The pursuit of alternative fuel generation technologies has gained momentum due to the diminishing reserves of fossil fuels and global warming from increased CO_(2)emission.Among the proposed methods,the hydrogenation...The pursuit of alternative fuel generation technologies has gained momentum due to the diminishing reserves of fossil fuels and global warming from increased CO_(2)emission.Among the proposed methods,the hydrogenation of CO_(2)to produce marketable carbon-based products like methanol and ethanol is a practical approach that offers great potential to reduce CO_(2)emissions.Although significant volumes of methanol are currently produced from CO_(2),developing highly efficient and stable catalysts is crucial for further enhancing conversion and selectivity,thereby reducing process costs.An in-depth examination of the differences and similarities in the reaction pathways for methanol and ethanol production highlights the key factors that drive C-C coupling.Identifying these factors guides us toward developing more effective catalysts for ethanol synthesis.In this paper,we explore how different catalysts,through the production of various intermediates,can initiate the synthesis of methanol or ethanol.The catalytic mechanisms proposed by spectroscopic techniques and theoretical calculations,including operando X-ray methods,FTIR analysis,and DFT calculations,are summarized and presented.The following discussion explores the structural properties and composition of catalysts that influence C-C coupling and optimize the conversion rate of CO_(2)into ethanol.Lastly,the review examines recent catalysts employed for selective methanol and ethanol production,focusing on single-atom catalysts.展开更多
We used the ocean reanalysis dataset SODA 2.2.4 to investigate the relationship between the interior branch of subtropical-tropical cells(STCs)in the Pacific Ocean and El Nino-Southern Oscillation(ENSO)over interdecad...We used the ocean reanalysis dataset SODA 2.2.4 to investigate the relationship between the interior branch of subtropical-tropical cells(STCs)in the Pacific Ocean and El Nino-Southern Oscillation(ENSO)over interdecadal timescales between 1930 and 2010,as well as the possible mechanisms involved.Interior transport within the upper pycnocline layers of STCs(InSTC)along 9°S(InSTC9s)shows a significant correlation of 0.54 with ENSO over the study period.However,there is an interdecadal shift in the relationship between InSTC along 9°N(InSTC9n)and ENSO.The correlation coefficient between InSTC9n and ENSO is not statistically significant between 1930 and 1965(PD1),but is as high as 0.68(significant at the 95% confidence level)between 1965 and 2010(PD2).Composite and regression analysis suggests that this shift may be caused by the relationship between InSTC 9 n and the tropical wind field.During PD1,InSTC9n was driven primarily by the local wind field outside equatorial region,with a relatively weak response to the equatorial wind related to ENSO.In contrast,during PD2,the wind field associated with InSTC 9 n showed a similar spatial distribution to that of ENSO within the equatorial region,indicating a close relationship between InSTC9n and ENSO.The wind stress curl associated with ENSO drives the anomalous InSTC9n in off-equatorial regions,whose signal can propagate westward in the form of Rossby wave and modulate the thermal structure of the tropical Pacific,favoring the development of ENSO.The possible connection between the Atlantic Multidecadal Oscillation(AMO)and interdecadal changes in the ENSO-InSTC9n relationship was also examined.There is a significant connection between the AMO and the interdecadal change in the relationship between ENSO and InSTC9n;however,the associated mechanism remains to be explored in future studies.展开更多
CuO-CeO2 catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature.The catalytic performance was evaluated and the catalysts were characterized by inductive...CuO-CeO2 catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature.The catalytic performance was evaluated and the catalysts were characterized by inductively coupled plasma atomic emission spectroscopy,X-ray diffraction,temperature-programmed reduction,field emission scanning electron microscopy and thermo-gravimetric analysis.Over CuOCeO2 catalysts,H2 with low CO content was produced in the whole tested temperature range of 250–450 C.The non-noble metal catalyst 20CuCe showed higher H2production rate than 1%Rh/CeO2 catalyst at 300–400 C and the advantage was more obvious after 20 h testing at400 C.These results further confirmed that CuO-CeO2 catalysts may be suitable candidates for low temperature hydrogen production from ethanol.展开更多
