Interface engineering is an effective and feasible method to regulate the magnetic anisotropy of films by altering interfacial states between films.Using the technique of pulsed laser deposition,we prepared La_(0.67)S...Interface engineering is an effective and feasible method to regulate the magnetic anisotropy of films by altering interfacial states between films.Using the technique of pulsed laser deposition,we prepared La_(0.67)Sr_(0.33)MnO_(3)(LSMO)and La_(0.67)Sr_(0.33)MnO_(3)/SrCoO_(2.5)(LSMO/SCO)films on(110)-oriented La_(0.3)Sr_(0.7)Al_(0.65)Ta_(0.35)O_(3) substrates.By covering the SCO film above the LSMO film,we transformed the easy magnetization axis of LSMO from the[001]axis to the[110]axis in the film plane.Based on statistical analyses,we find that the corresponding Mn-Mn ionic distances are different in the two types of LSMO films,causing different distortions of Mn-O octahedron in LSMO.In addition,it also induces diverse electronic occupation states in Mn^(3+)ions.The e_(g) electron of Mn^(3+)occupies 3z^(2)-r^(2) and x^(2)-y^(2) orbitals in the LSMO and LSMO/SCO,respectively.We conclude that the electronic spin reorientation leads to the transformation of the easy magnetization axis in the LSMO films.展开更多
2D MoTe_(2),WTe_(2) and their alloys have received intensive research interest because of their unique properties arising from the polymorph structures,chiral anomaly,strong spin-orbit coupling,and so on.In this revie...2D MoTe_(2),WTe_(2) and their alloys have received intensive research interest because of their unique properties arising from the polymorph structures,chiral anomaly,strong spin-orbit coupling,and so on.In this review,we have summarized recent advances of 2D MoTe_(2),WTe_(2) and their alloys from the materials perspective with special focus on the synthesis,electrical and magnetic properties.The polymorph structures of MoTe_(2),WTe_(2) and their alloys are presented first and then the preparation methods have been discussed,including mechanical exfoliation,metal-organic chemical vapor deposition(MOCVD),molecular beam epitaxy(MBE),chemical vapor deposition(CVD)and solution-phase method.After that,fascinating physical properties arising from the large spin-orbit coupling and non-trivial band structures have been summarized,including phase transition,optoelectri-cal properties,Weyl semimetal state,superconducting and ferromagnetism.At last,potential device applications of MoTe_(2),WTe_(2) and their alloys are reviewed,including field-effect transistors(FETs),memory devices,spin-to-charge conversion,solar cells,and so on.展开更多
基金the National Key Research Program of China(Grant Nos.2017YFA0206200,2016YFA0300701,and2018YFA0208402)the National Natural Science Foundation of China(Grant Nos.11934017,11874413,11574376,and 51972333)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB33030200)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.2019009)。
文摘Interface engineering is an effective and feasible method to regulate the magnetic anisotropy of films by altering interfacial states between films.Using the technique of pulsed laser deposition,we prepared La_(0.67)Sr_(0.33)MnO_(3)(LSMO)and La_(0.67)Sr_(0.33)MnO_(3)/SrCoO_(2.5)(LSMO/SCO)films on(110)-oriented La_(0.3)Sr_(0.7)Al_(0.65)Ta_(0.35)O_(3) substrates.By covering the SCO film above the LSMO film,we transformed the easy magnetization axis of LSMO from the[001]axis to the[110]axis in the film plane.Based on statistical analyses,we find that the corresponding Mn-Mn ionic distances are different in the two types of LSMO films,causing different distortions of Mn-O octahedron in LSMO.In addition,it also induces diverse electronic occupation states in Mn^(3+)ions.The e_(g) electron of Mn^(3+)occupies 3z^(2)-r^(2) and x^(2)-y^(2) orbitals in the LSMO and LSMO/SCO,respectively.We conclude that the electronic spin reorientation leads to the transformation of the easy magnetization axis in the LSMO films.
基金support from NSFC(21822502)the Key Research Program of Frontier Sciences of CAS(QYZDB-SSWSYS031)+1 种基金the Strategic Priority Research Program of CAS(XDB30000000)Y.C.acknowledges support from the National Basic Research of China(2017YFA0206300)and NSFC(51972335).
文摘2D MoTe_(2),WTe_(2) and their alloys have received intensive research interest because of their unique properties arising from the polymorph structures,chiral anomaly,strong spin-orbit coupling,and so on.In this review,we have summarized recent advances of 2D MoTe_(2),WTe_(2) and their alloys from the materials perspective with special focus on the synthesis,electrical and magnetic properties.The polymorph structures of MoTe_(2),WTe_(2) and their alloys are presented first and then the preparation methods have been discussed,including mechanical exfoliation,metal-organic chemical vapor deposition(MOCVD),molecular beam epitaxy(MBE),chemical vapor deposition(CVD)and solution-phase method.After that,fascinating physical properties arising from the large spin-orbit coupling and non-trivial band structures have been summarized,including phase transition,optoelectri-cal properties,Weyl semimetal state,superconducting and ferromagnetism.At last,potential device applications of MoTe_(2),WTe_(2) and their alloys are reviewed,including field-effect transistors(FETs),memory devices,spin-to-charge conversion,solar cells,and so on.
