Gas-insulated equipment(GIE)that utilizes the most potent greenhouse gas sulfur hexafluoride(SF_(6))as insulation and arc-quenching medium has been widely used in the power industry.Seeking eco-friendly insulating gas...Gas-insulated equipment(GIE)that utilizes the most potent greenhouse gas sulfur hexafluoride(SF_(6))as insulation and arc-quenching medium has been widely used in the power industry.Seeking eco-friendly insulating gas with advanced performance for next-generation SF_(6)-free GIE is significant for the“net-zero”goal and sustainable development.In this paper,the utilization,emission,and reduction policies of SF_(6)around the world were summarized first.Then,we systematically reviewed the latest progress in comprehensive performance evaluation of eco-friendly insulating gas in terms of molecular design,dielectric insulation,arc-quenching,stability and decomposition,materials compatibility,biosafety,etc.Further,the representative applications of eco-friendly insulating gas in medium-voltage,high-voltage GIE as well as relevant maintenance-related technologies were highlighted.Accordingly,the existing challenges and future perspectives were proposed,presenting a roadmap to hopefully steer the development of eco-friendly insulating gas and GIE.展开更多
A method based upon the weighted total cross section （WTCS） theory is proposed to calculate the photo-ionisation cross sections and the radiative recombination rate coefficients between the fundamental level of CO a...A method based upon the weighted total cross section （WTCS） theory is proposed to calculate the photo-ionisation cross sections and the radiative recombination rate coefficients between the fundamental level of CO and the main electronic states of its corresponding ion. Total photo-ionisation cross sections and radiative recombination rate coefficients are determined from the calculation of elementary vibrational photo-ionisation cross sections. Transitions be- tween CO＋（X, A and B） and CO（X） are considered. Total photo-ionisation cross sections and recombination coefficients are computed in the temperature interval 500-15000 K.展开更多
Internal arcs cause a rapid increase in pressure in electrical installations. The type of insulation gas has influence on pressure development. Typically SF6 is used incompact metal-clad switchgear, however, it has a ...Internal arcs cause a rapid increase in pressure in electrical installations. The type of insulation gas has influence on pressure development. Typically SF6 is used incompact metal-clad switchgear, however, it has a high global warming potential. Because of this, the replacement of SF6 by alternative gases such as CO2 is under discussion. The pressure developments in a closed vessel filled with air, SF6 and CO2 are measured and compared. During internal arcing in gas-insulated switchgear, overpressure causes a rupture of a burst plate and hot gas escapes into the surrounding room mixing with air. In order to predict the pressure development in electrical installations reliably, the portion of energy causing pressure rise, arc voltage as well as reliable gas data i.e., thermodynamic and transport properties, must be known in a wide range of pressure and temperature. These data are up to now not available for CO2/air mixtures. The thermodynamic properties are directly calculated from the number densities, internal partition functions and enthalpies of formation. The transport coefficients are deduced using the Chapman-Enskog method. Comparing measured and calculated pressure developments in a test arrangement demonstrates the quality of the calculation approach.展开更多
基金supported in part by the National Natural Science Foundation of China(Nos.52277144,52107145,and 51907023)the fellowship of China Postdoctoral Science Foundation(No.2022M712446).
文摘Gas-insulated equipment(GIE)that utilizes the most potent greenhouse gas sulfur hexafluoride(SF_(6))as insulation and arc-quenching medium has been widely used in the power industry.Seeking eco-friendly insulating gas with advanced performance for next-generation SF_(6)-free GIE is significant for the“net-zero”goal and sustainable development.In this paper,the utilization,emission,and reduction policies of SF_(6)around the world were summarized first.Then,we systematically reviewed the latest progress in comprehensive performance evaluation of eco-friendly insulating gas in terms of molecular design,dielectric insulation,arc-quenching,stability and decomposition,materials compatibility,biosafety,etc.Further,the representative applications of eco-friendly insulating gas in medium-voltage,high-voltage GIE as well as relevant maintenance-related technologies were highlighted.Accordingly,the existing challenges and future perspectives were proposed,presenting a roadmap to hopefully steer the development of eco-friendly insulating gas and GIE.
基金the "Comite Mixté Franco-Tunisien pour la Coopération Universitaire(Partenariat Hubert Curien,Utique,Tunisie)"for its financial support in the achievement of this work
文摘A method based upon the weighted total cross section （WTCS） theory is proposed to calculate the photo-ionisation cross sections and the radiative recombination rate coefficients between the fundamental level of CO and the main electronic states of its corresponding ion. Total photo-ionisation cross sections and radiative recombination rate coefficients are determined from the calculation of elementary vibrational photo-ionisation cross sections. Transitions be- tween CO＋（X, A and B） and CO（X） are considered. Total photo-ionisation cross sections and recombination coefficients are computed in the temperature interval 500-15000 K.
文摘Internal arcs cause a rapid increase in pressure in electrical installations. The type of insulation gas has influence on pressure development. Typically SF6 is used incompact metal-clad switchgear, however, it has a high global warming potential. Because of this, the replacement of SF6 by alternative gases such as CO2 is under discussion. The pressure developments in a closed vessel filled with air, SF6 and CO2 are measured and compared. During internal arcing in gas-insulated switchgear, overpressure causes a rupture of a burst plate and hot gas escapes into the surrounding room mixing with air. In order to predict the pressure development in electrical installations reliably, the portion of energy causing pressure rise, arc voltage as well as reliable gas data i.e., thermodynamic and transport properties, must be known in a wide range of pressure and temperature. These data are up to now not available for CO2/air mixtures. The thermodynamic properties are directly calculated from the number densities, internal partition functions and enthalpies of formation. The transport coefficients are deduced using the Chapman-Enskog method. Comparing measured and calculated pressure developments in a test arrangement demonstrates the quality of the calculation approach.