Changes in water quality from source water to finished water and tap water at two conventional drinking water treatment plants(DWTPs)were monitored.Beside the routine water quality testing,Caenorhabditis elegans-based...Changes in water quality from source water to finished water and tap water at two conventional drinking water treatment plants(DWTPs)were monitored.Beside the routine water quality testing,Caenorhabditis elegans-based toxicity assays and the fluorescence excitation–emission matrices technique were also applied.Both DWTPs supplied drinking water that met government standards.Under current test conditions,both the investigated finished water and tap water samples exhibited stronger lethal,genotoxic and reprotoxic potential than the relative source water sample,and the tap water sample was more lethal but tended to be less genotoxic than the corresponding finished water sample.Meanwhile,the nearly complete removal of tryptophan-like substances and newly generated tyrosine-like substances were observed after the treatment of drinking water,and humic-like substances were identified in the tap water.Based on these findings,toxic pollutants,including genotoxic/reproductive toxicants,are produced in the drinking water treatment and/or distribution processes.Moreover,further studies are needed to clarify the potentially important roles of tyrosine-like and humic-like substances in mediating drinking water toxicity and to identify the potential sources of these contaminants.Additionally,tryptophan-like fluorescence may be adopted as a useful parameter to monitor the treatment performance of DWTPs.Our observations provided insights into the importance of utilizing biotoxicity assays and fluorescence spectroscopy as tools to complement the routine evaluation of drinking water.展开更多
Climate warming has prolonged the optimization of crop-growing seasons,shortened actual growth periods,and changed crop-planting boundaries.It also has boosted crop yields in certain regions while compromising crop qu...Climate warming has prolonged the optimization of crop-growing seasons,shortened actual growth periods,and changed crop-planting boundaries.It also has boosted crop yields in certain regions while compromising crop quality and affected the occurrence of meteorological disasters and pest diseases damage,which has resulted in reduction in grain yield.Crop production systems will evidence more sensitivity to climate change in future;for example,with an increase of 1°C in temperature,the average growth period will be shortened by 17 days for winter wheat and 7-8 days for maize and rice.Of course regional differences will exist.Climate change will threaten crop yield stability and affect crop quality.Vulnerability will be addressed in regard to extreme climatic events,which include reducing exposure and improving adaptive capacity,because the exposure of rain-fed agriculture is greater than that of irrigated agriculture.Therefore,we propose three suggestions to reduce the vulnerability of crop production systems to climate change.First,strengthen the evaluation capacity construction of sensitivity,which includes(1)refining and improving all types of evaluation indicator systems and models;(2)innovating and developing evaluation methods and tools;and(3)combining field observation and case studies,so that(1)the impact of climate change and sensitivity can be assessed scientifically;(2)uncertainty in the study can be identified and reduced;and(3)improved understanding of climate systems and their changes,climate change impact,and sensitivity will be achieved.Second,strengthen adaptive capacity construction for crop production systems,which includes(1)rebuilding existing farmland infrastructure to improve meteorological disaster defences;(2)adjusting agriculture structure and adopting new crop varieties with enhanced resistance;(3)popularizing water-saving technology and dry farming technology;and(4)further researching interdisciplinary theories and methods.Third,strengthen function construction for natural and social systems,which includes(1)popularizing innovative technology;(2)progressing agricultural insurance;and(3)improving energy efficiency and increasing carbon sequestration and emission reduction ability to maintain a favorable ecological environment.展开更多
Tabletop integral imaging display with a more realistic and immersive experience has always been a hot spot in three-dimensional imaging technology,widely used in biomedical imaging and visualization to enhance medica...Tabletop integral imaging display with a more realistic and immersive experience has always been a hot spot in three-dimensional imaging technology,widely used in biomedical imaging and visualization to enhance medical diagnosis.However,the traditional structural characteristics of integral imaging display inevitably introduce the flipping effect outside the effective viewing angle.Here,a full-parallax tabletop integral imaging display without the flipping effect based on space-multiplexed voxel screen and compound lens array is demonstrated,and two holographic functional screens with different parameters are optically designed and fabricated.To eliminate the flipping effect in the reconstruction process,the space-multiplexed voxel screen consisting of a projector array and the holographic functional screen is presented to constrain light beams passing through the corresponding lens.To greatly promote imaging quality within the viewing area,the aspherical structure of the compound lens is optimized to balance the aberrations.It cooperates with the holographic functional screen to modulate the light field spatial distribution.Compared with the simulation results,the distortion rate of the imaging display is reduced to less than 9%from more than 30%.In the experiment,the floating high-quality reconstructed three-dimensional image without the flipping effect can be observed with the correct 3D perception at 96°×96°viewing angle,where 44,100 viewpoints are employed.展开更多
