Objective The changes in serum adipokines and cytokines related to oxidative stress were examined during 3 months ‘Off to On’ and ‘On to Off’ periods using negatively charged particle-dominant indoor air condition...Objective The changes in serum adipokines and cytokines related to oxidative stress were examined during 3 months ‘Off to On’ and ‘On to Off’ periods using negatively charged particle-dominant indoor air conditions（NCPDIAC）.Methods Seven volunteers participated in the study,which included ‘OFF to 3 months ON’ periods（ON trials） for a total of 16 times,and ‘ON to 3 months OFF’（OFF trials） periods for a total of 13 times.Results With the exception of one case,serum amyloid A（SAA） levels decreased significantly during the ON trials.Conclusion Considering that SAA is an acute phase reactive protein such as C reactive protein（CRP）,this observed decrease might indicate the prevention of cardiovascular and atherosclerotic changes,since an increase in high-sensitive CRP is associated with the subsequent detection of these events.展开更多
The objective is to study whether the accumulation and utilization of plant N are controlled by Mo status in winter wheat cultivars. Mo-efficient cultivar 97003 （eft） and Mo-inefficient cultivar 97014 （ineff） were...The objective is to study whether the accumulation and utilization of plant N are controlled by Mo status in winter wheat cultivars. Mo-efficient cultivar 97003 （eft） and Mo-inefficient cultivar 97014 （ineff） were grown in severely Mo-deficient acidic soil （Tamm-reagent-extractable Mo 0.112 mg kg^-1） with （＋Mo） and without （-Mo） the application of 0.13 mg kg^-1 Mo. The accumulation and use efficiency of plant total N were significantly higher in ＋Mo than that in -Mo and in eft than that in ineff under Mo deficiency. N use efficiency was remarkably higher in maturity but it was forwarded to jointing stage after Mo supply, thus indicating that Mo supply promoted the N use efficiency besides N uptake and eff was efficient in N uptake and utilization. The overall activity of nitrate reductase （NR, EC 1.6.6.1） was significantly higher in ＋Mo than in -Mo and ratio of ＋Mo/-Mo was even to 14.8 at filleting stage for ineff. Activity of glutamine synthetase （GS, EC 6.3.1.2） was significantly lower in ＋Mo than in -Mo. Concentration of nitrate and glutamate were also significantly lower in ＋Mo than in -Mo, thus provided evidences for enhancing N use efficiency by Mo supply. Activities of NR and GS were significantly higher and concentrations of nitrate and glutamate were significantly lower in eff than ineff under Mo deficiency, thus indicated eff was more efficient in N reduction and utilization. It is therefore concluded that Mo could promote N accumulation and utilization in winter wheat which was directly related to NR and feedback regulated by GS. Higher Mo status also results in higher accumulation and utilization of plant N in eft.展开更多
The synthesis and luminescence properties of Zn2 SiO4: Mn phosphor layers on spherical silica spheres, i.e.,a kind of core-shell complex phosphor, Zn2SiO4: Mn@ SiO2 were described.Firstly, monodisperse silica spheres ...The synthesis and luminescence properties of Zn2 SiO4: Mn phosphor layers on spherical silica spheres, i.e.,a kind of core-shell complex phosphor, Zn2SiO4: Mn@ SiO2 were described.Firstly, monodisperse silica spheres were obtained via the Stober method by the hydrolysis of tetraethoxysilane(TEOS) Si ( OC2H5 ) 4 under base condition ( using NH4 OH as the