Codonopsis pilosula is a major Qi-tonifying medicinal herb,and its active composition is analyzed systematically.However,the relationship between its production origins and commodity specification grades with the acti...Codonopsis pilosula is a major Qi-tonifying medicinal herb,and its active composition is analyzed systematically.However,the relationship between its production origins and commodity specification grades with the active composition of C.pilosula lacks systematic research.This study integrates the HPLC and UV-Vis methodologies to evaluate the quality of C.pilosula from commodity specification grades and different origins,and it explores the correlation between ecological factors and production origins with active components.Here,network pharmacology is used to determine that lobetyolin,syringin,and tangshenoside I have potential efficacy in treating pulmonary fibrosis and oxidative stress.The HPLC and UV-Vis methods were employed to quantitatively analyse the levels of five active compounds from different origins and commodity specification grades.Ecological factors were collected from the different production origins with ArcGIS,and correlation analysis was conducted between these factors and the active components of C.pilosula to identify the key ecological influences that drive the accumulation of active compounds.Results showed that network pharmacology analyses indicated that the active components of C.pilosula,including lobetyolin,syringin,and tangshenoside I,bind to targets and exhibit antioxidant and antipulmonary fibrosis effects.Differences in the contents of active components across three commodity specification grades were not significant.The contents of active components in C.pilosula showed differences with varying origins,with the most variation observed in soluble sugar content,and notable variations are also observed in the levels of lobetyolin,syringin,and tangshenoside I,which could serve as potential biomarkers for different origins.Additionally,ecological factors influenced the accumulation of C.pilosula’s active components.The contents of soluble sugars and tangshenoside I were positively correlated with temperature and precipitation.Our study evaluated the active components of C.pilosula,and findings show that lobetyolin,syringin,and tangshenoside I have potential efficacy in treating pulmonary fibrosis and oxidative stress.The differences in the quality of C.pilosula across varying commodity specification grades are not significant.The different contents of C.pilosula across varying origins are significant,with soluble sugars and glycosides serving as potential markers for distinguishing C.pilosula from different origins.Moreover,ecological factors drove the accumulation of C.pilosula components.Soluble sugars and tangshenoside I content were particularly influenced by temperature and precipitation.Sand content and electrical conductivity significantly correlated with syringin,whereas organic carbon negatively influenced total flavonoids.This research provides a theoretical basis for the selection of the C.pilosula growing area and lays a foundation for the study of the C.pilosula quality standard.展开更多
High-temperature proton exchange membranes(HT-PEMs) possess excellent thermal and outstanding electrochemical stability, providing an avenue to realize high-temperature proton exchange membranes fuel cells(HT-PEMFCs) ...High-temperature proton exchange membranes(HT-PEMs) possess excellent thermal and outstanding electrochemical stability, providing an avenue to realize high-temperature proton exchange membranes fuel cells(HT-PEMFCs) with both superior power density and long-term durability. Unfortunately, polybenzimidazole(PBI), a typical material for conventional HT-PEMs, fails to compromise the high nonaqueous proton conductivity and high mechanical properties, thus hindering their practical applications.Achieving efficient nonaqueous proton conduction is crucial for HT-PEMFC, and many insightful research works have been done in this area. However, there still lacks a report that integrates the host-vip interactions of phosphoric acid doping and the structural stability of polymers to systematically illustrate modification strategies. Here, we summarize recent advancements in enhancing the nonaqueous proton conduction of HT-PEMs. Various polymer structure modification strategies, including main chain and side group modification, cross-linking, blocking, and branching, are reviewed. Composite approaches of polymer, including compounding with organic porous polymers, filling the inorganic components and modifying with ionic liquids, etc., are also covered in this work. These strategies endow the HT-PEMs with more free volume, nanophase-separated structure, and multi-stage proton transfer channels, which can facilitate the proton transportation and improve their performance. Finally, current challenges and future directions for further enhancements are also outlined.展开更多
