Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system perfor- mance. In this study we used polyvinyl alcohol (PVA) poly...Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system perfor- mance. In this study we used polyvinyl alcohol (PVA) polymer membrane crosslinked with sulfosuccinic acid (SSA) as a new separator for the MFC. The highest power density of 7594-4 mW-m-2 was obtained when MFC using the PVA membrane crosslinked with 15% of SSA due to its desirable proton conductivity (5.16 x 10-2 S.cml). The power density significantly increased to 11064- 30 mW.m-2 with a separator-electrode-assembly config- uration, which was comparable with glass fiber (11704- 46 mW.m-2). The coulombic efficiencies of the MFCs with crosslinked PVA membranes ranged from 36.3% to 45.7% at a fix external resistance of lO00f2. The crosslinked PVA membrane could be a promising alter- native to separator materials for constructing practical MFC system.展开更多
文摘Separator between anode and cathode is an essential part of the microbial fuel cell (MFC) and its property could significantly influence the system perfor- mance. In this study we used polyvinyl alcohol (PVA) polymer membrane crosslinked with sulfosuccinic acid (SSA) as a new separator for the MFC. The highest power density of 7594-4 mW-m-2 was obtained when MFC using the PVA membrane crosslinked with 15% of SSA due to its desirable proton conductivity (5.16 x 10-2 S.cml). The power density significantly increased to 11064- 30 mW.m-2 with a separator-electrode-assembly config- uration, which was comparable with glass fiber (11704- 46 mW.m-2). The coulombic efficiencies of the MFCs with crosslinked PVA membranes ranged from 36.3% to 45.7% at a fix external resistance of lO00f2. The crosslinked PVA membrane could be a promising alter- native to separator materials for constructing practical MFC system.