The evidence in this paper indicates that the alarming increase of common allergies can be reduced by the intake of particular “probiotics” or “paraprobiotics” along with food. This appears to build a consensus in...The evidence in this paper indicates that the alarming increase of common allergies can be reduced by the intake of particular “probiotics” or “paraprobiotics” along with food. This appears to build a consensus in the pharmaceutical and food communities about the role of probiotics in the prevention and treatments of common allergies. Food allergy is one of the common allergies, defined as an adverse health effect arising from a specific immune response that occurs reproducibly on exposure to a given food. Improving the digestion of foods and maintaining a healthy gastrointestinal (GI) tract is certainly critical to controlling food allergens. Therefore, the association between a leaky gut or an impaired intestinal permeability and food-allergenic reactions is explained. Gluten has been found to be somehow a justification for protein allergy, and should, therefore, be avoided by people with celiac disease. In several, in vitro models, surface layer (S- layer) proteins of selective paraprobiotics have shown potential in alleviating food allergies and intestinal disorders. Notably, lactobacilli paraprobiotics have proven to be the immediate immunomodulators against common allergies and other diseases, including viral (flu, hepatitis C), bacterial (bronchitis), asthma, chronic fatigue, fibromyalgia, gastrointestinal distress, and autism disorders in humans.展开更多
Objective: To investigate the mechanism of Shufeng Jiedu Capsule(SJC) for treatment of COVID-19 based on network pharmacology. Methods: Traditional Chinese Medicine Systems Pharmacology Database and Analysis Platform ...Objective: To investigate the mechanism of Shufeng Jiedu Capsule(SJC) for treatment of COVID-19 based on network pharmacology. Methods: Traditional Chinese Medicine Systems Pharmacology Database and Analysis Platform (TCMSP) was used to obtain the active components and targets information of Polygoni Cuspidati Rhizoma Et Radix, Forsythiae Fructus, Istidis Radix, Radix Bupleuri, Herba Patriniae, Verbenae Herb, Phragmitis Rhizoma and licorice in SJC. The Genecards databases were used to obtain COVID-19 targets. The meridian tropisms of each herb in SJC were collected from ETCM Database.the proteins interations network were build by STRING database. The GO and KEGG pathways were analyzed by the computer R language. Results: SFC contains 8herbs, 176 compounds and the corresponding targets 237. 48 COVID-19 targets are treated by SJC. Such as IL-10, IL-6, PTGS1, PTGS2, GSK3B, STAT-1, IL-17 signaling pathway, HIF-1 signaling pathway, Toll-like receptor signaling pathway, T cell receptor signaling pathway and VEGF signaling pathway may be potential targets and signaling pathways for the prevention and treatment of COVID-19. Conclusion: The COVID-19 cantreatmented the potential targets and signaling pathways by the SJC, and play the role of antipyretic, anti-inflammatory, balance immunity, antiviral and so on. It will provide strong support for the later stage experiment and clinical application of SJC.展开更多
基金the Canadian NRCan OERD Energy Innovation Programthe Natural Sciences and Engineering Research Council of Canada,and the Carbon Solution Program for their financial support.
文摘The pursuit of alternative fuel generation technologies has gained momentum due to the diminishing reserves of fossil fuels and global warming from increased CO_(2)emission.Among the proposed methods,the hydrogenation of CO_(2)to produce marketable carbon-based products like methanol and ethanol is a practical approach that offers great potential to reduce CO_(2)emissions.Although significant volumes of methanol are currently produced from CO_(2),developing highly efficient and stable catalysts is crucial for further enhancing conversion and selectivity,thereby reducing process costs.An in-depth examination of the differences and similarities in the reaction pathways for methanol and ethanol production highlights the key factors that drive C-C coupling.Identifying these factors guides us toward developing more effective catalysts for ethanol synthesis.In this paper,we explore how different catalysts,through the production of various intermediates,can initiate the synthesis of methanol or ethanol.The catalytic mechanisms proposed by spectroscopic techniques and theoretical calculations,including operando X-ray methods,FTIR analysis,and DFT calculations,are summarized and presented.The following discussion explores the structural properties and composition of catalysts that influence C-C coupling and optimize the conversion rate of CO_(2)into ethanol.Lastly,the review examines recent catalysts employed for selective methanol and ethanol production,focusing on single-atom catalysts.