Memtransistors in which the source-drain channel conductance can be nonvolatilely manipulated through the gate signals have emerged as promising components for implementing neuromorphic computing.On the other side,it ...Memtransistors in which the source-drain channel conductance can be nonvolatilely manipulated through the gate signals have emerged as promising components for implementing neuromorphic computing.On the other side,it is known that the complementary metal-oxide-semiconductor(CMOS)field effect transistors have played the fundamental role in the modern integrated circuit technology.Therefore,will complementary memtransistors(CMT)also play such a role in the future neuromorphic circuits and chips?In this review,various types of materials and physical mechanisms for constructing CMT(how)are inspected with their merits and need-to-address challenges discussed.Then the unique properties(what)and poten-tial applications of CMT in different learning algorithms/scenarios of spiking neural networks(why)are reviewed,including super-vised rule,reinforcement one,dynamic vision with in-sensor computing,etc.Through exploiting the complementary structure-related novel functions,significant reduction of hardware consuming,enhancement of energy/efficiency ratio and other advan-tages have been gained,illustrating the alluring prospect of design technology co-optimization(DTCO)of CMT towards neuro-morphic computing.展开更多
Iron deficiency chlorosis of Lilium davidii var. unicolor is often the case in practice in alkaline soils of northwest region of China. It is difficult to control iron chlorosis because of high cost and short effectiv...Iron deficiency chlorosis of Lilium davidii var. unicolor is often the case in practice in alkaline soils of northwest region of China. It is difficult to control iron chlorosis because of high cost and short effective work time of conventional iron fertilizers. In this study, a 2-year field experiment was conducted to evaluate the effects of two slow-release fertilizers on the suppression of iron deficiency chlorosis, soil chemical properties, and the yield and quality of L. davidii var. unicolor. Results show that both coated slow-release iron fertilizers and embedded slow-release iron fertilizer effectively controlled iron-deficiency chlorosis. The application of slow-release iron fertilizers significantly increased plant height and chlorophyll content of L. davidii var. unicolor at different growth stages. Furthermore, coated iron fertilizer application significantly increased starch, protein, soluble sugar and vitamin C content of L. davidii var. unicolor, and it also significantly improved total amino acid content, with increases in essential amino acids(Trp, Leu, Lys, Phe, Val, and Thr contents) and in nonessential amino acids(Asp, Glu, Cit, Ihs, Acc, Ala, Pro, and Cys contents). It was concluded that application of coated slow-release iron fertilizer could be a promising option for suppression of iron deficiency chlorosis and deserves further study.展开更多
Phase-change material(PCM)is generating widespread interest as a new candidate for artificial synapses in bioinspired computer systems.However,the amorphization process of PCM devices tends to be abrupt,unlike continu...Phase-change material(PCM)is generating widespread interest as a new candidate for artificial synapses in bioinspired computer systems.However,the amorphization process of PCM devices tends to be abrupt,unlike continuous synaptic depression.The relatively large power consumption and poor analog behavior of PCM devices greatly limit their applications.Here,we fabricate a GeTe/Sb2Te3 superlattice-like PCM device which allows a progressive RESET process.Our devices feature low-power consumption operation and potential high-density integration,which can effectively simulate biological synaptic characteristics.The programming energy can be further reduced by properly selecting the resistance range and operating method.The fabricated devices are implemented in both artificial neural networks(ANN)and convolutional neural network(CNN)simulations,demonstrating high accuracy in brain-like pattern recognition.展开更多
Local phase transition in transition metal dichalcogenides (TMDCs) by lithiumintercalation enables the fabrication of high-quality contact interfaces in twodimensional(2D) electronic devices. However, controlling the ...Local phase transition in transition metal dichalcogenides (TMDCs) by lithiumintercalation enables the fabrication of high-quality contact interfaces in twodimensional(2D) electronic devices. However, controlling the intercalation oflithium is hitherto challenging in vertically stacked van der Waalsheterostructures (vdWHs) due to the random diffusion of lithium ions in thehetero-interface, which hinders their application for contact engineering of 2DvdWHs devices. Herein, a strategy to restrict the lithium intercalation pathwayin vdWHs is