catalyst).Secondly, the silica spheres were coated with a Zn2 SiO4: Mn phosphor layer by a Pechini solgel process.X-ray diffraction ( XRD), scanning electron microscope ( SEM), energy-dispersive X-ray spectrum ( EDS )and photoluminescence (PL) were employed to characterize the resulting complex phosphor.The results confirm that1000 ℃ annealed sample consists of crystalline Zn2SiO4: Mn shells and amorphous SiO2 cores.The phosphor show the green emission of Mn2+ at 521 nm corresponding 4T1 (4G) - 6 A1 (6S) transition, and the possible luminescence mechanism is proposed.展开更多
Flame heating combined with water cooling was used to straighten A6N01 aluminum alloy welded joint and effect of flame heating pass on its microstructure and mechanical properties was studied. Results showed that the ...Flame heating combined with water cooling was used to straighten A6N01 aluminum alloy welded joint and effect of flame heating pass on its microstructure and mechanical properties was studied. Results showed that the flame induced the precipitation and growth of the Mg_2Si phase on the Al substrate for the thermal aging A6N01 aluminum alloy welded joints,thus it led the decrease of micro-hardness and tensile strength of the A6N01 aluminum alloy welded joint with the increase of the heating pass. However,the fatigue property of the flame heated joint was improved because the Mg_2Si precipitation hindered the initiation and propagation of the fatigue crack.展开更多
Two cadmium(I)coordination polymers,[CdI(TIPA)(CDC)_(0.5)]_(n)(1)and{[Cd(TIPA)(MPDA)].H_(2)O}_(n)(2),(TIPA=tris(4-imidazolylphenyl)amine,H_(2)CDC=1,4-cyclohexanedicarboxylic acid,H_(2)MPDA=5-methylisophthalic acid),ha...Two cadmium(I)coordination polymers,[CdI(TIPA)(CDC)_(0.5)]_(n)(1)and{[Cd(TIPA)(MPDA)].H_(2)O}_(n)(2),(TIPA=tris(4-imidazolylphenyl)amine,H_(2)CDC=1,4-cyclohexanedicarboxylic acid,H_(2)MPDA=5-methylisophthalic acid),have been synthesized and characterized by IR spectroscopy,elemental analyses and single-crystal X-ray diffraction.Structural analyses reveal that complex 1 features a rare 2D→2D polyrotaxane network with(3,4)-connected(4.5^(2))(4.5^(3).7^(2))topology,which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions,whereas complex 2 has a two-dimensional(3,5)-connected novel network with(42.67.8)(42.6)topology and shows a 2D→3D parallel-parallel polycatenation framework.The results show that the carboxylates exert obvious influence on the resulting architectures.Meanwhile,the solid-state photoluminescence of two complexes at room temperature was also investigated.CCDC:1557335,1;1557336,2.展开更多
基金supported by a Kawasaki Medical School Research Grant(28B051)
文摘Objective The changes in serum adipokines and cytokines related to oxidative stress were examined during 3 months ‘Off to On’ and ‘On to Off’ periods using negatively charged particle-dominant indoor air conditions（NCPDIAC）.Methods Seven volunteers participated in the study,which included ‘OFF to 3 months ON’ periods（ON trials） for a total of 16 times,and ‘ON to 3 months OFF’（OFF trials） periods for a total of 13 times.Results With the exception of one case,serum amyloid A（SAA） levels decreased significantly during the ON trials.Conclusion Considering that SAA is an acute phase reactive protein such as C reactive protein（CRP）,this observed decrease might indicate the prevention of cardiovascular and atherosclerotic changes,since an increase in high-sensitive CRP is associated with the subsequent detection of these events.
