The rapid advancement of flexible electronics technology has placed higher demands on the structural design and performance regulation of elastic materials.Cellulosic elastomers,with their biodegradability,renewabilit...The rapid advancement of flexible electronics technology has placed higher demands on the structural design and performance regulation of elastic materials.Cellulosic elastomers,with their biodegradability,renewability,and tunability,emerge as ideal candidate materials.Entropy-driven self-as sembly promotes the spontaneous formation of ordered structures,serving as a crucial pathway for optimizing cellulose elastomer properties.However,the structure-property relationship between the self-assembled ordered structures of cellulose elastomers and their mechanical and electrical properties remains insufficiently explored.It hinders the expansion of their applications in electronic devices.This paper systematically reviews the structure-property regulation mechanisms of self-assembled cellulosic elastomers from an entropy-driven perspective.It elucidates the application principles and performance optimization strategies for mechanical energy harvesting and self-powered sensing,while also exploring the challenges and prospects for performance enhancement.This work provides a reference for the development of self-assembled cellulosic elastomers in the field of energy devices.展开更多
The metallic tip-induced superconductivity in normal Weyl semimetal offers a promising platform to study topological superconductivity,which is currently a research focus in condensed matter physics.Here we experiment...The metallic tip-induced superconductivity in normal Weyl semimetal offers a promising platform to study topological superconductivity,which is currently a research focus in condensed matter physics.Here we experimentally uncover that unconventional superconductivity can be induced by hard point contact(PC)method of ferromagnetic tips in Ta As single crystals.The magneto-transport measurements of the ferromagnetic tip-induced superconducting(FTISC)states exhibit the quantum oscillations,which reveal that the superconductivity is induced in the topologically nontrivial Fermi surface of the Weyl semimetal,and show compatibility of ferromagnetism and induced superconductivity.We further measure the point contact spectra(PCS)of tunneling transport for FTISC states which are potentially of nontrivial topology.Considering that the magnetic Weyl semimetal with novel superconductivity is hard to realize in experiment,our results show a new route to investigate the unconventional superconductivity by combining the topological semimetal with ferromagnetism through hard PC method.展开更多
基金supported by the National Natural Science Foundation of China(32571991)Guangxi Natural Science Foundation of China(2023GXNSFGA026001&2025GXNSFAA069870)the Foundation of State Key Laboratory of Biobased Material and Green Papermaking.(No.GZKF202323)。
文摘The rapid advancement of flexible electronics technology has placed higher demands on the structural design and performance regulation of elastic materials.Cellulosic elastomers,with their biodegradability,renewability,and tunability,emerge as ideal candidate materials.Entropy-driven self-as sembly promotes the spontaneous formation of ordered structures,serving as a crucial pathway for optimizing cellulose elastomer properties.However,the structure-property relationship between the self-assembled ordered structures of cellulose elastomers and their mechanical and electrical properties remains insufficiently explored.It hinders the expansion of their applications in electronic devices.This paper systematically reviews the structure-property regulation mechanisms of self-assembled cellulosic elastomers from an entropy-driven perspective.It elucidates the application principles and performance optimization strategies for mechanical energy harvesting and self-powered sensing,while also exploring the challenges and prospects for performance enhancement.This work provides a reference for the development of self-assembled cellulosic elastomers in the field of energy devices.
基金financially supported by the National Key R&D Program of China (2018YFA0305604, 2017YFA0303302, and 2016YFA0301604)the National Natural Science Foundation of China (11888101, 11774008, 0401210001, 11574008, 11761161003, 11825401, 11704279, 11774255, U1832214, and 11774007)+3 种基金the Strategic Priority Research Program of Chinese Academy of Sciences (XDB28000000)the Beijing Natural Science Foundation (Z180010)the Key Project of Natural Science Foundation of Tianjin City (17JCZDJC30100)China Postdoctoral Science Foundation (0401130005)
文摘The metallic tip-induced superconductivity in normal Weyl semimetal offers a promising platform to study topological superconductivity,which is currently a research focus in condensed matter physics.Here we experimentally uncover that unconventional superconductivity can be induced by hard point contact(PC)method of ferromagnetic tips in Ta As single crystals.The magneto-transport measurements of the ferromagnetic tip-induced superconducting(FTISC)states exhibit the quantum oscillations,which reveal that the superconductivity is induced in the topologically nontrivial Fermi surface of the Weyl semimetal,and show compatibility of ferromagnetism and induced superconductivity.We further measure the point contact spectra(PCS)of tunneling transport for FTISC states which are potentially of nontrivial topology.Considering that the magnetic Weyl semimetal with novel superconductivity is hard to realize in experiment,our results show a new route to investigate the unconventional superconductivity by combining the topological semimetal with ferromagnetism through hard PC method.