developed by using surface-permeation assisted intercalationwhile sealing all edges, based on which a high-performance edge-contact MoS_(2)vdWHs floating-gate transistor is demonstrated. Our method avoids intercalationfrom edges that are prone to be random but intentionally promotes lithiumintercalation from the top surface. The derived MoS_(2) floating-gatetransistor exhibits improved interface quality and significantly reduced subthresholdswing (SS) from >600 to 100 mV dec^(–1). In addition, ultrafast program/erase performance together with well-distinguished 32 memory statesare demonstrated, making it a promising candidate for low-power artificialsynapses. The study on controlling the lithium intercalation pathways in 2DvdWHs offers a viable route toward high-performance 2D electronics for memoryand neuromorphic computing purposes.展开更多
Lilium davidii var.unicolor(Lanzhou lily)is an important economic crop in the northwest cold and arid regions of China.Effective regulation of tiller-bulb development and plant growth is the key to improving yield and...Lilium davidii var.unicolor(Lanzhou lily)is an important economic crop in the northwest cold and arid regions of China.Effective regulation of tiller-bulb development and plant growth is the key to improving yield and quality of the lily.This study attempted to evaluate the effect of gibberellic acid(GA3)on tiller-bulb development and plant growth of Lanzhou lily by applying GA3 at various concentrations(0 mg/L,10 mg/L,30 mg/L,60 mg/L,and 100 mg/L)before planting and in the seedling period.Results showed that the 60-mg/L GA3 application had an inhibiting effect on tiller-bulb formation and increased the ratios of single and double bulbs but decreased the ratios of bulbs with three or more tiller bulbs,as com pared to the control(CK)and other GA3 treatments.The difference in flower number did not reach significant levels among the treatments.The tillering-related endogenous hormones IAA(indole-3-acetic acid)and Z(zeatin)content de creased,while IAA/Z increased with the 60-mg/L GA3 treatment during tiller initiation.And also,the shoot-bulb number and total daughter-bulb number decreased significantly with the 60-mg/L GA3 treatment.Furthermore,the 10-mg/L GA3 application promoted growth of Lanzhou lily significantly and resulted in an increase in plant height;bulb diameter;bulb circumference;and biomass of shoots,bulbs,fibrous roots,and the whole plant.Therefore,GA3 application is promising as a new regulation method for inhibiting tiller-bulb development and promoting bulb growth in Lanzhou lily production.展开更多
Solid-state lithium-metal batteries based on poly(vinylidene fluoride-co-hexafluoropropylene)(PVH)are frequently proposed to address the detrimental safety issue of conventional lithium-ion batteries by eliminating th...Solid-state lithium-metal batteries based on poly(vinylidene fluoride-co-hexafluoropropylene)(PVH)are frequently proposed to address the detrimental safety issue of conventional lithium-ion batteries by eliminating the use of flammable solvents,but still face a key challenge:low capacity and sluggish charge/discharge rate due to the intrinsic large-gradient Li^(+)distribution across the ionically-inert PVH matrix.Herein,Te vacancies in form of Bi_(2)Te_(3-x) are proposed to polarize the PVH unit to realize efficient decoupling of lithium salts at the atomic level in PVH-based solid polymeric electrolyte.Te vacancies in the PVH electrolyte doped with Bi_(2)Te_(3-x)(PVBT)induce a high-throughput and homogenous Li^(+)flow within the PVH matrices and near the Li metal.Theoretical calculations show that Te vacancies own high adsorption energy with bis(trifluoromethanesulfonyl)imide anions(TFSI^(-)),repulsive effect on Li^(+),and localized electron distribution,giving rise to a lithium-ion concentration gradient of 30 mol m^(-3),the smallest among the PVH-based inorganic/organic composite electrolytes.Consequently,the polarized electrolyte owns an unprecedented high-rate battery capacity of 114 mAh g^(-1)at~700 mA g^(-1)and also superior capacity performances with a cathode loading of 12 mg cm^(-2),outperforming the state-of-art PVH-based inorganic/organic composite electrolytes in Li||LiFePO_(4)battery.The work demonstrates an efficient strategy for achieving fast Liþdiffusion dynamics across polymeric matrices of classic solid-state electrolytes.展开更多
This paper studies the elastic deformation field in lattice-mismatched Ge-Si core-shell nanowires(NWs).Infinite wires with a cylindrical cross section under the assumption of translational symmetry are considered.The ...This paper studies the elastic deformation field in lattice-mismatched Ge-Si core-shell nanowires(NWs).Infinite wires with a cylindrical cross section under the assumption of translational symmetry are considered.The strain distributions are found by minimizing the elastic energy per unit cell using finite element method.This paper finds that the trace of the strain is discontinuous with a simple,almost piecewise variation between core and shell,whereas the individual components of the strain can exhibit complex variations.The simulation results are prerequisite of strained band structure calculation,and pave a way for further investigation of strain effect on the related transport property simulation.展开更多