基金Supported by the National Natural Science Foundation of China(No.41976027)the Laoshan Laboratory(No.LSKJ202201601)。
文摘We used the ocean reanalysis dataset SODA 2.2.4 to investigate the relationship between the interior branch of subtropical-tropical cells(STCs)in the Pacific Ocean and El Nino-Southern Oscillation(ENSO)over interdecadal timescales between 1930 and 2010,as well as the possible mechanisms involved.Interior transport within the upper pycnocline layers of STCs(InSTC)along 9°S(InSTC9s)shows a significant correlation of 0.54 with ENSO over the study period.However,there is an interdecadal shift in the relationship between InSTC along 9°N(InSTC9n)and ENSO.The correlation coefficient between InSTC9n and ENSO is not statistically significant between 1930 and 1965(PD1),but is as high as 0.68(significant at the 95% confidence level)between 1965 and 2010(PD2).Composite and regression analysis suggests that this shift may be caused by the relationship between InSTC 9 n and the tropical wind field.During PD1,InSTC9n was driven primarily by the local wind field outside equatorial region,with a relatively weak response to the equatorial wind related to ENSO.In contrast,during PD2,the wind field associated with InSTC 9 n showed a similar spatial distribution to that of ENSO within the equatorial region,indicating a close relationship between InSTC9n and ENSO.The wind stress curl associated with ENSO drives the anomalous InSTC9n in off-equatorial regions,whose signal can propagate westward in the form of Rossby wave and modulate the thermal structure of the tropical Pacific,favoring the development of ENSO.The possible connection between the Atlantic Multidecadal Oscillation(AMO)and interdecadal changes in the ENSO-InSTC9n relationship was also examined.There is a significant connection between the AMO and the interdecadal change in the relationship between ENSO and InSTC9n;however,the associated mechanism remains to be explored in future studies.
基金supported by the National Basic Research Program of China (2010CB732304)the National Natural Science Foundation of China (21177142 and 20973193)
文摘CuO-CeO2 catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature.The catalytic performance was evaluated and the catalysts were characterized by inductively coupled plasma atomic emission spectroscopy,X-ray diffraction,temperature-programmed reduction,field emission scanning electron microscopy and thermo-gravimetric analysis.Over CuOCeO2 catalysts,H2 with low CO content was produced in the whole tested temperature range of 250–450 C.The non-noble metal catalyst 20CuCe showed higher H2production rate than 1%Rh/CeO2 catalyst at 300–400 C and the advantage was more obvious after 20 h testing at400 C.These results further confirmed that CuO-CeO2 catalysts may be suitable candidates for low temperature hydrogen production from ethanol.
基金supported by the National High Technology Research and Development Program(863 Program) of China(No.2013AA065204)the Fundamental Research Funds for the Central Universities in China(No.2015TS103)
文摘Changes in water quality from source water to finished water and tap water at two conventional drinking water treatment plants(DWTPs)were monitored.Beside the routine water quality testing,Caenorhabditis elegans-based toxicity assays and the fluorescence excitation–emission matrices technique were also applied.Both DWTPs supplied drinking water that met government standards.Under current test conditions,both the investigated finished water and tap water samples exhibited stronger lethal,genotoxic and reprotoxic potential than the relative source water sample,and the tap water sample was more lethal but tended to be less genotoxic than the corresponding finished water sample.Meanwhile,the nearly complete removal of tryptophan-like substances and newly generated tyrosine-like substances were observed after the treatment of drinking water,and humic-like substances were identified in the tap water.Based on these findings,toxic pollutants,including genotoxic/reproductive toxicants,are produced in the drinking water treatment and/or distribution processes.Moreover,further studies are needed to clarify the potentially important roles of tyrosine-like and humic-like substances in mediating drinking water toxicity and to identify the potential sources of these contaminants.Additionally,tryptophan-like fluorescence may be adopted as a useful parameter to monitor the treatment performance of DWTPs.Our observations provided insights into the importance of utilizing biotoxicity assays and fluorescence spectroscopy as tools to complement the routine evaluation of drinking water.
文摘Climate warming has prolonged the optimization of crop-growing seasons,shortened actual growth periods,and changed crop-planting boundaries.It also has boosted crop yields in certain regions while compromising crop quality and affected the occurrence of meteorological disasters and pest diseases damage,which has resulted in reduction in grain yield.Crop production systems will evidence more sensitivity to climate change in future;for example,with an increase of 1°C in temperature,the average growth period will be shortened by 17 days for winter wheat and 7-8 days for maize and rice.Of course regional differences will exist.Climate change will threaten crop yield stability and affect crop quality.Vulnerability will be addressed in regard to extreme climatic events,which include reducing exposure and improving adaptive capacity,because the exposure of rain-fed agriculture is greater than that of irrigated agriculture.Therefore,we propose three suggestions to reduce the vulnerability of crop production systems to climate change.First,strengthen the evaluation capacity construction of sensitivity,which includes(1)refining and improving all types of evaluation indicator systems and models;(2)innovating and developing evaluation methods and tools;and(3)combining field observation and case studies,so that(1)the impact of climate change and sensitivity can be assessed scientifically;(2)uncertainty in the study can be identified and reduced;and(3)improved understanding of climate systems and their changes,climate change impact,and sensitivity will be achieved.Second,strengthen adaptive capacity construction for crop production systems,which includes(1)rebuilding existing farmland infrastructure to improve meteorological disaster defences;(2)adjusting agriculture structure and adopting new crop varieties with enhanced resistance;(3)popularizing water-saving technology and dry farming technology;and(4)further researching interdisciplinary theories and methods.Third,strengthen function construction for natural and social systems,which includes(1)popularizing innovative technology;(2)progressing agricultural insurance;and(3)improving energy efficiency and increasing carbon sequestration and emission reduction ability to maintain a favorable ecological environment.
