The performance of lithium-sulfur batteries(LSBs)is severely limited by a detrimental negative feedback loop:sluggish polysulfide conversion kinetics lead to Li_(2)S accumulation,which further hinders lithiumion trans...The performance of lithium-sulfur batteries(LSBs)is severely limited by a detrimental negative feedback loop:sluggish polysulfide conversion kinetics lead to Li_(2)S accumulation,which further hinders lithiumion transport and exacerbates capacity decay.To address this,we propose a positive feedback strategy that simultaneously enhances lithium polysulfides(LiPSs)conversion and lithium-ion diffusion through a rationally designed separator.By modifying the separator with phosphorus-doped two-dimensional hollow holey carbon nanosheets(Hollow HCNS),we establish an interconnected network where rapid LiPSs confinement and conversion within the hollow cavities promote efficient lithium-ion transport,while the improved ion flux further accelerates reaction kinetics.This mutual reinforcement mechanism ensures stable cycling by suppressing the shuttle effect and promoting uniform Li_(2)S deposition,as verified by in situ spectroscopic and electrochemical analysis.The resulting LSBs exhibit high-rate capability,ultralow capacity decay,and exceptional stability under high sulfur loading.This work presents a general approach to overcoming the persistent negative feedback problem in high-energy battery systems by synergistically optimizing catalytic conversion and ionic transport.展开更多
Interacting Multiple Model (IMM) estimator can provide better performance of target tracking than mono model Kalman filter. In multi-sensor system ordinarily, availability of measurement from different sensors is stoc...Interacting Multiple Model (IMM) estimator can provide better performance of target tracking than mono model Kalman filter. In multi-sensor system ordinarily, availability of measurement from different sensors is stochastic, and it is difficult to construct uniform global observation vector and observation matrix appropri-ately in existing method. An IMM estimator for uncertain measurement is presented. By the method invalid measurement is regarded as outlier, and approximation is reconstructed by feedback of system state estima-tion of fusion center. Then nominally generalized certain measurement can be obtained by substituting re-constructed one for invalid one. The generalized certain measurement can be centralized to construct global measurement and provided to IMM estimator, and existing multi-sensor IMM estimation method is general-ized to uncertain environment. Theoretical analysis and simulation results show the effectiveness of the method.展开更多
To adapt to the trend toward low-energy precision irrigation, the droplet distributions for two new prototype sprinklers, outside signal sprinkler(OS) and fluidic sprinkler(FS), were compared with impact sprinkler(IS)...To adapt to the trend toward low-energy precision irrigation, the droplet distributions for two new prototype sprinklers, outside signal sprinkler(OS) and fluidic sprinkler(FS), were compared with impact sprinkler(IS). A laser precipitation monitor was used to measure the droplet distributions. Droplet size and velocity distributions were tested under four operating pressures for nozzles 1.5 m above the ground. For the operating pressures tested, the mean OS, FS and IS droplet diameters ranged from 0 to 3.4, 0 to 3.5, 0 to 4.0 mm, respectively.The mean OS and FS droplet velocities ranged from 0 to6.3 m$s–1, whereas IS ranged from 0 to 6.3 m$s–1. Being gas-liquid fluidic sprinklers, droplet distributions of the OS and FS were similar, although not identical. IS mostly produced a 0.5 mm larger droplet diameter and a 0.5 m$s–1greater velocity than OS and FS. A new empirical equation is proposed for determination of droplet size for OS and FS, which is sufficiently accurate and simple to use. Basic statistics for droplet size and velocity were performed on data obtained by the photographic methods. The mean droplet diameter(arithmetic, volumetric and median)decreased and the mean velocity increased in operating pressure for the three types of sprinkler.展开更多
To improve the tracking accuracy and stability of an optic-electronic target tracking system,the concept of generalized synergic target and an algorithm named error-space estimate method is presented.In this algorithm...To improve the tracking accuracy and stability of an optic-electronic target tracking system,the concept of generalized synergic target and an algorithm named error-space estimate method is presented.In this algorithm,the motion of target is described by guide data and guide errors,and then the maneuver of the target is separated into guide data and guide errors to reduce the maneuver level.Then state estimate is implemented in target state-space and error-space respectively,and the prediction data of target position are acquired by synthesizing the filtering data from target state-space according to kinematic model and the prediction data from errorspace according to guide error model.Differing from typical multi-model method,the kinematic and guide error models work concurrently rather than switch between models.Experiment results show that the performance of the algorithm is better than Kalman filter and strong tracking filter at the same maneuver level.展开更多