With the rapid growth of computer science and big data,the traditional von Neumann architecture suffers the aggravating data communication costs due to the separated structure of the processing units and memories.Memr...With the rapid growth of computer science and big data,the traditional von Neumann architecture suffers the aggravating data communication costs due to the separated structure of the processing units and memories.Memristive in-memory computing paradigm is considered as a prominent candidate to address these issues,and plentiful applications have been demonstrated and verified.These applications can be broadly categorized into two major types:soft computing that can tolerant uncertain and imprecise results,and hard computing that emphasizes explicit and precise numerical results for each task,leading to different requirements on the computational accuracies and the corresponding hardware solutions.In this review,we conduct a thorough survey of the recent advances of memristive in-memory computing applications,both on the soft computing type that focuses on artificial neural networks and other machine learning algorithms,and the hard computing type that includes scientific computing and digital image processing.At the end of the review,we discuss the remaining challenges and future opportunities of memristive in-memory computing in the incoming Artificial Intelligence of Things era.展开更多
Similarity search,that is,finding similar items in massive data,is a fundamental computing problem in many fields such as data mining and information retrieval.However,for large-scale and high-dimension data,it suffer...Similarity search,that is,finding similar items in massive data,is a fundamental computing problem in many fields such as data mining and information retrieval.However,for large-scale and high-dimension data,it suffers from high computational complexity,requiring tremendous computation resources.Here,based on the low-power self-selective memristors,for the first time,we propose an in-memory search(IMS)system with two innovative designs.First,by exploiting the natural distribution law of the devices resistance,a hardware locality sensitive hashing encoder has been designed to transform the realvalued vectors into more efficient binary codes.Second,a compact memristive ternary content addressable memory is developed to calculate the Hamming distances between the binary codes in parallel.Our IMS system demonstrated a 168energy efficiency improvement over all-transistors counterparts in clustering and classification tasks,while achieving a software-comparable accuracy,thus providing a low-complexity and low-power solution for in-memory data mining applications.展开更多
With small thickness,commercial polyolefin separators own low porosity to ensure sufficient thermomechanical properties,resulting in tortuous and enlarged Li+diffusion pathways that induce large overpotentials and det...With small thickness,commercial polyolefin separators own low porosity to ensure sufficient thermomechanical properties,resulting in tortuous and enlarged Li+diffusion pathways that induce large overpotentials and detrimental dendrite growth.As a dilemma,the exploration of highly porous separators has been challenged by their large thickness,impairing the applicability of such pursuits.Herein,an ultraporous architecture is designed to shorten Li+transfer pathways by impregnating electrolyteaffinitive poly(vinylidene fluoride-co-hexafluoropropylene)into ultralight~3μm 3D-polytetrafluoroethylene scaffold(abbreviated as UP3D).The UP3D separator with a porosity of 74%gives rise to 70%enhancement in Li+transference and 77%reduction in Li+transfer resistance(2.67 mΩmm^(−1))and thus enables an ultrahigh Li+flux of 22.7 mA cm^(−2),effectively alleviating Li+concentration gradient across the separator.With the separator,the LiFePO4 half cell delivers a capacity of 118 mAh g^(−1) with an unparalleled capacity retention of 90%after 1000 cycles at 2 C,and a graphite||LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)pouch full cell delivers an areal energy density of 6.8 mWh cm^(−2)at 8.848 mA(1.4 mA cm^(−2))with a high cathode loading of 134.9 mg.Such results,together with the scalable production of the separator,reflect its promising potential in high-flux battery applications of separators that require both ultrahigh porosity and reliability.展开更多
基金funded by the National Key R&D Plan(2022YFC3501804)Fundamental Research Funds for the Central Public Welfare Research Institutes(No.ZZ13-YQ-049)National Natural Science Foundation of China(ZXKT22001).
