The research on low-dimensional organic-inorganic hybrid metal halide materials is attractive due to their flexible structures and outstanding optoelectronic properties.This paper reports on a series of novel(PIP)CdX_...The research on low-dimensional organic-inorganic hybrid metal halide materials is attractive due to their flexible structures and outstanding optoelectronic properties.This paper reports on a series of novel(PIP)CdX_(4) compounds(PIP=protonated piperazine),including(PIP)CdI_(4)(Cd-I),(PIP)CdI_(2)Cl_(2)(Cd-ICl)and(PIP)CdI_(2.4)Br_(1.6)(Cd-IBr).It is notable that PIP·2Cl can diffuse into their structures resulting in a luminescent phase.展开更多
基金supported by the National Natural Science Foundation of China(22373014)the Natural Science Foundation of Fujian Province(2022J06019).
文摘The research on low-dimensional organic-inorganic hybrid metal halide materials is attractive due to their flexible structures and outstanding optoelectronic properties.This paper reports on a series of novel(PIP)CdX_(4) compounds(PIP=protonated piperazine),including(PIP)CdI_(4)(Cd-I),(PIP)CdI_(2)Cl_(2)(Cd-ICl)and(PIP)CdI_(2.4)Br_(1.6)(Cd-IBr).It is notable that PIP·2Cl can diffuse into their structures resulting in a luminescent phase.
