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紫外光固化聚氨酯丙烯酸酯粘结剂的优化设计 被引量:8
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作者 马彦军 冶银平 +3 位作者 陈磊 万宏启 周惠娣 陈建敏 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2018年第5期111-115,共5页
采用红外光谱对聚氨酯丙烯酸酯(PUA)涂料的紫外固化过程进行定量分析;测试了不同配方和固化条件下涂膜的摆杆硬度、柔韧性和抗冲击性;考察了γ-甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)对粘结剂附着力的影响,并对其作用机制进行了分析。... 采用红外光谱对聚氨酯丙烯酸酯(PUA)涂料的紫外固化过程进行定量分析;测试了不同配方和固化条件下涂膜的摆杆硬度、柔韧性和抗冲击性;考察了γ-甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)对粘结剂附着力的影响,并对其作用机制进行了分析。结果表明,固化过程中C=C双键发生聚合,其转化率反映了涂膜的固化程度;增大光强、减少稀释剂用量和延长固化时间均有利于提高双键转化率和摆杆硬度;随着光引发剂浓度的增加,双键转化率先增后减;增大二官能PUA比例能够提高涂膜柔韧性和抗冲击性;KH570能够改善涂膜附着力,加入量越大改善效果越明显,且静置对附着力有很大影响;其作用机制是KH570分子中的双键与丙烯酸双键发生聚合,羟基与基底间形成氢键作用。 展开更多
关键词 聚氨酯丙烯酸酯 紫外光固化 Γ-甲基丙烯酰氧基丙基三甲氧基硅烷 附着力
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Corrosion and tribocorrosion resistance of MAO-based composite coating on AZ31 magnesium alloy 被引量:4
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作者 Siqin Liu Guihua Li +3 位作者 Yuming Qi Zhenjun Peng yinping ye Jun Liang 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2022年第12期3406-3417,共12页
In this paper, a multi-functional composite coating with low friction coefficient, high wear resistance and excellent tribocorrosion resistance is fabricated on AZ31 Mg alloys by micro-arc oxidation and spray-coating ... In this paper, a multi-functional composite coating with low friction coefficient, high wear resistance and excellent tribocorrosion resistance is fabricated on AZ31 Mg alloys by micro-arc oxidation and spray-coating methods. The microstructure, and composition of the coating are characterized by SEM, EDS, XRD, and FT-IR. Potentiodynamic polarization and EIS tests are conducted to evaluate the corrosion resistance of the composite coating. The tribocorrosion property is also studied using pin-on-disk tribometer in 3.5 wt.% Na Cl solution. It is found that the composite coating possesses better long-term corrosion resistance than the single MAO coating. The tribocorrosion tests prove that the composite coating exhibits much better wear and tribocorrosion resistance than the single MAO coating and can protect the substrate from corrosion under a sliding condition. 展开更多
关键词 Magnesium alloy Micro-arc oxidation Composite coating CORROSION TRIBOCORROSION
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