文摘Codonopsis pilosula is a major Qi-tonifying medicinal herb,and its active composition is analyzed systematically.However,the relationship between its production origins and commodity specification grades with the active composition of C.pilosula lacks systematic research.This study integrates the HPLC and UV-Vis methodologies to evaluate the quality of C.pilosula from commodity specification grades and different origins,and it explores the correlation between ecological factors and production origins with active components.Here,network pharmacology is used to determine that lobetyolin,syringin,and tangshenoside I have potential efficacy in treating pulmonary fibrosis and oxidative stress.The HPLC and UV-Vis methods were employed to quantitatively analyse the levels of five active compounds from different origins and commodity specification grades.Ecological factors were collected from the different production origins with ArcGIS,and correlation analysis was conducted between these factors and the active components of C.pilosula to identify the key ecological influences that drive the accumulation of active compounds.Results showed that network pharmacology analyses indicated that the active components of C.pilosula,including lobetyolin,syringin,and tangshenoside I,bind to targets and exhibit antioxidant and antipulmonary fibrosis effects.Differences in the contents of active components across three commodity specification grades were not significant.The contents of active components in C.pilosula showed differences with varying origins,with the most variation observed in soluble sugar content,and notable variations are also observed in the levels of lobetyolin,syringin,and tangshenoside I,which could serve as potential biomarkers for different origins.Additionally,ecological factors influenced the accumulation of C.pilosula’s active components.The contents of soluble sugars and tangshenoside I were positively correlated with temperature and precipitation.Our study evaluated the active components of C.pilosula,and findings show that lobetyolin,syringin,and tangshenoside I have potential efficacy in treating pulmonary fibrosis and oxidative stress.The differences in the quality of C.pilosula across varying commodity specification grades are not significant.The different contents of C.pilosula across varying origins are significant,with soluble sugars and glycosides serving as potential markers for distinguishing C.pilosula from different origins.Moreover,ecological factors drove the accumulation of C.pilosula components.Soluble sugars and tangshenoside I content were particularly influenced by temperature and precipitation.Sand content and electrical conductivity significantly correlated with syringin,whereas organic carbon negatively influenced total flavonoids.This research provides a theoretical basis for the selection of the C.pilosula growing area and lays a foundation for the study of the C.pilosula quality standard.
基金supported by the Science Foundation of National Key Laboratory of Science and Technology on Advanced Composites in Special Environmentsthe National Natural Science Foundation of China (No.12002109)+1 种基金sponsored by Natural Science Foundation of Chongqing, China (Nos.CSTC2021jcyj-msxm X10305, CSTB2022NSCQMSX0246, CSTB2022NSCQ-MSX0242, CSTB2022NSCQMSX1244, CSTB2022NSCQ-MSX0441, CSTB2022NSCQMSX1356, CSTB2022NSCQ-MSX1572, CSTB2022NSCQ-MSX1583, CSTB2022NSCQ-MSX0487, CSTB2022TFII-OFX0034)Chongqing Technology Innovation and Application Development Special Key Project (No.CSTB2023TIAD-KPX0010)。
文摘High-temperature proton exchange membranes(HT-PEMs) possess excellent thermal and outstanding electrochemical stability, providing an avenue to realize high-temperature proton exchange membranes fuel cells(HT-PEMFCs) with both superior power density and long-term durability. Unfortunately, polybenzimidazole(PBI), a typical material for conventional HT-PEMs, fails to compromise the high nonaqueous proton conductivity and high mechanical properties, thus hindering their practical applications.Achieving efficient nonaqueous proton conduction is crucial for HT-PEMFC, and many insightful research works have been done in this area. However, there still lacks a report that integrates the host-vip interactions of phosphoric acid doping and the structural stability of polymers to systematically illustrate modification strategies. Here, we summarize recent advancements in enhancing the nonaqueous proton conduction of HT-PEMs. Various polymer structure modification strategies, including main chain and side group modification, cross-linking, blocking, and branching, are reviewed. Composite approaches of polymer, including compounding with organic porous polymers, filling the inorganic components and modifying with ionic liquids, etc., are also covered in this work. These strategies endow the HT-PEMs with more free volume, nanophase-separated structure, and multi-stage proton transfer channels, which can facilitate the proton transportation and improve their performance. Finally, current challenges and future directions for further enhancements are also outlined.
基金supported by the National Key Research and Development Program of China(No.2023YFB4502200)Natural Science Foundation of China(Nos.92164204 and 62374063)the Science and Technology Major Project of Hubei Province(No.2022AEA001).
文摘Memtransistors in which the source-drain channel conductance can be nonvolatilely manipulated through the gate signals have emerged as promising components for implementing neuromorphic computing.On the other side,it is known that the complementary metal-oxide-semiconductor(CMOS)field effect transistors have played the fundamental role in the modern integrated circuit technology.Therefore,will complementary memtransistors(CMT)also play such a role in the future neuromorphic circuits and chips?In this review,various types of materials and physical mechanisms for constructing CMT(how)are inspected with their merits and need-to-address challenges discussed.Then the unique properties(what)and poten-tial applications of CMT in different learning algorithms/scenarios of spiking neural networks(why)are reviewed,including super-vised rule,reinforcement one,dynamic vision with in-sensor computing,etc.Through exploiting the complementary structure-related novel functions,significant reduction of hardware consuming,enhancement of energy/efficiency ratio and other advan-tages have been gained,illustrating the alluring prospect of design technology co-optimization(DTCO)of CMT towards neuro-morphic computing.
