FeNi-based MGs exhibit the most excellent room-temperature mechanical properties among different Fe-based metallic glasses(MGs)systems.However,the glass-forming ability(GFA)of FeNi-based MGs is much lower than that of...FeNi-based MGs exhibit the most excellent room-temperature mechanical properties among different Fe-based metallic glasses(MGs)systems.However,the glass-forming ability(GFA)of FeNi-based MGs is much lower than that of their counterparts.Thus,uncovering the solidification and anomalous nano-crystallization behavior of FeNi-based MGs is crucial to the development of FeNibased bulk metallic glasses with larger plasticity and critical size concurrently.Regarding this,a combination of complementary in situ synchrotron radiation high-energy X-ray diffraction,small-angle neutron scattering(SANS),and 3-dimentional atom probe tomography(3-D APT)is used to study solidification and nano-crystallization behavior of Fe_(48)Ni_(30)Mo_(3)B_(19)liquid and MG.The time–temperature–transformation diagram was successfully depicted via melting spun,in situ solidification,and isothermal annealing methods.We found that the Fe_(48)Ni_(30)Mo_(3)B_(19)MG can only be prepared via the meltspinning method to obtain amorphous ribbons,which could contribute to the low activation energy for the nano-crystallization growth E_(p).Moreover,during isothermal annealing,the anomalous slow growth behavior in kinetic of theγ-FeNi phase embedded in the amorphous matrix is caused by the Fe and Ni partitioning,and the Mo-enriched region around the nanosizedγ-FeNi phase,which is revealed by 3-D APT.These results exhibit a new perspective for understanding the relationship between GFA and nano-crystallization behavior and provide feasible guidance for the development of newγ-FeNi-containing Fe-based BMG composites with desired mechanical properties and GFA.展开更多
基金financially supported by the National Key R&D Program of China(No.2022YFA1603801)the Open Fund of the Science and Technology on Metrology and Calibration Laboratory(No.JLKG2023001C004)+6 种基金the National Natural Science Foundation of China(Nos.52130108,52301213,52071024,52271003,and 52101188)Guangdong Basic and Applied Basic Research Foundation(Nos.2022A1515110805,2021B1515140028,and 2021CX02C087)the Open Fund of the China Spallation Neutron Source Songshan Lake Science City(No.KFKT2023B11)Construction of a Coordination Network for Science and Technology Assistance to Latin American Countries(Science and Technology Partnership Program,Ministry of Science and Technology of China,No.KY202401006)the Youth Innovation Promotion Association,CAS(No.2020010)the State Key Lab of Advanced Metals and Materials(No.2022-ZD01)the SSRF proposal(No.2024-SSRF-PT-506766)
文摘FeNi-based MGs exhibit the most excellent room-temperature mechanical properties among different Fe-based metallic glasses(MGs)systems.However,the glass-forming ability(GFA)of FeNi-based MGs is much lower than that of their counterparts.Thus,uncovering the solidification and anomalous nano-crystallization behavior of FeNi-based MGs is crucial to the development of FeNibased bulk metallic glasses with larger plasticity and critical size concurrently.Regarding this,a combination of complementary in situ synchrotron radiation high-energy X-ray diffraction,small-angle neutron scattering(SANS),and 3-dimentional atom probe tomography(3-D APT)is used to study solidification and nano-crystallization behavior of Fe_(48)Ni_(30)Mo_(3)B_(19)liquid and MG.The time–temperature–transformation diagram was successfully depicted via melting spun,in situ solidification,and isothermal annealing methods.We found that the Fe_(48)Ni_(30)Mo_(3)B_(19)MG can only be prepared via the meltspinning method to obtain amorphous ribbons,which could contribute to the low activation energy for the nano-crystallization growth E_(p).Moreover,during isothermal annealing,the anomalous slow growth behavior in kinetic of theγ-FeNi phase embedded in the amorphous matrix is caused by the Fe and Ni partitioning,and the Mo-enriched region around the nanosizedγ-FeNi phase,which is revealed by 3-D APT.These results exhibit a new perspective for understanding the relationship between GFA and nano-crystallization behavior and provide feasible guidance for the development of newγ-FeNi-containing Fe-based BMG composites with desired mechanical properties and GFA.
