caused by temperature. Deformable VNbMoTa particles effectively alleviated the stress concentration, delayed the crack initiation, generated more dislocations and pile-ups, and, in turn, improved the overall high-temperature strength of composites.
基金supported by the Projects of Major Scientific and Technological Achievements Local Transformation of Xi’an(2022JH-ZDZH-0039)International Science and Technology Cooperation Program of Shaanxi Province (2023-GHZD-50)+9 种基金Project of Qin Chuangyuan ‘Scientist+Engineer’team constructionKey R&D plan of Shaanxi Province (S2023-YF-QCYK-0001-237)Projects of Major Scientific and Technological Achievements Local Transformation of Xi’an (2022JH-ZDZH-0039)National Natural Science Foundation of China (52101134)Natural Science Foundation of Guangdong Province (2022A1515010275)Scientific Research Program Funded by Shaanxi Provincial Education Department (22JK0479)Doctoral Dissertations Innovation Fund of Xi’an University of Technology (101-252072305)Research Start-up Project of Xi’an University of Technology(101-256082204)Natural Science Foundation of Shaanxi Province (2023-JC-QN-0573)Natural Science Basic Research Program of Shaanxi(2023-JC-YB-412)
文摘Customized heat treatment is essential for enhancing the mechanical properties of additively manufactured metallic materials,especially for alloys with complex phase constituents and heterogenous microstructure.However,the interrelated evolutions of different microstructure features make it difficult to establish optimal heat treatment processes.Herein,we proposed a method for customized heat treatment process exploration and establishment to overcome this challenge for such kind of alloys,and a wire arc additively manufactured(WAAM)Mg-Gd-Y-Zn-Zr alloy with layered heterostructure was used for feasibility verification.Through this method,the optimal microstructures(fine grain,controllable amount of long period stacking ordered(LPSO)structure and nano-scaleβ'precipitates)and the corresponding customized heat treatment processes(520°C/30 min+200°C/48 h)were obtained to achieve a good combination of a high strength of 364 MPa and a considerable elongation of 6.2%,which surpassed those of other state-of-the-art WAAM-processed Mg alloys.Furthermore,we evidenced that the favorable effect of the undeformed LPSO structures on the mechanical properties was emphasized only when the nano-scaleβ'precipitates were present.It is believed that the findings promote the application of magnesium alloy workpieces and help to establish customized heat treatment processes for additively manufactured materials.
基金Project supported by the National Key Research and Development Program of China(Grant No.2021YFA1200700)the National Natural Science Foundation of China(Grant Nos.T2222025 and 62174053)+5 种基金the Open Research Projects of Zhejiang Laboratory(Grant No.2021MD0AB03)the Shanghai Science and Technology Innovation Action Plan(Grant Nos.21JC1402000 and 21520714100)the Guangdong Provincial Key Laboratory Program(Grant No.2021B1212040001)the Fundamental Research Funds for the Central Universitiessupport from the Zuckerman STEM Leadership ProgramPazy Research Foundation(Grant No.149-2020)。
文摘Hafnium-based ferroelectric films,remaining their ferroelectricity down to nanoscale thickness,present a promising application for low-power logic devices and nonvolatile memories.It has been appealing for researchers to reduce the required temperature to obtain the ferroelectric phase in hafnium-based ferroelectric films for applications such as flexible and wearable electronics.This work demonstrates that a remanent polarization(P_(r))value of>5μC/cm^(2)can be obtained in asdeposited Hf_(0.5)Zr_(0.5)O_(2)(HZO)films that are fabricated by thermal atomic layer deposition(TALD)under low temperature of 250℃.The ferroelectric orthorhombic phase(o-phase)in the as-deposited HZO films is detected by scanning transmission electron microscopy(STEM).This low fabrication temperature further extends the compatibility of ferroelectric HZO films to flexible electronics and avoids the cost imposed by following high-temperature annealing treatments.