基金supported by China's National Natural Science Foundation (No. 41501043)by the "West Light" project of the Chinese Academy of Sciencesby the project of 60th Chinese postdoctorate science fund (No. 2016M602904)
文摘Iron deficiency chlorosis of Lilium davidii var. unicolor is often the case in practice in alkaline soils of northwest region of China. It is difficult to control iron chlorosis because of high cost and short effective work time of conventional iron fertilizers. In this study, a 2-year field experiment was conducted to evaluate the effects of two slow-release fertilizers on the suppression of iron deficiency chlorosis, soil chemical properties, and the yield and quality of L. davidii var. unicolor. Results show that both coated slow-release iron fertilizers and embedded slow-release iron fertilizer effectively controlled iron-deficiency chlorosis. The application of slow-release iron fertilizers significantly increased plant height and chlorophyll content of L. davidii var. unicolor at different growth stages. Furthermore, coated iron fertilizer application significantly increased starch, protein, soluble sugar and vitamin C content of L. davidii var. unicolor, and it also significantly improved total amino acid content, with increases in essential amino acids(Trp, Leu, Lys, Phe, Val, and Thr contents) and in nonessential amino acids(Asp, Glu, Cit, Ihs, Acc, Ala, Pro, and Cys contents). It was concluded that application of coated slow-release iron fertilizer could be a promising option for suppression of iron deficiency chlorosis and deserves further study.
基金Project supported by the National Science and Technology Major Project of China(Grant No.2017ZX02301007-002)the National Key R&D Plan of China(Grant No.2017YFB0701701)the National Natural Science Foundation of China(Grant Nos.61774068 and 51772113).The authors acknowledge the support from Hubei Key Laboratory of Advanced Memories&Hubei Engineering Research Center on Microelectronics.
文摘Phase-change material(PCM)is generating widespread interest as a new candidate for artificial synapses in bioinspired computer systems.However,the amorphization process of PCM devices tends to be abrupt,unlike continuous synaptic depression.The relatively large power consumption and poor analog behavior of PCM devices greatly limit their applications.Here,we fabricate a GeTe/Sb2Te3 superlattice-like PCM device which allows a progressive RESET process.Our devices feature low-power consumption operation and potential high-density integration,which can effectively simulate biological synaptic characteristics.The programming energy can be further reduced by properly selecting the resistance range and operating method.The fabricated devices are implemented in both artificial neural networks(ANN)and convolutional neural network(CNN)simulations,demonstrating high accuracy in brain-like pattern recognition.
基金National Key Research and Development Program of China,Grant/Award Number:2023YFB4502200National Natural Science Foundation of China,Grant/Award Numbers:52372149,U21A2069+2 种基金Innovation Project of Optics Valley Laboratory,Grant/Award Number:OVL2023PY007Guangdong HUST Industrial Technology Research Institute,Guangdong Provincial Key Laboratory of Manufacturing Equipment Digitization,Grant/Award Number:2023B1212060012Interdiciplinary Research Program of HUST,Grant/Award Number:2024JCYJ008。
文摘Local phase transition in transition metal dichalcogenides (TMDCs) by lithiumintercalation enables the fabrication of high-quality contact interfaces in twodimensional(2D) electronic devices. However, controlling the intercalation oflithium is hitherto challenging in vertically stacked van der Waalsheterostructures (vdWHs) due to the random diffusion of lithium ions in thehetero-interface, which hinders their application for contact engineering of 2DvdWHs devices. Herein, a strategy to restrict the lithium intercalation pathwayin vdWHs is developed by using surface-permeation assisted intercalationwhile sealing all edges, based on which a high-performance edge-contact MoS_(2)vdWHs floating-gate transistor is demonstrated. Our method avoids intercalationfrom edges that are prone to be random but intentionally promotes lithiumintercalation from the top surface. The derived MoS_(2) floating-gatetransistor exhibits improved interface quality and significantly reduced subthresholdswing (SS) from >600 to 100 mV dec^(–1). In addition, ultrafast program/erase performance together with well-distinguished 32 memory statesare demonstrated, making it a promising candidate for low-power artificialsynapses. The study on controlling the lithium intercalation pathways in 2DvdWHs offers a viable route toward high-performance 2D electronics for memoryand neuromorphic computing purposes.