基金the support from the National Science Foundation of China(22471226,22272142)the 111 Project(B16029)。
文摘The performance of lithium-sulfur batteries(LSBs)is severely limited by a detrimental negative feedback loop:sluggish polysulfide conversion kinetics lead to Li_(2)S accumulation,which further hinders lithiumion transport and exacerbates capacity decay.To address this,we propose a positive feedback strategy that simultaneously enhances lithium polysulfides(LiPSs)conversion and lithium-ion diffusion through a rationally designed separator.By modifying the separator with phosphorus-doped two-dimensional hollow holey carbon nanosheets(Hollow HCNS),we establish an interconnected network where rapid LiPSs confinement and conversion within the hollow cavities promote efficient lithium-ion transport,while the improved ion flux further accelerates reaction kinetics.This mutual reinforcement mechanism ensures stable cycling by suppressing the shuttle effect and promoting uniform Li_(2)S deposition,as verified by in situ spectroscopic and electrochemical analysis.The resulting LSBs exhibit high-rate capability,ultralow capacity decay,and exceptional stability under high sulfur loading.This work presents a general approach to overcoming the persistent negative feedback problem in high-energy battery systems by synergistically optimizing catalytic conversion and ionic transport.
文摘Interacting Multiple Model (IMM) estimator can provide better performance of target tracking than mono model Kalman filter. In multi-sensor system ordinarily, availability of measurement from different sensors is stochastic, and it is difficult to construct uniform global observation vector and observation matrix appropri-ately in existing method. An IMM estimator for uncertain measurement is presented. By the method invalid measurement is regarded as outlier, and approximation is reconstructed by feedback of system state estima-tion of fusion center. Then nominally generalized certain measurement can be obtained by substituting re-constructed one for invalid one. The generalized certain measurement can be centralized to construct global measurement and provided to IMM estimator, and existing multi-sensor IMM estimation method is general-ized to uncertain environment. Theoretical analysis and simulation results show the effectiveness of the method.
基金supported by grants from the Program for National Hi-Tech Research and Development of China(2011AA100506)the National Natural Science Foundation of China(51309117)the Six Talent Peaks Project in Jiangsu Province(ZBZZ-018)
文摘To adapt to the trend toward low-energy precision irrigation, the droplet distributions for two new prototype sprinklers, outside signal sprinkler(OS) and fluidic sprinkler(FS), were compared with impact sprinkler(IS). A laser precipitation monitor was used to measure the droplet distributions. Droplet size and velocity distributions were tested under four operating pressures for nozzles 1.5 m above the ground. For the operating pressures tested, the mean OS, FS and IS droplet diameters ranged from 0 to 3.4, 0 to 3.5, 0 to 4.0 mm, respectively.The mean OS and FS droplet velocities ranged from 0 to6.3 m$s–1, whereas IS ranged from 0 to 6.3 m$s–1. Being gas-liquid fluidic sprinklers, droplet distributions of the OS and FS were similar, although not identical. IS mostly produced a 0.5 mm larger droplet diameter and a 0.5 m$s–1greater velocity than OS and FS. A new empirical equation is proposed for determination of droplet size for OS and FS, which is sufficiently accurate and simple to use. Basic statistics for droplet size and velocity were performed on data obtained by the photographic methods. The mean droplet diameter(arithmetic, volumetric and median)decreased and the mean velocity increased in operating pressure for the three types of sprinkler.
基金supported by the Hi-Tech Research and Development Program of China.
文摘To improve the tracking accuracy and stability of an optic-electronic target tracking system,the concept of generalized synergic target and an algorithm named error-space estimate method is presented.In this algorithm,the motion of target is described by guide data and guide errors,and then the maneuver of the target is separated into guide data and guide errors to reduce the maneuver level.Then state estimate is implemented in target state-space and error-space respectively,and the prediction data of target position are acquired by synthesizing the filtering data from target state-space according to kinematic model and the prediction data from errorspace according to guide error model.Differing from typical multi-model method,the kinematic and guide error models work concurrently rather than switch between models.Experiment results show that the performance of the algorithm is better than Kalman filter and strong tracking filter at the same maneuver level.
