Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sust...Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sustainable development.Despite significant progress in various electrochemical systems,the regulatory mechanisms of PDE in energy and mass transfer and the lifespan extension of electrolysis systems,particularly in water electrolysis(WE)for hydrogen production,remain insufficiently explored.Therefore,there is an urgent need for a deeper understanding of the unique contributions of PDE in mass transfer enhancement,microenvironment regulation,and hydrogen production optimization,aiming to achieve low-energy consumption,high catalytic activity,and long-term stability in the generation of target products.Here,this review critically examines the microenvironmental effects of PDE on energy and mass transfer,the electrode degradation mechanisms in the lifespan extension of electrolysis systems,and the key factors in enhancing WE for hydrogen production,providing a comprehensive summary of current research progress.The review focuses on the complex regulatory mechanisms of frequency,duty cycle,amplitude,and other factors in hydrogen evolution reaction(HER)performance within PDE strategies,revealing the interrelationships among them.Finally,the potential future directions and challenges for transitioning from laboratory studies to industrial applications are proposed.展开更多
Based on outcrop, drilling, logging and seismic data, the reservoir forming conditions, reservoir forming model and exploration potential of the ultra-deep Sinian Dengying Formation at the northwest margin of Yangtze ...Based on outcrop, drilling, logging and seismic data, the reservoir forming conditions, reservoir forming model and exploration potential of the ultra-deep Sinian Dengying Formation at the northwest margin of Yangtze craton region were examined.(1) This area is in craton rifting stage from Sinian to Early Cambrian, characterized by syn-sedimentary faults and rapid subsidence, significant sedimentary differences, and development of Dengying Formation platform margins on both sides of the rift.(2) The Sinian–Cambrian in this area has two sets of high-quality source rocks, Doushantuo Formation and Maidiping-Qiongzhusi Formation;of which, the latter has a thickness of 150–600 m and hydrocarbon generation intensity of(100-200)×10;m;/km;.(3) The mounds and shoals in the platform margin of Sinian Dengying Formation controlled by faults are thick and distributed in rows and zones;they are reformed by contemporaneous–quasi-contemporaneous and supergene karstification jointly, forming pore-type reservoirs with a thickness of 200-400 m.(4) The two sets of source rocks enter oil generation windows from Permian to Early Triassic, and the oil migrates a short distance to the lithologic traps of mounds and shoals to form a huge scale paleo-oil reservoir group;from Late Triassic to Jurassic, the oil in the paleo-oil reservoirs is cracked into gas, laying the foundation of present natural gas reservoirs.(5) The mound-shoal body at the platform margin of Dengying Formation and the two sets of high-quality source rocks combine into several types of favorable source-reservoir combinations, which, with the advantage of near-source and high-efficiency reservoir formation, and can form large lithologic gas reservoirs. The Mianyang-Jiange area is a potential large gas field with trillion cubic meters of reserves. According to seismic prediction, the Laoguanmiao structure in this area has the Deng-2 Member mound-shoal reservoir of about 1300 km^(2), making it a ultra-deep target worthy of exploration in the near future.展开更多
基金financially supported by the Key Research and Development Program of Heilongjiang Province(No.2024ZXJ03C06)National Natural Science Foundation of China(No.52476192,No.52106237)+1 种基金Natural Science Foundation of Heilongjiang Province(No.YQ2022E027)Technology Project of China Datang Technology Innovation Co.,Ltd(No.DTKC-2024-20610).
文摘Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sustainable development.Despite significant progress in various electrochemical systems,the regulatory mechanisms of PDE in energy and mass transfer and the lifespan extension of electrolysis systems,particularly in water electrolysis(WE)for hydrogen production,remain insufficiently explored.Therefore,there is an urgent need for a deeper understanding of the unique contributions of PDE in mass transfer enhancement,microenvironment regulation,and hydrogen production optimization,aiming to achieve low-energy consumption,high catalytic activity,and long-term stability in the generation of target products.Here,this review critically examines the microenvironmental effects of PDE on energy and mass transfer,the electrode degradation mechanisms in the lifespan extension of electrolysis systems,and the key factors in enhancing WE for hydrogen production,providing a comprehensive summary of current research progress.The review focuses on the complex regulatory mechanisms of frequency,duty cycle,amplitude,and other factors in hydrogen evolution reaction(HER)performance within PDE strategies,revealing the interrelationships among them.Finally,the potential future directions and challenges for transitioning from laboratory studies to industrial applications are proposed.
基金Supported by the PetroChina Forward-looking and Fundamental Major Scientific and Technological Project (2021DJ0605)。
文摘Based on outcrop, drilling, logging and seismic data, the reservoir forming conditions, reservoir forming model and exploration potential of the ultra-deep Sinian Dengying Formation at the northwest margin of Yangtze craton region were examined.(1) This area is in craton rifting stage from Sinian to Early Cambrian, characterized by syn-sedimentary faults and rapid subsidence, significant sedimentary differences, and development of Dengying Formation platform margins on both sides of the rift.(2) The Sinian–Cambrian in this area has two sets of high-quality source rocks, Doushantuo Formation and Maidiping-Qiongzhusi Formation;of which, the latter has a thickness of 150–600 m and hydrocarbon generation intensity of(100-200)×10;m;/km;.(3) The mounds and shoals in the platform margin of Sinian Dengying Formation controlled by faults are thick and distributed in rows and zones;they are reformed by contemporaneous–quasi-contemporaneous and supergene karstification jointly, forming pore-type reservoirs with a thickness of 200-400 m.(4) The two sets of source rocks enter oil generation windows from Permian to Early Triassic, and the oil migrates a short distance to the lithologic traps of mounds and shoals to form a huge scale paleo-oil reservoir group;from Late Triassic to Jurassic, the oil in the paleo-oil reservoirs is cracked into gas, laying the foundation of present natural gas reservoirs.(5) The mound-shoal body at the platform margin of Dengying Formation and the two sets of high-quality source rocks combine into several types of favorable source-reservoir combinations, which, with the advantage of near-source and high-efficiency reservoir formation, and can form large lithologic gas reservoirs. The Mianyang-Jiange area is a potential large gas field with trillion cubic meters of reserves. According to seismic prediction, the Laoguanmiao structure in this area has the Deng-2 Member mound-shoal reservoir of about 1300 km^(2), making it a ultra-deep target worthy of exploration in the near future.