基金supported by the Science and Technology Service Network Initiative of the Chinese Academy of Sciences (Grant No. KFJ-STS-QYZD-120)the Gansu Province Major Project of Science and Technology (Grant No. 18ZD2NA010)the National Natural Science Foundation of China (Grant No. 41801076)
文摘Lilium davidii var.unicolor(Lanzhou lily)is an important economic crop in the northwest cold and arid regions of China.Effective regulation of tiller-bulb development and plant growth is the key to improving yield and quality of the lily.This study attempted to evaluate the effect of gibberellic acid(GA3)on tiller-bulb development and plant growth of Lanzhou lily by applying GA3 at various concentrations(0 mg/L,10 mg/L,30 mg/L,60 mg/L,and 100 mg/L)before planting and in the seedling period.Results showed that the 60-mg/L GA3 application had an inhibiting effect on tiller-bulb formation and increased the ratios of single and double bulbs but decreased the ratios of bulbs with three or more tiller bulbs,as com pared to the control(CK)and other GA3 treatments.The difference in flower number did not reach significant levels among the treatments.The tillering-related endogenous hormones IAA(indole-3-acetic acid)and Z(zeatin)content de creased,while IAA/Z increased with the 60-mg/L GA3 treatment during tiller initiation.And also,the shoot-bulb number and total daughter-bulb number decreased significantly with the 60-mg/L GA3 treatment.Furthermore,the 10-mg/L GA3 application promoted growth of Lanzhou lily significantly and resulted in an increase in plant height;bulb diameter;bulb circumference;and biomass of shoots,bulbs,fibrous roots,and the whole plant.Therefore,GA3 application is promising as a new regulation method for inhibiting tiller-bulb development and promoting bulb growth in Lanzhou lily production.
基金supported by Chongqing Technology Innovation and Application Development Special Key Project,CSTB2023TIAD-KPX0010Chongqing Technology Innovation and Application Development Special Major Project,CSTB2023TIAD-STX0033+1 种基金Natural Science Foundation of Chongqing,China(CSTB2022NSCQ-MSX0246,CSTB2022NSCQ-MSX1572,CSTB2022NSCQ-MSX0310)the Science Foundation of National Key Laboratory of Science and Technology on Advanced Composites in Special Environments.
文摘Solid-state lithium-metal batteries based on poly(vinylidene fluoride-co-hexafluoropropylene)(PVH)are frequently proposed to address the detrimental safety issue of conventional lithium-ion batteries by eliminating the use of flammable solvents,but still face a key challenge:low capacity and sluggish charge/discharge rate due to the intrinsic large-gradient Li^(+)distribution across the ionically-inert PVH matrix.Herein,Te vacancies in form of Bi_(2)Te_(3-x) are proposed to polarize the PVH unit to realize efficient decoupling of lithium salts at the atomic level in PVH-based solid polymeric electrolyte.Te vacancies in the PVH electrolyte doped with Bi_(2)Te_(3-x)(PVBT)induce a high-throughput and homogenous Li^(+)flow within the PVH matrices and near the Li metal.Theoretical calculations show that Te vacancies own high adsorption energy with bis(trifluoromethanesulfonyl)imide anions(TFSI^(-)),repulsive effect on Li^(+),and localized electron distribution,giving rise to a lithium-ion concentration gradient of 30 mol m^(-3),the smallest among the PVH-based inorganic/organic composite electrolytes.Consequently,the polarized electrolyte owns an unprecedented high-rate battery capacity of 114 mAh g^(-1)at~700 mA g^(-1)and also superior capacity performances with a cathode loading of 12 mg cm^(-2),outperforming the state-of-art PVH-based inorganic/organic composite electrolytes in Li||LiFePO_(4)battery.The work demonstrates an efficient strategy for achieving fast Liþdiffusion dynamics across polymeric matrices of classic solid-state electrolytes.
文摘This paper studies the elastic deformation field in lattice-mismatched Ge-Si core-shell nanowires(NWs).Infinite wires with a cylindrical cross section under the assumption of translational symmetry are considered.The strain distributions are found by minimizing the elastic energy per unit cell using finite element method.This paper finds that the trace of the strain is discontinuous with a simple,almost piecewise variation between core and shell,whereas the individual components of the strain can exhibit complex variations.The simulation results are prerequisite of strained band structure calculation,and pave a way for further investigation of strain effect on the related transport property simulation.