基金The Basic Research Fund of Central-Level Nonprofit Scientific Research Institutes(No.TKS20220304)The Key Research and Development Projects of Guangxi Science and Technology Department(No.2021AB05087).
文摘Tabletop integral imaging display with a more realistic and immersive experience has always been a hot spot in three-dimensional imaging technology,widely used in biomedical imaging and visualization to enhance medical diagnosis.However,the traditional structural characteristics of integral imaging display inevitably introduce the flipping effect outside the effective viewing angle.Here,a full-parallax tabletop integral imaging display without the flipping effect based on space-multiplexed voxel screen and compound lens array is demonstrated,and two holographic functional screens with different parameters are optically designed and fabricated.To eliminate the flipping effect in the reconstruction process,the space-multiplexed voxel screen consisting of a projector array and the holographic functional screen is presented to constrain light beams passing through the corresponding lens.To greatly promote imaging quality within the viewing area,the aspherical structure of the compound lens is optimized to balance the aberrations.It cooperates with the holographic functional screen to modulate the light field spatial distribution.Compared with the simulation results,the distortion rate of the imaging display is reduced to less than 9%from more than 30%.In the experiment,the floating high-quality reconstructed three-dimensional image without the flipping effect can be observed with the correct 3D perception at 96°×96°viewing angle,where 44,100 viewpoints are employed.
文摘The evidence in this paper indicates that the alarming increase of common allergies can be reduced by the intake of particular “probiotics” or “paraprobiotics” along with food. This appears to build a consensus in the pharmaceutical and food communities about the role of probiotics in the prevention and treatments of common allergies. Food allergy is one of the common allergies, defined as an adverse health effect arising from a specific immune response that occurs reproducibly on exposure to a given food. Improving the digestion of foods and maintaining a healthy gastrointestinal (GI) tract is certainly critical to controlling food allergens. Therefore, the association between a leaky gut or an impaired intestinal permeability and food-allergenic reactions is explained. Gluten has been found to be somehow a justification for protein allergy, and should, therefore, be avoided by people with celiac disease. In several, in vitro models, surface layer (S- layer) proteins of selective paraprobiotics have shown potential in alleviating food allergies and intestinal disorders. Notably, lactobacilli paraprobiotics have proven to be the immediate immunomodulators against common allergies and other diseases, including viral (flu, hepatitis C), bacterial (bronchitis), asthma, chronic fatigue, fibromyalgia, gastrointestinal distress, and autism disorders in humans.
基金Scientific research project of Heilongjiang administration of traditional Chinese MedicineGeneral project of scientific research fund of Heilongjiang University of traditional Chinese Medicine(201819)
文摘Objective: To investigate the mechanism of Shufeng Jiedu Capsule(SJC) for treatment of COVID-19 based on network pharmacology. Methods: Traditional Chinese Medicine Systems Pharmacology Database and Analysis Platform (TCMSP) was used to obtain the active components and targets information of Polygoni Cuspidati Rhizoma Et Radix, Forsythiae Fructus, Istidis Radix, Radix Bupleuri, Herba Patriniae, Verbenae Herb, Phragmitis Rhizoma and licorice in SJC. The Genecards databases were used to obtain COVID-19 targets. The meridian tropisms of each herb in SJC were collected from ETCM Database.the proteins interations network were build by STRING database. The GO and KEGG pathways were analyzed by the computer R language. Results: SFC contains 8herbs, 176 compounds and the corresponding targets 237. 48 COVID-19 targets are treated by SJC. Such as IL-10, IL-6, PTGS1, PTGS2, GSK3B, STAT-1, IL-17 signaling pathway, HIF-1 signaling pathway, Toll-like receptor signaling pathway, T cell receptor signaling pathway and VEGF signaling pathway may be potential targets and signaling pathways for the prevention and treatment of COVID-19. Conclusion: The COVID-19 cantreatmented the potential targets and signaling pathways by the SJC, and play the role of antipyretic, anti-inflammatory, balance immunity, antiviral and so on. It will provide strong support for the later stage experiment and clinical application of SJC.
