Acid catalyzed rearrangements of 1 and 3 were examined. The olefinic double bond was the most reactive group in protonation reaction. In the absence of olefinic double bond, tert-hydroxy group reacted faster than cycl...Acid catalyzed rearrangements of 1 and 3 were examined. The olefinic double bond was the most reactive group in protonation reaction. In the absence of olefinic double bond, tert-hydroxy group reacted faster than cyclopropane ring.展开更多
文摘Acid catalyzed rearrangements of 1 and 3 were examined. The olefinic double bond was the most reactive group in protonation reaction. In the absence of olefinic double bond, tert-hydroxy group reacted faster than cyclopropane ring.