基金This work was financially supported by the National Key R&D Program of China(Nos.2019YFB2205100 and 2021ZD0201201)the National Natural Science Foundation of China(Grant Nos.92064012 and 61874164).
文摘With the rapid growth of computer science and big data,the traditional von Neumann architecture suffers the aggravating data communication costs due to the separated structure of the processing units and memories.Memristive in-memory computing paradigm is considered as a prominent candidate to address these issues,and plentiful applications have been demonstrated and verified.These applications can be broadly categorized into two major types:soft computing that can tolerant uncertain and imprecise results,and hard computing that emphasizes explicit and precise numerical results for each task,leading to different requirements on the computational accuracies and the corresponding hardware solutions.In this review,we conduct a thorough survey of the recent advances of memristive in-memory computing applications,both on the soft computing type that focuses on artificial neural networks and other machine learning algorithms,and the hard computing type that includes scientific computing and digital image processing.At the end of the review,we discuss the remaining challenges and future opportunities of memristive in-memory computing in the incoming Artificial Intelligence of Things era.
基金supported in part by the National Science and Technology Major Project of China(2017ZX02301007-002)Xu M acknowledges the National Natural Science Foundation of China(62174060)Miao X acknowledges the funding for Hubei Key Laboratory of Advanced Memories。
基金National Key Research and Development Plan of MOST of China,Grant/Award Numbers:2019YFB2205100,2021ZD0201201National Natural Science Foundation of China,Grant/Award Number:92064012+1 种基金Hubei Engineering Research Center on MicroelectronicsChua Memristor Institute。
文摘Similarity search,that is,finding similar items in massive data,is a fundamental computing problem in many fields such as data mining and information retrieval.However,for large-scale and high-dimension data,it suffers from high computational complexity,requiring tremendous computation resources.Here,based on the low-power self-selective memristors,for the first time,we propose an in-memory search(IMS)system with two innovative designs.First,by exploiting the natural distribution law of the devices resistance,a hardware locality sensitive hashing encoder has been designed to transform the realvalued vectors into more efficient binary codes.Second,a compact memristive ternary content addressable memory is developed to calculate the Hamming distances between the binary codes in parallel.Our IMS system demonstrated a 168energy efficiency improvement over all-transistors counterparts in clustering and classification tasks,while achieving a software-comparable accuracy,thus providing a low-complexity and low-power solution for in-memory data mining applications.
基金National Natural Science Foundation of China,Grant/Award Number:12002109Science Foundation of National Key Laboratory of Science and Technology on Advanced Composites in Special EnvironmentsNatural Science Foundation of Chongqing,China,Grant/Award Numbers:CSTB2022NSCQ-MSX1533,CSTC2021jcyj-msxmX10305,CSTB2022NSCQ-MSX1583,CSTB2022NSCQ-MSX1365,CSTB2022NSCQ-MSX1572,CSTB2022NSCQ-MSX0246,CSTB2022NSCQ-MSX0242,CSTB2022NSCQ-MSX0441,CSTB2022NSCQ-MSX0487,CSTB2022TFII-OFX0034。
文摘With small thickness,commercial polyolefin separators own low porosity to ensure sufficient thermomechanical properties,resulting in tortuous and enlarged Li+diffusion pathways that induce large overpotentials and detrimental dendrite growth.As a dilemma,the exploration of highly porous separators has been challenged by their large thickness,impairing the applicability of such pursuits.Herein,an ultraporous architecture is designed to shorten Li+transfer pathways by impregnating electrolyteaffinitive poly(vinylidene fluoride-co-hexafluoropropylene)into ultralight~3μm 3D-polytetrafluoroethylene scaffold(abbreviated as UP3D).The UP3D separator with a porosity of 74%gives rise to 70%enhancement in Li+transference and 77%reduction in Li+transfer resistance(2.67 mΩmm^(−1))and thus enables an ultrahigh Li+flux of 22.7 mA cm^(−2),effectively alleviating Li+concentration gradient across the separator.With the separator,the LiFePO4 half cell delivers a capacity of 118 mAh g^(−1) with an unparalleled capacity retention of 90%after 1000 cycles at 2 C,and a graphite||LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)pouch full cell delivers an areal energy density of 6.8 mWh cm^(−2)at 8.848 mA(1.4 mA cm^(−2))with a high cathode loading of 134.9 mg.Such results,together with the scalable production of the separator,reflect its promising potential in high-flux battery applications of separators that require both ultrahigh porosity and reliability.
