The salt effects on molecular orientation at air/liquid methanol interface were investigated by the polarization-dependent sum frequency generation vibrational spectroscopy（SFG-VS）. We clarified that the average til...The salt effects on molecular orientation at air/liquid methanol interface were investigated by the polarization-dependent sum frequency generation vibrational spectroscopy（SFG-VS）. We clarified that the average tilting angle of the methyl group to be u = 308 58 at the air/pure methanol surface assuming a d-function orientational distribution. Upon the addition of 3 mol/L Na I, the methyl group tilts further away from the surface normal with a new u = 418 38. This orientational change does not explain the enhancement of the SFG-VS intensities when adding Na I, implying the number density of the methanol molecules with a net polar ordering in the surface region also changed with the Na I concentrations. These spectroscopic findings shed new light on the salt effects on the surfaces structures of the polar organic solutions. It was also shown that the accurate determination of the bulk refractive indices and Raman depolarization ratios for different salt concentrations is crucial to quantitatively interpret the SFG-VS data.展开更多
Seamless switching is an important guarantee for the inverter to work continuously without stopping when gridconnected power generation system is the transient process from grid-connected to isolated island and from i...Seamless switching is an important guarantee for the inverter to work continuously without stopping when gridconnected power generation system is the transient process from grid-connected to isolated island and from isolated island reclosing. Based on the principle of pre-synchronous operation of traditional synchronous generators, this paper analyzes the principle of pre-synchronous process and its effect on the steady-state of micro grid with multiple virtual synchronous generators. At the same time, the paper analyzes the transient influence of the closed pre-synchronous switch on the power distribution of the micro grid under different phase modes. This paper proposes a pre-synchronous control strategy based on phase recognition. MATLAB/Simulink simulation software is used to verify the correctness and validity of the proposed method.展开更多
基金supported by the National Natural Science Foundation of China (Nos. 21227802, 21303216 and 21473217)
文摘The salt effects on molecular orientation at air/liquid methanol interface were investigated by the polarization-dependent sum frequency generation vibrational spectroscopy（SFG-VS）. We clarified that the average tilting angle of the methyl group to be u = 308 58 at the air/pure methanol surface assuming a d-function orientational distribution. Upon the addition of 3 mol/L Na I, the methyl group tilts further away from the surface normal with a new u = 418 38. This orientational change does not explain the enhancement of the SFG-VS intensities when adding Na I, implying the number density of the methanol molecules with a net polar ordering in the surface region also changed with the Na I concentrations. These spectroscopic findings shed new light on the salt effects on the surfaces structures of the polar organic solutions. It was also shown that the accurate determination of the bulk refractive indices and Raman depolarization ratios for different salt concentrations is crucial to quantitatively interpret the SFG-VS data.
文摘Seamless switching is an important guarantee for the inverter to work continuously without stopping when gridconnected power generation system is the transient process from grid-connected to isolated island and from isolated island reclosing. Based on the principle of pre-synchronous operation of traditional synchronous generators, this paper analyzes the principle of pre-synchronous process and its effect on the steady-state of micro grid with multiple virtual synchronous generators. At the same time, the paper analyzes the transient influence of the closed pre-synchronous switch on the power distribution of the micro grid under different phase modes. This paper proposes a pre-synchronous control strategy based on phase recognition. MATLAB/Simulink simulation software is used to verify the correctness and validity of the proposed method.