基金Financial supports by the National Natural Science Foun-dation of China (30070431)the Key Technologies R&D Program of China during the 9th Five-Year Plan period(95-Agric-18-04)+1 种基金the Doctoral Fund of Ministry of Edu-cation of China (200805041061)the Earmarked Fund for Modern Agro-Industry Technology Research System, China
文摘The objective is to study whether the accumulation and utilization of plant N are controlled by Mo status in winter wheat cultivars. Mo-efficient cultivar 97003 （eft） and Mo-inefficient cultivar 97014 （ineff） were grown in severely Mo-deficient acidic soil （Tamm-reagent-extractable Mo 0.112 mg kg^-1） with （＋Mo） and without （-Mo） the application of 0.13 mg kg^-1 Mo. The accumulation and use efficiency of plant total N were significantly higher in ＋Mo than that in -Mo and in eft than that in ineff under Mo deficiency. N use efficiency was remarkably higher in maturity but it was forwarded to jointing stage after Mo supply, thus indicating that Mo supply promoted the N use efficiency besides N uptake and eff was efficient in N uptake and utilization. The overall activity of nitrate reductase （NR, EC 1.6.6.1） was significantly higher in ＋Mo than in -Mo and ratio of ＋Mo/-Mo was even to 14.8 at filleting stage for ineff. Activity of glutamine synthetase （GS, EC 6.3.1.2） was significantly lower in ＋Mo than in -Mo. Concentration of nitrate and glutamate were also significantly lower in ＋Mo than in -Mo, thus provided evidences for enhancing N use efficiency by Mo supply. Activities of NR and GS were significantly higher and concentrations of nitrate and glutamate were significantly lower in eff than ineff under Mo deficiency, thus indicated eff was more efficient in N reduction and utilization. It is therefore concluded that Mo could promote N accumulation and utilization in winter wheat which was directly related to NR and feedback regulated by GS. Higher Mo status also results in higher accumulation and utilization of plant N in eft.
文摘The synthesis and luminescence properties of Zn2 SiO4: Mn phosphor layers on spherical silica spheres, i.e.,a kind of core-shell complex phosphor, Zn2SiO4: Mn@ SiO2 were described.Firstly, monodisperse silica spheres were obtained via the Stober method by the hydrolysis of tetraethoxysilane(TEOS) Si ( OC2H5 ) 4 under base condition ( using NH4 OH as the catalyst).Secondly, the silica spheres were coated with a Zn2 SiO4: Mn phosphor layer by a Pechini solgel process.X-ray diffraction ( XRD), scanning electron microscope ( SEM), energy-dispersive X-ray spectrum ( EDS )and photoluminescence (PL) were employed to characterize the resulting complex phosphor.The results confirm that1000 ℃ annealed sample consists of crystalline Zn2SiO4: Mn shells and amorphous SiO2 cores.The phosphor show the green emission of Mn2+ at 521 nm corresponding 4T1 (4G) - 6 A1 (6S) transition, and the possible luminescence mechanism is proposed.
文摘Flame heating combined with water cooling was used to straighten A6N01 aluminum alloy welded joint and effect of flame heating pass on its microstructure and mechanical properties was studied. Results showed that the flame induced the precipitation and growth of the Mg_2Si phase on the Al substrate for the thermal aging A6N01 aluminum alloy welded joints,thus it led the decrease of micro-hardness and tensile strength of the A6N01 aluminum alloy welded joint with the increase of the heating pass. However,the fatigue property of the flame heated joint was improved because the Mg_2Si precipitation hindered the initiation and propagation of the fatigue crack.
文摘Two cadmium(I)coordination polymers,[CdI(TIPA)(CDC)_(0.5)]_(n)(1)and{[Cd(TIPA)(MPDA)].H_(2)O}_(n)(2),(TIPA=tris(4-imidazolylphenyl)amine,H_(2)CDC=1,4-cyclohexanedicarboxylic acid,H_(2)MPDA=5-methylisophthalic acid),have been synthesized and characterized by IR spectroscopy,elemental analyses and single-crystal X-ray diffraction.Structural analyses reveal that complex 1 features a rare 2D→2D polyrotaxane network with(3,4)-connected(4.5^(2))(4.5^(3).7^(2))topology,which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions,whereas complex 2 has a two-dimensional(3,5)-connected novel network with(42.67.8)(42.6)topology and shows a 2D→3D parallel-parallel polycatenation framework.The results show that the carboxylates exert obvious influence on the resulting architectures.Meanwhile,the solid-state photoluminescence of two complexes at room temperature was also investigated.CCDC:1557335,1;1557336,2.
