Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulv...Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulvic acid could promote leachability and vertical transference of all the mineral-bound Hg. Brown humic acid could retard the leaching and transferring processes of CaCO3-Hg, Fe2O3-Hg, MnO2-Hg and kaolinite Hg but not bentonite-Hg. Grey humic acid could greatly enhance residing ability of the mineral-bound Hg in the soil column and restrain them from vertical transferring. The effect of humus on leachability and transferring activity on the mineral-bound Hg was closely related to its ability to convert the mineral-bound Hg into organic-bound form and the transferability of the latter in the soil column. The characteristics of the mineral-bound Hg in speciation were the internal factors that determined the extent and rate of the influence of the humus.展开更多
基金Project (No. 970601) supported by the State Education Commission, China.
文摘Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulvic acid could promote leachability and vertical transference of all the mineral-bound Hg. Brown humic acid could retard the leaching and transferring processes of CaCO3-Hg, Fe2O3-Hg, MnO2-Hg and kaolinite Hg but not bentonite-Hg. Grey humic acid could greatly enhance residing ability of the mineral-bound Hg in the soil column and restrain them from vertical transferring. The effect of humus on leachability and transferring activity on the mineral-bound Hg was closely related to its ability to convert the mineral-bound Hg into organic-bound form and the transferability of the latter in the soil column. The characteristics of the mineral-bound Hg in speciation were the internal factors that determined the extent and rate of the influence of the humus.